ChemicalBook > CAS DataBase List > 1-Bromo-3-methyl-2-butanone

1-Bromo-3-methyl-2-butanone

Product Name
1-Bromo-3-methyl-2-butanone
CAS No.
19967-55-6
Chemical Name
1-Bromo-3-methyl-2-butanone
Synonyms
1-Bromo-3-methylbutan-2-one;1-BROMO-3-METHYL-2-BUTANONE;2-BroMo-1-isopropylethanone;Isopropyl bromomethyl ketone;Bromomethyl isopropyl ketone;2-Butanone, 1-bromo-3-methyl-;1-BroMo-3,3-diMethyl-2-propanone;1-BroMo-3-Methylbutan-2-one, 95+%
CBNumber
CB2504683
Molecular Formula
C5H9BrO
Formula Weight
165.03
MOL File
19967-55-6.mol
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1-Bromo-3-methyl-2-butanone Property

Boiling point:
164 °C
Density 
1.355
refractive index 
1.4685
Flash point:
56 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
Chloroform, Ethyl Acetate
form 
Oil
color 
Clear Colourless
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Safety

HS Code 
2914120000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B685510
Product name
1-Bromo-3-methyl-2-butanone
Packaging
50g
Price
$1260
Updated
2021/12/16
Oakwood
Product number
079016
Product name
1-Bromo-3-methylbutan-2-one
Purity
95%
Packaging
250mg
Price
$27
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB15324
Product name
1-Bromo-3-methyl-2-butanone
Packaging
500mg
Price
$65
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB15324
Product name
1-Bromo-3-methyl-2-butanone
Packaging
1g
Price
$100
Updated
2021/12/16
AK Scientific
Product number
W4222
Product name
1-Bromo-3-methyl-2-butanone
Packaging
1g
Price
$149
Updated
2021/12/16
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1-Bromo-3-methyl-2-butanone Chemical Properties,Usage,Production

Synthesis

563-80-4

19967-55-6

Example 1 Synthesis of 1-bromo-3-methylbutan-2-one: (1) Bromine (12.9 mL, 250 mmol) was added slowly and dropwise to an ethanol (EtOH, 250 mL) solution of 3-methyl-2-butanone (25.8 g, 300 mmol) under ice bath cooling conditions. The reaction mixture was stirred continuously for 2 h in an ice bath. After completion of the reaction, it was diluted by adding petroleum ether (600 mL). The organic phase was separated and washed twice with distilled water. The combined aqueous phases were back-extracted twice with petroleum ether. All organic phases were combined and washed twice each with cold sodium carbonate solution and saturated saline in that order. The organic phase was dried over anhydrous sodium sulfate and concentrated under reduced pressure at room temperature to afford the target product 1-bromo-3-methylbutan-2-one in 50% yield.

References

[1] Patent: US5910506, 1999, A
[2] Patent: WO2007/14921, 2007, A1. Location in patent: Page/Page column 69
[3] Patent: WO2003/106455, 2003, A1. Location in patent: Page 60
[4] Patent: WO2007/14922, 2007, A1. Location in patent: Page/Page column 79-80
[5] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 8, p. 2922 - 2926

1-Bromo-3-methyl-2-butanone Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Bromo-3-methyl-2-butanone Suppliers

Canada 1 China 114 Europe 1 Germany 2 India 1 Switzerland 1 United Kingdom 3 United States 6 Global 129
Nanjing Huarui Biopharmaceutical Technology Co., Ltd.
Tel
18014824111
Email
908320070@qq.com
Country
China
ProdList
65
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58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Chemsky（shanghai）International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
3829
Advantage
50
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9510
Advantage
58
Nanjing Norris-Pharm Technology Co., Ltd
Tel
18652989687
Fax
+86-25-52131256
Email
sales@norris-pharm.com
Country
China
ProdList
8878
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55
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
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View Lastest Price from 1-Bromo-3-methyl-2-butanone manufacturers

Henan Fengda Chemical Co., Ltd
Product
1-Bromo-3-methyl-2-butanone 19967-55-6
Price
US $30.00-0.50/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-22
Career Henan Chemical Co
Product
1-Bromo-3-methyl-2-butanone 19967-55-6
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000kg
Release date
2020-01-13

19967-55-6, 1-Bromo-3-methyl-2-butanoneRelated Search:

Bensulfuron methyl 3-Methyl-2-butanone Kresoxim-methyl 4-Bromomethylbenzoic acid Methylparaben 3,3-Dimethylallyl bromide Bromotrimethylsilane ISOPROPYL LAURATE 4-Methyl-2-pentanone Methyl acrylate Methyltris(methylethylketoxime)silane Isopropyl alcohol 2-Butanone oxime 2,4-Dimethyl-3-pentanone Thiophanate-methyl Methyl Bromine Methyl bromide

  • 1-BROMO-3-METHYL-2-BUTANONE
  • Bromomethyl isopropyl ketone
  • Isopropyl bromomethyl ketone
  • 2-Butanone, 1-bromo-3-methyl-
  • 1-Bromo-3-methylbutan-2-one
  • 1-BroMo-3,3-diMethyl-2-propanone
  • 2-BroMo-1-isopropylethanone
  • 1-BroMo-3-Methylbutan-2-one, 95+%
  • 19967-55-6