Reaction
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(R)-MONOPHOS

Reaction
Product Name
(R)-MONOPHOS
CAS No.
157488-65-8
Chemical Name
(R)-MONOPHOS
Synonyms
(R)-MONOPHOS;(S)-MONOPHOS;97% (R)-MONOPHOS;3,4-a']dinaphthalen;3,4-a']dinaphthalen-4-yl)piperidine;3,4-a']dinaphthalen-4-yl)Morpholine;3,4-a']dinaphthalen-4-yl)dipropylaMine;3,4-a']dinaphthalen-4-yl)dimethylamine;(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine, R-MonoPhos
CBNumber
CB2704984
Molecular Formula
C22H18NO2P
Formula Weight
359.36
MOL File
157488-65-8.mol
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(R)-MONOPHOS Property

Melting point:
190 °C (dec.)
alpha 
-583° (c 0.06, CHCl3)
Boiling point:
548.7±33.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
pka
1.22±0.20(Predicted)
color 
white
Sensitive 
air sensitive
InChIKey
QCHAVHXSBZARBO-UHFFFAOYSA-N
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
TSCA 
No
HS Code 
2934.99.4400
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
668206
Product name
(R)-(?)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)dimethylamine
Purity
97%
Packaging
1g
Price
$55.4
Updated
2023/06/20
TCI Chemical
Product number
D4992
Product name
(R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine
Purity
>98.0%(HPLC)(N)
Packaging
1g
Price
$56
Updated
2024/03/01
TCI Chemical
Product number
D4992
Product name
(R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine
Purity
>98.0%(HPLC)(N)
Packaging
5g
Price
$180
Updated
2024/03/01
Strem Chemicals
Product number
15-1232
Product name
(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS
Packaging
250mg
Price
$29
Updated
2024/03/01
Strem Chemicals
Product number
15-1232
Product name
(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS
Packaging
1g
Price
$85
Updated
2024/03/01
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(R)-MONOPHOS Chemical Properties,Usage,Production

Reaction

  1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
  2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
  3. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
  4. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
  5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.

Uses

DSM MonoPhos Family of Highly Efficient Privileged Ligands

(R)-MONOPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-MONOPHOS Suppliers

Americas 1 Canada 2 China 86 Europe 1 France 1 Germany 3 India 3 Japan 2 Switzerland 1 The Netherlands 1 United States 15 Global 116
R&D Scientific Inc.
Tel
+1-2266000236
Email
sales@rdscientific.com
Country
Canada
ProdList
1604
Advantage
58
Digital Specialty Chemicals Ltd. (DSC)
Tel
--
Fax
--
Email
tajinder.malik@digitalchem.ca
Country
Canada
ProdList
83
Advantage
58
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View Lastest Price from (R)-MONOPHOS manufacturers

R&D Scientific Inc.
Product
N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 157488-65-8
Price
US $3800.00/Kg
Min. Order
1Kg
Purity
97
Supply Ability
500 Kg
Release date
2024-07-11
Henan Aochuang Chemical Co.,Ltd.
Product
(r)-(-)-(3,5-dioxa-4-phosphacyclohepta(2,1-a 157488-65-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-()-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)dimethylamine 157488-65-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

157488-65-8, (R)-MONOPHOSRelated Search:

3,4-a']dinaphthalen-4-yl)dimethylamine (R)-MONOPHOS (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE (11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D:1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE, KANATA PURITY (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

  • (R)-(-)-[4-N,N-Dimethylamino]dinaphtho[2.1-d:1'.2'-f][1.3.2]dioxaphosphepine(R)-monophos]
  • (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
  • 3,4-a']dinaphthalen-4-yl)dimethylamine,min.97%(R)-MONOPHOS
  • (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS
  • 3,4-a']dinaphthalen-4-yl)dimethylamine
  • (R)-()-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]di-naphthalen-4-yl)dimethylamine,(R)-Monophos
  • 3,4-a']dinaphthalen
  • 3,4-a']dinaphthalen-4-yl)[(1S)-1-phenylethyl]-aMine
  • 3,4-a']dinaphthalen-4-yl)dipropylaMine
  • 3,4-a']dinaphthalen-4-yl)Morpholine
  • 3,4-a']dinaphthalen-4-yl)piperidine
  • R-8,9,10,11,12,13,14,15,Octahydro-3,5-dioxa-4-phosphacyclohepta[2,1-a
  • (R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diMethylaMine 97%
  • (R)-N,N-DiMethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine
  • 3,4-a']dinaphthalen-4-yl)dimethylamine,97% (R)-MONOPHOS
  • (11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 97% (R)-MONOPHOS
  • -N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin-4-amine,99%e.e.
  • (R)-(-)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE
  • (R)-(-)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE
  • (S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE
  • (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE
  • (R)-MONOPHOS
  • (S)-MONOPHOS
  • 3,4-a']dinaphthalen-4-yl)dimethylamine, R-MonoPhos
  • (11bR)-N,N-Dimethyl-dinaphtho[2,1-9d8:1%',21'-5f]7[418,38,-26]5d-i8ox
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-dimethyl-, (11bR)-
  • (R)-(-)-[4-N,N-Dimethylamino]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinapht...
  • (R)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 3,4-a']dinaphthalen-4-yl)dimethylamine, R-MonoPhos
  • (11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 157488-65-8
  • 422509-53-5
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Privileged Ligands
  • DSM MonoPhos Phosphoramidites
  • SF160006
  • Chiral Phosphine
  • CPN