Methyl nitroacetate

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Methyl nitroacetate

Product Name: Methyl nitroacetate
CAS No.: 2483-57-0
Chemical Name: Methyl nitroacetate
Synonyms: Methyl 2-nitroacetate;METHYL NITROACETATE;Methyl nitrozcetate;methyl2-nitroacetate;Methyl a-nitroacetate;MethylNitroacetate>Methylnitroacetate,98%;METHYL ALFA NITROACETATE;nitro-aceticacimethylester;NITROACETIC ACID METHYL ESTER
CBNumber: CB2722496
Molecular Formula: C3H5NO4
Formula Weight: 119.08
MOL File: 2483-57-0.mol

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Methyl nitroacetate Property

Boiling point:: 195-198 °C (lit.)
Density: 1.294 g/mL at 25 °C (lit.)
refractive index: n20/D 1.425(lit.)
Flash point:: 221 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Miscible with ethanol, ether and most organic solvents.
form: clear liquid
pka: 5.73±0.29(Predicted)
color: Colorless to Light yellow
Sensitive: Light Sensitive
BRN: 1758670
InChI: InChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
InChIKey: ALBSWLMUHHZLLR-UHFFFAOYSA-N
SMILES: C(OC)(=O)C[N+]([O-])=O
CAS DataBase Reference: 2483-57-0(CAS DataBase Reference)
NIST Chemistry Reference: Acetic acid, nitro-, methyl ester(2483-57-0)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
WGK Germany: 2
RTECS: AJ1093000
F: 8
HS Code: 29161995

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 366463
Product name: Methyl nitroacetate
Purity: 98%
Packaging: 5g
Price: $256.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 366463
Product name: Methyl nitroacetate
Purity: 98%
Packaging: 1g
Price: $119
Updated: 2023/06/20

TCI Chemical

Product number: N0656
Product name: Methyl Nitroacetate
Purity: >97.0%(GC)
Packaging: 5g
Price: $94
Updated: 2024/03/01

TCI Chemical

Product number: N0656
Product name: Methyl Nitroacetate
Purity: >97.0%(GC)
Packaging: 25g
Price: $315
Updated: 2024/03/01

Alfa Aesar

Product number: L18950
Product name: Methyl nitroacetate, 98%
Packaging: 2g
Price: $68.65
Updated: 2024/03/01

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Methyl nitroacetate Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

Uses

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

Synthesis Reference(s)

The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606

Methyl nitroacetate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl nitroacetate manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: Methyl nitroacetate 2483-57-0
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-22

Career Henan Chemical Co

Product: Methyl nitroacetate 2483-57-0
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: as request
Release date: 2018-12-25

2483-57-0, Methyl nitroacetateRelated Search:

Methyl acetate Methyl glycolate Methylparaben Acetonitrile Methyl bromoacetate Methyl phenylacetate Basic Violet 1 Methyl cyanoacetate Methyl methoxyacetate Methanol Diethyl nitromalonate Ethyl nitroacetate Methyl acrylate Paraquat dichloride Kresoxim-methyl DIETHYL SUBERATE Methyl 4-CHLORO-3-NITROCOUMARIN

NITROACETIC ACID METHYL ESTER

Methyl 2-nitroacetate

Methyl a-nitroacetate

methyl2-nitroacetate

nitro-aceticacimethylester

METHYL ALFA NITROACETATE

METHYL NITROACETATE

Methylnitroacetate,98%

Methyl nitrozcetate

Acetic acid, 2-nitro-,Methyl ester

Nitroacetic acid methyl ester, Methyl 2-nitroethanoate

MethylNitroacetate&gt

2483-57-0

NO2CH2COOCH3

O2NCH2CO2CH3

Building Blocks

C2 to C5

Carbonyl Compounds

Esters

Organic Building Blocks

Acetics acid and esters

Acids and Derivatives

C2 to C5

Carbonyl Compounds

Esters