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Tris(3-methoxyphenyl)phosphine

Product Name
Tris(3-methoxyphenyl)phosphine
CAS No.
29949-84-6
Chemical Name
Tris(3-methoxyphenyl)phosphine
Synonyms
Tris(3-methoxyphenyl);tri(m-anisyl)phosphine;TRIS(M-ANISYL)PHOSPHINE;TRIS(3-METHOXYPHENYL)PHOSP;ris(3-methoxyphenyl)phosphane;tris(3-Methoxyphenyl)phosphane;TRIS(M-METHOXYPHENYL)PHOSPHINE;TRIS(3-METHOXYPHENYL)PHOSPHINE;Phosphine,tris(3-methoxyphenyl)-;Phosphine,tris(3-METHOXYBENZYL)-
CBNumber
CB2490360
Molecular Formula
C21H21O3P
Formula Weight
352.36
MOL File
29949-84-6.mol
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Tris(3-methoxyphenyl)phosphine Property

Melting point:
113-115 °C(lit.)
Boiling point:
476.3±40.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
Crystalline Powder
color 
White to almost white
InChI
InChI=1S/C21H21O3P/c1-22-16-7-4-10-19(13-16)25(20-11-5-8-17(14-20)23-2)21-12-6-9-18(15-21)24-3/h4-15H,1-3H3
InChIKey
CCXTYQMZVYIQRP-UHFFFAOYSA-N
SMILES
P(C1=CC=CC(OC)=C1)(C1=CC=CC(OC)=C1)C1=CC=CC(OC)=C1
CAS DataBase Reference
29949-84-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
No
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T2946
Product name
Tris(3-methoxyphenyl)phosphine
Packaging
5G
Price
$69
Updated
2024/03/01
TCI Chemical
Product number
T2946
Product name
Tris(3-methoxyphenyl)phosphine
Packaging
25G
Price
$206
Updated
2024/03/01
Alfa Aesar
Product number
A17949
Product name
Tris(3-methoxyphenyl)phosphine
Purity
98%
Packaging
1g
Price
$66.65
Updated
2024/03/01
Alfa Aesar
Product number
A17949
Product name
Tris(3-methoxyphenyl)phosphine
Purity
98%
Packaging
5g
Price
$262.65
Updated
2024/03/01
Strem Chemicals
Product number
15-7975
Product name
Tris(m-methoxyphenyl)phosphine, 97+%
Packaging
1g
Price
$103
Updated
2024/03/01
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Tris(3-methoxyphenyl)phosphine Chemical Properties,Usage,Production

Chemical Properties

White to almost white crystalline powder

Uses

suzuki reaction

Synthesis

1-iodo-3-methoxybenzene could be used to synthesize Tri(o-anisole)phosphine (Tris(3-methoxyphenyl)phosphine). Reactions performed using 0.1?mmol NaPH2, 2?mol?% PF6, 11?equiv 1-iodo-3-methoxybenzene, 15?equiv Et3N in 2.0?mL MeCN under blue LED irradiation and N2 atmosphere for 24?h[1]. 

References

[1]"Photocatalytic Arylation of P4 and PH3: Reaction Development Through Mechanistic Insight." Angewandte Chemie (2021).

Tris(3-methoxyphenyl)phosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(3-methoxyphenyl)phosphine Suppliers

SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from Tris(3-methoxyphenyl)phosphine manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tris(3-Methoxyphenyl)Phosphine 29949-84-6
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-17
Hebei Weibang Biotechnology Co., Ltd
Product
TRIS(3-METHOXYPHENYL)PHOSPHINE 29949-84-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-22
Shaanxi Dideu Medichem Co. Ltd
Product
Tris(3-Methoxyphenyl)phosphine 29949-84-6
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 Tons
Release date
2020-01-14

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