(R)-MONOPHOS

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Reaction

Product Name: (R)-MONOPHOS
CAS No.: 157488-65-8
Chemical Name: (R)-MONOPHOS
Synonyms: (R)-MONOPHOS;(S)-MONOPHOS;97% (R)-MONOPHOS;3,4-a']dinaphthalen;3,4-a']dinaphthalen-4-yl)piperidine;3,4-a']dinaphthalen-4-yl)Morpholine;3,4-a']dinaphthalen-4-yl)dipropylaMine;3,4-a']dinaphthalen-4-yl)dimethylamine;(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine, R-MonoPhos
CBNumber: CB2704984
Molecular Formula: C22H18NO2P
Formula Weight: 359.36
MOL File: 157488-65-8.mol

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(R)-MONOPHOS Property

Melting point:: 190 °C (dec.)
alpha: -583° (c 0.06, CHCl3)
Boiling point:: 548.7±33.0 °C(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: crystal
pka: 1.22±0.20(Predicted)
color: white
Sensitive: air sensitive
InChIKey: QCHAVHXSBZARBO-UHFFFAOYSA-N

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3
TSCA: No
HS Code: 2934.99.4400

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 668206
Product name: (R)-(?)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)dimethylamine
Purity: 97%
Packaging: 1g
Price: $55.4
Updated: 2023/06/20

TCI Chemical

Product number: D4992
Product name: (R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine
Purity: >98.0%(HPLC)(N)
Packaging: 1g
Price: $56
Updated: 2024/03/01

TCI Chemical

Product number: D4992
Product name: (R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine
Purity: >98.0%(HPLC)(N)
Packaging: 5g
Price: $180
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1232
Product name: (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS
Packaging: 250mg
Price: $29
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1232
Product name: (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS
Packaging: 1g
Price: $85
Updated: 2024/03/01

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(R)-MONOPHOS Chemical Properties,Usage,Production

Reaction

Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.

Uses

DSM MonoPhos Family of Highly Efficient Privileged Ligands

(R)-MONOPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-MONOPHOS Suppliers

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View Lastest Price from (R)-MONOPHOS manufacturers

R&D Scientific Inc.

Product: N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 157488-65-8
Price: US $3800.00/Kg
Min. Order: 1Kg
Purity: 97
Supply Ability: 500 Kg
Release date: 2024-07-11

Henan Aochuang Chemical Co.,Ltd.

Product: (r)-(-)-(3,5-dioxa-4-phosphacyclohepta(2,1-a 157488-65-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-30

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R)-()-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)dimethylamine 157488-65-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

157488-65-8, (R)-MONOPHOSRelated Search:

3,4-a']dinaphthalen-4-yl)dimethylamine (R)-MONOPHOS (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE (11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D:1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE, KANATA PURITY (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(R)-(-)-[4-N,N-Dimethylamino]dinaphtho[2.1-d:1'.2'-f][1.3.2]dioxaphosphepine(R)-monophos]

(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

3,4-a']dinaphthalen-4-yl)dimethylamine,min.97%(R)-MONOPHOS

(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS

3,4-a']dinaphthalen-4-yl)dimethylamine

(R)-()-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]di-naphthalen-4-yl)dimethylamine,(R)-Monophos

3,4-a']dinaphthalen

3,4-a']dinaphthalen-4-yl)[(1S)-1-phenylethyl]-aMine

3,4-a']dinaphthalen-4-yl)dipropylaMine

3,4-a']dinaphthalen-4-yl)Morpholine

3,4-a']dinaphthalen-4-yl)piperidine

R-8,9,10,11,12,13,14,15,Octahydro-3,5-dioxa-4-phosphacyclohepta[2,1-a

(R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diMethylaMine 97%

(R)-N,N-DiMethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine

3,4-a']dinaphthalen-4-yl)dimethylamine,97% (R)-MONOPHOS

(11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

97% (R)-MONOPHOS

-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin-4-amine,99%e.e.

(R)-(-)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE

(R)-(-)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE

(S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE

(R)-MONOPHOS

(S)-MONOPHOS

3,4-a']dinaphthalen-4-yl)dimethylamine, R-MonoPhos

(11bR)-N,N-Dimethyl-dinaphtho[2,1-9d8:1%',21'-5f]7[418,38,-26]5d-i8ox

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-dimethyl-, (11bR)-

(R)-(-)-[4-N,N-Dimethylamino]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinapht...

(R)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

3,4-a']dinaphthalen-4-yl)dimethylamine, R-MonoPhos

(11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

157488-65-8

422509-53-5

Chiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis

Privileged Ligands

DSM MonoPhos Phosphoramidites

SF160006

Chiral Phosphine

CPN