ChemicalBook > CAS DataBase List > 2-AMINO-3-BROMO-4-METHYLPYRIDINE

2-AMINO-3-BROMO-4-METHYLPYRIDINE

Product Name
2-AMINO-3-BROMO-4-METHYLPYRIDINE
CAS No.
40073-38-9
Chemical Name
2-AMINO-3-BROMO-4-METHYLPYRIDINE
Synonyms
3-broMo-4-Methylpyridin-2-aMine;2-AMINO-3-BROMO-4-PICOLINE;3-Bromo-4-methyl-2-pyridinamine;2-AMino-3-broMo-4-Methyopyridine;2-AMINO-3-BROMO-4-METHYLPYRIDINE;3-Bromo-4-methylpyridin-2-ylamine;2-Pyridinamine, 3-bromo-4-methyl-;2 - amino 4 - methy 3 - bromo pyridine;2-AMINO-3-BROMO-4-METHYLPYRIDINE ISO 9001:2015 REACH
CBNumber
CB2697736
Molecular Formula
C6H7BrN2
Formula Weight
187.04
MOL File
40073-38-9.mol
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2-AMINO-3-BROMO-4-METHYLPYRIDINE Property

Boiling point:
255.2±35.0 °C(Predicted)
Density 
1.593±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
4.71±0.47(Predicted)
Appearance
Off-white to light yellow Solid
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
A595808
Product name
2-Amino-3-bromo-4-picoline
Packaging
100mg
Price
$65
Updated
2021/12/16
AK Scientific
Product number
J97881
Product name
2-Amino-3-bromo-4-picoline
Packaging
1g
Price
$60
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA42913
Product name
2-Amino-3-bromo-4-picoline
Packaging
250mg
Price
$100
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA42913
Product name
2-Amino-3-bromo-4-picoline
Packaging
500mg
Price
$115
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA42913
Product name
2-Amino-3-bromo-4-picoline
Packaging
1g
Price
$138
Updated
2021/12/16
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2-AMINO-3-BROMO-4-METHYLPYRIDINE Chemical Properties,Usage,Production

Synthesis

3430-29-3

40073-38-9

General procedure for the synthesis of 2-amino-3-bromo-4-methylpyridine from 2-amino-3,5-dibromo-4-methylpyridine: 3,5-dibromo-4-methylpyridin-2-amine (3.38 g, 12.7 mmol) was dissolved in dry tetrahydrofuran (60 mL) under the protection of nitrogen, and cooled to -78°C. n-Butyllithium (1.9 M in pentane, 13.4 mL, 25.4 mmol) was added slowly and the reaction mixture turned orange. The reaction was quenched by careful addition of water (10 mL) after 1 h of continuous stirring at -78°C. The reaction was stopped by the addition of a solution of 10 N sodium hydroxide. The pH of the reaction mixture was adjusted to about 12 with 10 N sodium hydroxide solution and then extracted with dichloromethane (3 x 30 mL). The organic phases were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give an orange oil. Purification by silica gel column chromatography (with ether as eluent) afforded 2-amino-3-bromo-4-methylpyridine (1.68 g, 71% yield) as a light yellow solid.1H NMR (CDCl3) δ 2.32 (s, 3H), 5.00 (br s, 2H), 6.52 (d, 1H, J = 6.0 Hz), 7.84 (d, 1H, J = 6.0 Hz ).

References

[1] Patent: US2005/277668, 2005, A1. Location in patent: Page/Page column 28
[2] Patent: EP3372601, 2018, A1. Location in patent: Paragraph 0693; 0694

2-AMINO-3-BROMO-4-METHYLPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-3-BROMO-4-METHYLPYRIDINE Suppliers

Capot Chemical Co., Ltd
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+86 (0) 571 85 58 67 18
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0086-571-85864795
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China
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Shanghai Longsheng chemical Co.,Ltd.
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021-58099652-8005 13585536065
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021-58099609
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bin.wu@shlschem.com
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China
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China Langchem Inc.
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0086-21-58956006
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0086-21-58956100
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China
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Shanghai Sunway Pharmaceutical Technology Co., Ltd
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18270980682
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021 51613951
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mlcheng@sunwaypharm.cn
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China
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Nanjing Vital Chemical Co., Ltd.
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Please Send Email 18652950785
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025-87193546
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chemweiao@163.com
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China
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Hangzhou Sage Chemical Co., Ltd.
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+86057186818502 13588463833
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Pls mail us for more information!
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info@sagechem.com
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China
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Nanjing Norris-Pharm Technology Co., Ltd
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+86-25-52131256
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sales@norris-pharm.com
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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
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025-66113011 17798518460
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(1)02557626880
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cfzhang@aikonchem.com
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China
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SuZhou ShiYa Biopharmaceuticals, Inc.
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86(512)5235 8471 17715136450
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86(512)5235 6881
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sales@shiyabiopharm.com
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China
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SynAsst Chemical.
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021-60343070
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021-35122006
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China
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View Lastest Price from 2-AMINO-3-BROMO-4-METHYLPYRIDINE manufacturers

Dideu Industries Group Limited
Product
2-AMINO-3-BROMO-4-METHYLPYRIDINE 40073-38-9
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons min
Release date
2021-08-27
Career Henan Chemical Co
Product
2-AMINO-3-BROMO-4-METHYLPYRIDINE 40073-38-9
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
10 tons
Release date
2020-01-10