Ethyl nitroacetate

Product Name: Ethyl nitroacetate
CAS No.: 626-35-7
Chemical Name: Ethyl nitroacetate
Synonyms: NSC 42302;JACS-626-35-7;2-nitrobutanoate;Ethlnitroacetate;Ethyl nitrocetate;ETHYL NITROACETATE;NITRO ETHYL ACETATE;EthylNitroacetate>Ethylnitroacetate,97%;Ethyl nitroacetate,98%
CBNumber: CB1175310
Molecular Formula: C4H7NO4
Formula Weight: 133.1
MOL File: 626-35-7.mol

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Ethyl nitroacetate Property

Boiling point:: 105-107 °C/25 mmHg (lit.)
Density: 1.199 g/mL at 25 °C (lit.)
refractive index: n20/D 1.424(lit.)
Flash point:: 198 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka: pK1:5.85 (25°C)
form: Liquid
color: Clear colorless to slightly yellow
Water Solubility: Slightly soluble in water. Soluble in chloroform and ethyl acetate.
BRN: 1210027
InChIKey: FTKASJMIPSSXBP-UHFFFAOYSA-N
CAS DataBase Reference: 626-35-7(CAS DataBase Reference)
NIST Chemistry Reference: Acetic acid, nitro-, ethyl ester(626-35-7)
EPA Substance Registry System: Acetic acid, nitro-, ethyl ester (626-35-7)

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Safety

Hazard Codes: Xi
Risk Statements: 38
Safety Statements: 23-24/25-37
WGK Germany: 2
RTECS: AJ1074000
Hazard Note: Irritant
TSCA: T
HazardClass: IRRITANT, KEEP COLD
HS Code: 29159080

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 192333
Product name: Ethyl nitroacetate
Purity: 97%
Packaging: 5g
Price: $43.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 192333
Product name: Ethyl nitroacetate
Purity: 97%
Packaging: 25g
Price: $166
Updated: 2024/03/01

TCI Chemical

Product number: N0657
Product name: Ethyl Nitroacetate
Purity: >95.0%(GC)
Packaging: 5g
Price: $56
Updated: 2024/03/01

TCI Chemical

Product number: N0657
Product name: Ethyl Nitroacetate
Purity: >95.0%(GC)
Packaging: 25g
Price: $164
Updated: 2024/03/01

Alfa Aesar

Product number: A14433
Product name: Ethyl nitroacetate, 97%
Packaging: 5g
Price: $63.65
Updated: 2024/03/01

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Ethyl nitroacetate Chemical Properties,Usage,Production

Chemical Properties

clear colourless to slightly yellow liquid

Uses

Ethyl nitroacetate has been used in the synthesis of γ-oxoacids via Michael addition reaction with α,β-unsaturated ketones, fuctionalization of C4-position on pyrimidine and C6-position on 2?-deoxyguanosine to produce novel nucleosides, facile synthesis of α,α-diisobutylglycine, synthesis of DL-4,4-difluoroglutamic acid. It is also used as an intermediate in the preparation of unsubstituted amino acids.

Uses

Ethyl Nitroacetate is an ester of nitrocarboxylic acid used as an intermediate in the preparation of unsubstituted amino acids.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 1208, 1994 DOI: 10.1021/jo00084a047

Purification Methods

Purify the ester by repeated distillation. IR:max 1748 (CO2), 1570 and 1337 (NO2), and 800cm-1 [Haszeldine J Chem Soc 2525 1953]. The hydrazine salt crystallises from 95% EtOH or MeOH as yellow crystals m 104-105o [Ungnade & Kissinger J Org Chem 22 1661 1957, Emmons & Freeman J Am Chem Soc 77 4391 1955]. [Beilstein 2 IV 537.]

Ethyl nitroacetate Preparation Products And Raw materials

Raw materials

Preparation Products

4-HYDROXY-5-NITROPYRIMIDINE 4-BROMO-2-(TRIFLUOROMETHYL)-5-METHOXYPYRIDINE 3-FLUORO-DL-TYROSINE

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Ethyl nitroacetate Suppliers

Americas 1 Austria 1 Belgium 2 Canada 1 China 221 Europe 2 Germany 6 India 8 Japan 4 Jordan 1 Slovakia 1 Switzerland 4 United Kingdom 14 United States 34 Global 300

Shanghai hanchen new material technology co., ltd

Tel: 13564554711
Email: 26639560@qq.com
Country: China
ProdList: 126
Advantage: 58

Shandong Meiao Huawei Technology Co., LTD

Tel: 18595278766 18595278766
Email: mahw@mayowell.com
Country: China
ProdList: 49
Advantage: 58

Shanghai Jiuju Chemical Technology Co. LTD

Tel: 021-54290889 18117093889
Email: 1261932215@qq.com
Country: China
ProdList: 394
Advantage: 58

AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: 15928766785 15928766785
Fax: QQ961458712
Email: wupengcheng@astatech.cn
Country: China
ProdList: 1995
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

PharmaBlock Sciences (Nanjing),Inc.

Tel: 400-0255188 4000255188
Fax: 86-025-86918232
Email: sales@pharmablock.com
Country: China
ProdList: 4986
Advantage: 55

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

future industrial shanghai co., ltd

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: sales@jonln.com
Country: China
ProdList: 1998
Advantage: 65

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TAIYUAN RHF CO.,LTD.

Tel: +86 351 7031519
Fax: +86 351 7031519
Email: sales@RHFChem.com
Country: China
ProdList: 2341
Advantage: 56

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View Lastest Price from Ethyl nitroacetate manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: Ethyl nitroacetate 626-35-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-09-06

Hebei Guanlang Biotechnology Co., Ltd.

Product: Ethyl nitroacetate 626-35-7
Price: US $10.00/PCS
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-03-11

Honest Joy Holdings Limited

Product: Ethyl nitroacetate 626-35-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.1%
Supply Ability: 100 tons
Release date: 2022-02-21

626-35-7, Ethyl nitroacetateRelated Search:

Ethanol Ethyl acetate Ethylparaben ISOXADIFEN-ETHYL 2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER Ethyl hydrazinoacetate hydrochloride Ethyl bromoacetate Ethyl phenylacetate Ethyl cyanoacetate Ethyl propiolate Ethyl acrylate ETHYL (METHYLTHIO)ACETATE Trinexapac-ethyl Diethyl nitromalonate Methyl vanillate Cadmium diethyldithiocarbamate Methyl nitroacetate Bromoacetaldehyde diethyl acetal

Acetic Acid Nitro Ethyl Ester

nitro-aceticaciethylester

NITROACETIC ACID ETHYL ESTER

NITRO ETHYL ACETATE

ETHYL NITROACETATE

Ethlnitroacetate

wEthyl nitroacetate, 97%

Ethylnitroacetate,97%

Ethyl nitroacetate 97%

2-nitrobutanoate

Ethyl nitroacetate,98%

2-Nitroacetic Acid Ethyl Ester

NSC 42302

Ethyl nitrocetate

Nitroacetic acid ethyl ester, Ethyl 2-nitroethanoate

Ethyl nitroacetate, 95+%

JACS-626-35-7

EthylNitroacetate&gt

Acetic acid, 2-nitro-, ethyl ester

626-35-7

NO2CH2CO2C2H5

O2NCH2CO2CH2CH3

O2NCH2COOC2H5

Carbonyl Compounds

C2 to C5

Building Blocks

Organic Building Blocks

Esters

Halogenated Heterocycles ,Quinolines

C2 to C5

Carbonyl Compounds

Esters