ChemicalBook > CAS DataBase List > Methyl nitroacetate

Methyl nitroacetate

Product Name
Methyl nitroacetate
CAS No.
2483-57-0
Chemical Name
Methyl nitroacetate
Synonyms
Methyl 2-nitroacetate;METHYL NITROACETATE;Methyl nitrozcetate;methyl2-nitroacetate;Methyl a-nitroacetate;MethylNitroacetate>Methylnitroacetate,98%;METHYL ALFA NITROACETATE;nitro-aceticacimethylester;NITROACETIC ACID METHYL ESTER
CBNumber
CB2722496
Molecular Formula
C3H5NO4
Formula Weight
119.08
MOL File
2483-57-0.mol
More
Less

Methyl nitroacetate Property

Boiling point:
195-198 °C (lit.)
Density 
1.294 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.425(lit.)
Flash point:
221 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Miscible with ethanol, ether and most organic solvents.
form 
clear liquid
pka
5.73±0.29(Predicted)
color 
Colorless to Light yellow
Sensitive 
Light Sensitive
BRN 
1758670
InChIKey
ALBSWLMUHHZLLR-UHFFFAOYSA-N
CAS DataBase Reference
2483-57-0(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, nitro-, methyl ester(2483-57-0)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
2
RTECS 
AJ1093000
8
HS Code 
29161995
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
366463
Product name
Methyl nitroacetate
Purity
98%
Packaging
5g
Price
$256.2
Updated
2024/03/01
Sigma-Aldrich
Product number
366463
Product name
Methyl nitroacetate
Purity
98%
Packaging
1g
Price
$119
Updated
2023/06/20
TCI Chemical
Product number
N0656
Product name
Methyl Nitroacetate
Purity
>97.0%(GC)
Packaging
5g
Price
$94
Updated
2024/03/01
TCI Chemical
Product number
N0656
Product name
Methyl Nitroacetate
Purity
>97.0%(GC)
Packaging
25g
Price
$315
Updated
2024/03/01
Alfa Aesar
Product number
L18950
Product name
Methyl nitroacetate, 98%
Packaging
2g
Price
$68.65
Updated
2024/03/01
More
Less

Methyl nitroacetate Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

Uses

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

Synthesis Reference(s)

The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606

Methyl nitroacetate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Methyl nitroacetate Suppliers

TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23662
Advantage
75
More
Less

View Lastest Price from Methyl nitroacetate manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
Methyl nitroacetate 2483-57-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-22
Career Henan Chemical Co
Product
Methyl nitroacetate 2483-57-0
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
as request
Release date
2018-12-25

2483-57-0, Methyl nitroacetateRelated Search:


  • NITROACETIC ACID METHYL ESTER
  • Methyl 2-nitroacetate
  • Methyl a-nitroacetate
  • methyl2-nitroacetate
  • nitro-aceticacimethylester
  • METHYL ALFA NITROACETATE
  • METHYL NITROACETATE
  • Methylnitroacetate,98%
  • Methyl nitrozcetate
  • Acetic acid, 2-nitro-,Methyl ester
  • Nitroacetic acid methyl ester, Methyl 2-nitroethanoate
  • MethylNitroacetate&gt
  • 2483-57-0
  • NO2CH2COOCH3
  • O2NCH2CO2CH3
  • Building Blocks
  • C2 to C5
  • Carbonyl Compounds
  • Esters
  • Organic Building Blocks
  • Acetics acid and esters
  • Acids and Derivatives
  • C2 to C5
  • Carbonyl Compounds
  • Esters