Methyl nitroacetate
- Product Name
- Methyl nitroacetate
- CAS No.
- 2483-57-0
- Chemical Name
- Methyl nitroacetate
- Synonyms
- Methyl 2-nitroacetate;METHYL NITROACETATE;Methyl nitrozcetate;methyl2-nitroacetate;Methyl a-nitroacetate;MethylNitroacetate>Methylnitroacetate,98%;METHYL ALFA NITROACETATE;nitro-aceticacimethylester;NITROACETIC ACID METHYL ESTER
- CBNumber
- CB2722496
- Molecular Formula
- C3H5NO4
- Formula Weight
- 119.08
- MOL File
- 2483-57-0.mol
Methyl nitroacetate Property
- Boiling point:
- 195-198 °C (lit.)
- Density
- 1.294 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.425(lit.)
- Flash point:
- 221 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Miscible with ethanol, ether and most organic solvents.
- form
- clear liquid
- pka
- 5.73±0.29(Predicted)
- color
- Colorless to Light yellow
- Sensitive
- Light Sensitive
- BRN
- 1758670
- InChI
- InChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
- InChIKey
- ALBSWLMUHHZLLR-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C[N+]([O-])=O
- CAS DataBase Reference
- 2483-57-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Acetic acid, nitro-, methyl ester(2483-57-0)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- WGK Germany
- 2
- RTECS
- AJ1093000
- F
- 8
- HS Code
- 29161995
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 366463
- Product name
- Methyl nitroacetate
- Purity
- 98%
- Packaging
- 5g
- Price
- $256.2
- Updated
- 2024/03/01
- Product number
- 366463
- Product name
- Methyl nitroacetate
- Purity
- 98%
- Packaging
- 1g
- Price
- $119
- Updated
- 2023/06/20
- Product number
- N0656
- Product name
- Methyl Nitroacetate
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $94
- Updated
- 2024/03/01
- Product number
- N0656
- Product name
- Methyl Nitroacetate
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $315
- Updated
- 2024/03/01
- Product number
- L18950
- Product name
- Methyl nitroacetate, 98%
- Packaging
- 2g
- Price
- $68.65
- Updated
- 2024/03/01
Methyl nitroacetate Chemical Properties,Usage,Production
Chemical Properties
clear yellow liquid
Uses
Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.
Synthesis Reference(s)
The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606
Methyl nitroacetate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl nitroacetate Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from Methyl nitroacetate manufacturers
- Product
- Methyl nitroacetate 2483-57-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-22
- Product
- Methyl nitroacetate 2483-57-0
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 95%-99%
- Supply Ability
- as request
- Release date
- 2018-12-25