1,3-Butadiene

ChemicalBook > CAS DataBase List > 1,3-Butadiene

Product Name: 1,3-Butadiene
CAS No.: 106-99-0
Chemical Name: 1,3-Butadiene
Synonyms: BUTADIENE;Butadien;1,3-Butadien;Butadieen;PYRROLYLENE;1,3-butadine;DIVINYL;BUDIENE;BIVINYL;ERYTHRENE
CBNumber: CB2733269
Molecular Formula: C4H6
Formula Weight: 54.09
MOL File: 106-99-0.mol

Less

1,3-Butadiene Property

Melting point:: −109 °C(lit.)
Boiling point:: −4.5 °C(lit.)
Density: 0.62 g/mL at 20 °C(lit.)
vapor density: 1.9 (15 °C, vs air)
vapor pressure: 1863 mm Hg ( 21 °C)
refractive index: 1.4292
Flash point:: −105 °F
storage temp.: 0-6°C
solubility: water: soluble0.5g/L at 20°C
form: Colorless gas
color: Colorless to Almost colorless
explosive limit: 12%
Odor Threshold: 0.23ppm
Water Solubility: 735mg/L(25 ºC)
FreezingPoint: -108.91℃
Merck: 14,1509
BRN: 605258
Henry's Law Constant: (x 10^-2 atm?m³/mol): 6.3 at 25 °C (Hine and Mookerjee, 1975)
Exposure limits: TLV-TWA 10 ppm (～22 mg/m³) (ACGIH), 1000 ppm (OSHA and NIOSH); IDLH 20,000 ppm (NIOSH); A2–Suspected Human Carcinogen (ACGIH).
Stability:: Stable. Extremely flammable. May form explosive mixtures with air. Incompatible with strong oxidizing agents, copper, copper alloys. May contain stabilizer.
InChIKey: KAKZBPTYRLMSJV-UHFFFAOYSA-N
LogP: 1.99 at 20℃
CAS DataBase Reference: 106-99-0(CAS DataBase Reference)
IARC: 1 (Vol. Sup 7, 54, 71, 97, 100F) 2012
EPA Substance Registry System: 1,3-Butadiene (106-99-0)

Less

Safety

Hazard Codes: F+,T,F,N
Risk Statements: 45-46-12-67-65-63-48/20-36/38-11-62-51/53-38
Safety Statements: 53-45-62-46-36/37-26-61-33-16
RIDADR: UN 1010 2.1
WGK Germany: 2
RTECS: EI9275000
F: 4.5-31
Autoignition Temperature: 788 °F
Hazard Note: Extremely Flammable/Carcinogen
DOT Classification: 2.1 (Flammable gas)
HazardClass: 2.1
PackingGroup: II
HS Code: 29012410
Hazardous Substances Data: 106-99-0(Hazardous Substances Data)
Toxicity: LC₅₀ (inhalation) for mice 270 gm/m³/2-h, rats 285 gm/m³/4-h (quoted, RTECS, 1985).
IDLA: 2,000 ppm (10% LEL)

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H220Extremely flammable gas

H280Contains gas under pressure; may explode if heated

H340May cause genetic defects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P377Leaking gas fire: Do not extinguish, unless leak can be stopped safely.

P410+P403Protect from sunlight. Store in a well-ventilated place.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 295035
Product name: 1,3-Butadiene
Purity: ≥99%
Packaging: 100g
Price: $233
Updated: 2024/03/01

Sigma-Aldrich

Product number: 295035
Product name: 1,3-Butadiene
Purity: ≥99%
Packaging: 1kg
Price: $722
Updated: 2024/03/01

TCI Chemical

Product number: B4358
Product name: 1,3-Butadiene (ca. 15% in Hexane)
Packaging: 100mL
Price: $84
Updated: 2024/03/01

TCI Chemical

Product number: B4358
Product name: 1,3-Butadiene (ca. 15% in Hexane)
Packaging: 500mL
Price: $248
Updated: 2024/03/01

Sigma-Aldrich

Product number: 695904
Product name: 1,3-Butadiene solution
Purity: 15wt. % in hexane
Packaging: 250g
Price: $601
Updated: 2024/03/01

Less

1,3-Butadiene Chemical Properties,Usage,Production

Description

1,3-Butadiene is a simple conjugated diene. It is a colourless gas with a mild aromatic or gasoline-like odour and incompatible with phenol, chlorine dioxide, copper, and crotonaldehyde. The gas is heavier than air and may travel along the ground; distant ignition is possible. It is an important industrial chemical used as a monomer in the production of synthetic rubber. Most butadiene is polymerised to produce synthetic rubber. While polybutadiene itself is a very soft, almost liquid, material, polymers prepared from mixtures of butadiene with styrene or acrylonitrile, such as ABS, are both tough and elastic. Styrene–butadiene rubber is the material most commonly used for the production of automobile tyres. Smaller amounts of butadiene are used to make nylon via the intermediate adiponitrile, other synthetic rubber materials such as chloroprene, and the solvent sulpholane. Butadiene is used in the industrial production of cyclododecatriene via a trimerisation reaction.

1,3-Butadiene structure

Chemical Properties

Butadiene is a gas, b.p. -4°C.

Physical properties

Colorless gas with a mild, aromatic or gasoline-like odor. Experimentally determined detection and recognition odor threshold concentrations were 1.0 mg/m³ (0.45 ppm_v) and 2.4 mg/m³ (1.1 ppmv), respectively (Hellman and Small, 1974).

Uses

One major use of 1,3-butadiene has been in the making of synthetic rubber. Among the types of synthetic rubber made with 1,3-butadiene are styrene-butadiene and nitrile-butadiene rubbers. Cis-polybutadiene is also an extender and substitute for rubber, and trans-polybutadiene is a type of rubber with unusual properties.
1,3-Butadiene is also used extensively for various polymerizations in manufacturing plastics. It combines with activated olefins in the Diels-Alder reaction to give hydroaromatic hydrocarbons. 1,3-Butadiene undergoes 1,4 cyclization with reactants containing sulfur, oxygen, and nitrogen.

Uses

1,3-Butadiene is a petroleum product obtainedby catalytic cracking of naphtha orlight oil or by dehydrogenation of buteneor butane. It is used to produce butadiene–styrene elastomer (for tires), syntheticrubber, thermoplastic elastomers, foodwrapping materials, and in the manufactureof adiponitrile. It is also used forthe synthesis of organics by Diels–Aldercondensation.

Uses

Synthetic elastomers (styrene-butadiene, polybutadiene, neoprene, nitriles), ABS resins, chemical intermediate.
1,3-Butadiene can undergo a four-component coupling reaction with aryl Grignard reagents, and alkyl fluorides in the presence of nickel catalyst to form 1,6-octadiene carbon compound substituted with alkyl and aryl groups at the 3- and 8-positions.
1,3-Butadiene is a useful diene for Diels Alder reaction.
It may be used in the synthesis of the following:

1-Silyl-substituted 1,3-butadienes, by [RuHCl(CO)(PCy3)2]-catalyzed silylative coupling of terminal (E)-1,3-dienes with vinylsilanes.
Synthetic rubber and thermoplastic resins.
Disilylated dimers by reacting with chlorosilanes.
Octa-2,7-dien-1-ol via palladium catalyzed-hydrodimerization.

Preparation

Butadiene is obtained when n-butenes are dehydrogenated:

n-Butenes are mostly obtained from the catalytic cracking operations carried out on various petroleum fractions; thermal cracking processes usually give low yields of butenes. The dehydrogenation of n-butenes is carried out by mixing the feed with steam (which lowers the partial pressures of the reactants) and passing over a catalyst such as mixed calcium/nickel phosphate stabilized with chromium oxide at about 650??C.

Definition

ChEBI: 1,3-Butadiene is a butadiene with unsaturation at positions 1 and 3. It is a chemical made from the processing of petroleum. About 75% of the manufactured 1,3-butadiene is used to make synthetic rubber. Synthetic rubber is widely used for tires on cars and trucks.

Production Methods

Except for a small amount of butadiene produced by the oxydehydrogenation of n-butane, most of butadiene is produced commercially as a by-product of ethylene production during the steam cracking of hydrocarbon streams. It is separated and purificated from other components by extractive distillation, using acetonitrile and dimethylformamide as solvents.

General Description

1,3-Butadiene is a colorless gas with a mild, aromatic, gasoline-like odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. It must be shipped inhibited as butadiene is liable to polymerization. If polymerization occurs in the container, It may violently rupture. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. It is used to make synthetic rubber and plastics, and to make other chemicals.

Air & Water Reactions

Highly flammable. In contact with air, butadiene may form violently explosive peroxides, which can be exploded by mild heat or shock. Solid butadiene absorbs enough oxygen at sub atmospheric pressures to make 1,3-BUTADIENE explode violently when heated just above its melting point [Ind. Eng. Chem. 51:733 1959].

Reactivity Profile

A colorless gas, 1,3-BUTADIENE can react with oxidizing reagents. Upon long exposure to air 1,3-BUTADIENE forms explosive peroxides. They are sensitive to heat or shock; sudden polymerization may occur [Scott, D. A., Chem. Eng. News, 1940, 18, p.404]. Butadiene polyperoxides are insoluble in liquefied butadiene (m. p. -113° C, b. p. -2.6° C) and progressively separate leading to local concentration build up. Self-heating from a spontaneous decomposition will lead to explosion [Hendry, D. G. et al., Ind. Eng. Chem., 1968, 7, p. 136, 1145]. Explodes on contact with aluminum tetrahydroborate, potentially explosive reaction with chlorine dioxide (peroxide) and crotonaldehyde (above 180° C). Reaction with sodium nitrite forms a spontaneously flammable product [Sax, 9th ed., 1996, p. 539].

Hazard

A confirmed carcinogen. Irritant in high concentration. Highly flammable gas or liquid, explosive limits in air 2–11%. May form explosive peroxides on exposure to air. Must be kept inhibited during storage and shipment. Inhibitors often used are di-n-butylamine or phenyl-β-naphthylamine. Storage is usually under pressure or in insulated tanks <35F (<1.67C).

Health Hazard

The toxicity of 1,3-butadiene has been foundto be very low in humans and animals. It isan asphyxiant. In humans, low toxic effectsmay be observed at exposure to 2000 ppmfor 7 hours. The symptoms may be hallucinations,distorted perception, and irritation ofeyes, nose, and throat. Higher concentrationsmay result in drowsiness, lightheadedness,and narcosis. High dosages of 1,3-butadienewas toxic to animals by inhalation and skincontact. General anesthetic effects and respiratorydepression were noted. Concentrationsof 25–30% may be lethal to rats and rabbits.Contact with the liquefied gas can cause burnand frostbite.
Exposure to 1,3-butadiene caused cancersin the stomach, lungs, and blood in ratsand mice. It is suspected to be a humancarcinogen. It is a mutagen and a teratogen.

Fire Hazard

Behavior in Fire: Vapors heavier than air and may travel a considerable distance to a source of ignition and flashback. Containers may explode in a fire due to polymerization.

Flammability and Explosibility

Extremely flammable

Biochem/physiol Actions

Environmental carcinogen. Induces cardiac hemangiosarcomas in mice.

Materials Uses

1,3-Butadiene is noncorrosive and may be used with any common metals. Steel is recommended for tanks and piping in butadiene service by some authorities. If used with plastics, compatibility must be confirmed. Welded rather than threaded connections are similarly recommended because 1,3-butadiene tends to leak through even extremely small openings. If threaded connections are used, Schedule 80 pipe should be used. Before being exposed to 1,3-butadiene that is not inhibited, iron surfaces should be treated with an appropriate reducing agent such as sodium nitrite because polymerization is accelerated by oxygen (even if present as in ferrous oxide), as well as by heat.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. An experimental teratogen. Mutation data reported. Inhalation of high concentrations can cause unconsciousness and death. Human systemic effects by inhalation: cough, hallucinations, dstorted perceptions, changes in the visual field and other

Potential Exposure

Tumorigen,Mutagen; Reproductive Effector; Human Data. 1,3-Butadiene is used chiefly as the principal monomer in themanufacture of many types of synthetic rubber and otherchemicals. Butadiene is finding increasing usage in the formation of rocket fuels, plastics, and resins.

Physiological effects

If inhaled in high concentrations, 1,3-butadiene has an anesthetic or mild narcotic action, which appears to vary with individuals. Inhalation of a I percent concentration in air has been reported to have had no effect on the respiration or blood pressure of individuals. However, such exposure may cause the pulse rate to quicken and give a sensation of prickling and dryness in the nose and mouth. Inhalation in higher concentrations has brought on blurring of vision and nausea in some persons. Inhalation in excessive amounts leads to progressive anesthesia, irritation of eyes, lungs, and nasal passages. Exposure to a 25 percent concentration for 23 minutes proved fatal in one instance. No cumulative action on the blood, lungs, liver, or kidneys has been reported. Because 1,3-butadiene liquid evaporates rapidly, prolonged contact between liquid butadiene and the skin causes freezing of the tissue. Delayed skin bums may result if liquid butadiene is allowed to remain trapped in clothing or in shoes.
OSHA has concluded that there is strong evidence that workplace exposure to 1,3-butadiene poses an increased risk of death from cancers of the Iymphokematopoietic system. ACGIH has classified 1,3-butadiene as a "suspected human carcinogen" . The National Toxicology Program has classified 1,3-butadiene as showing clear evidence of carcinogenicity.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for atleast 15 min, occasionally lifting upper and lower lids.Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and washimmediately with soap and water. Seek medical attentionimmediately. If this chemical has been inhaled, removefrom exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. If frostbite has occurred, seek medicalattention immediately; do NOT rub the affected areas orflush them with water. In order to prevent further tissuedamage, do NOT attempt to remove frozen clothing fromfrostbitten areas. If frostbite has NOT occurred, immediately and thoroughly wash contaminated skin with soapand water.

Carcinogenicity

1,3-Butadiene is known to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in humans, including epidemiological and mechanistic studies. 1,3-Butadiene was first listed in the Fifth Annual Report on Carcinogens in 1989 as reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals. The listing was revised to known to be a human carcinogen in the Ninth Report on Carcinogens in 2000.

Source

Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The gas-phase emission rate of 1,3-butadiene was 177 mg/kg of pine burned. Emission rates of 1,3-butadiene were not measured during the combustion of oak and eucalyptus.

Environmental Fate

Surface Water. The estimated volatilization half-life of 1,3-butadiene in a model river 1 m deep, flowing 1 m/sec and a wind speed of 3 m/sec is 3.8 h (Lyman et al., 1982).
Photolytic. The following rate constants were reported for the reaction of 1,3-butadiene and OH radicals in the atmosphere: 6.9 x 10^-11 cm³/molecule·sec (Atkinson et al., 1979) and 6.7 x 10^-11 cm³/molecule·sec (Sablji? and Güsten, 1990). Atkinson and Carter (1984) reported a rate constant of 6.7–8.4 x 10^-11 cm³/molecule·sec for the reaction of 1,3-butadiene and ozone in the atmosphere. Photooxidation reaction rate constants of 2.13 x 10^-13 and 7.50 x 10^-18 cm³/molecule·sec were reported for the reaction of 1,3-butadiene and NO3 (Benter and Schindler, 1988; Sablji? and Güsten, 1990). The half-life in air for the reaction of 1,3-butadiene and NO3 radicals is 15 h (Atkinson et al., 1984a).
Chemical/Physical. Will polymerize in the presence of oxygen if no inhibitor is present (Hawley, 1981).

storage

1,3-Butadiene is stored in a cool and wellventilatedlocation separated from combustibleand oxidizing substances. Smallamounts of stabilizers, such as o-dihydroxybenzene,p-tert-butylcatechol, or aliphaticmercaptans, are added to prevent its polymerizationor peroxides formation. The cylindersare stored vertically and protected againstphysical damage.

Shipping

Butadiene, inhibited, requires a shipping label of“FLAMMABLE GAS.” This material falls in Hazard Class2.1 and does not have an assigned Packing Group.[19, 20]

Toxicity evaluation

Butadiene is a gas under normal environmental conditions with limited water solubility (735 mg l^-1 at 25°C). Butadiene released to the atmosphere will remain there with very small amounts being distributed to water and soil. In air, butadiene will be removed by reaction with photochemically produced hydroxyl radicals (5.6-h half-life), nitrate radicals (15-h half-life), and ozone (1.5-day half-life). When released to water, butadiene will be removed by volatilization to air (Henry’s law constant of 7460 Pam3 mol^-1), biodegradation (aerobic half-life of 15 days), and reaction with singlet oxygen. Based on its estimated organic carbon partition coefficient (Koc of 288), butadiene will not exhibit significant adsorption to soil or suspended particulate matter; its biodegradation half-life in soil is estimated to be 30 days. Due to volatilization to air and degradation in soil, butadiene is not expected to leach to groundwater. As butadiene is readily metabolized, it is not expected to pose a significant bioaccumulation hazard.

Incompatibilities

Self-reactive. May form explosive peroxides on exposure to air. High heat can cause a violent chemical reaction that will cause container rupture. Fires,explosions, or hazardous polymerization may result fromcontact with air, strong oxidizers, strong acids, ozone, rust,nitrogen dioxide, phenol, chlorine dioxide, crotonaldehyde,or a free radical polymerization initiator, such as hydroquinone. Unsafe in contact with acetylide-forming materials,such as monel, copper, and copper alloys (piping material for this gas must not contain more than 63% copper). Addinhibitor (such as tributylcatechol) to prevent self-polymerization and monitor to insure effective levels are maintainedat all times. May accumulate static electrical charges, andmay cause ignition of its vapors.

Waste Disposal

Disposal of l,3-butadiene by venting, incineration, using a suitable flare system, or by other means may be subject to permitting by federal, state, provincial, or local regulations. Persons involved with disposal of 1,3-butadiene should check with the environmental authorities having jurisdiction to determine the applicability of permitting regulations to disposal activities.

GRADES AVAILABLE

1,3-Butadiene is available for commercial and industrial use in various grades having much the same component proportions from one producer to another.
All grades contain approximately lIS ppm of a polymerization inhibitor, such as tertiary- butylcathechol. Distillation or washing with dilute caustic solution is used for removing the inhibitor when necessary.

1,3-Butadiene Preparation Products And Raw materials

Raw materials

Acetonitrile Nitrogen Toluene Calcium carbide n-Butane PETROLEUM ETHER

Preparation Products

Cross-linking agent Carboxy styrene-butadiene latex Methacrylonitrile 1-BUTENE 1,2,3,6-Tetrahydrophthalic anhydride modified filling agent SBR 5-ETHYLIDENE-2-NORBORNENE Muscone N,N,N',N'-TETRAMETHYL-2-BUTENE-1,4-DIAMINE 2-(2-CHLOROETHOXY)-BENZENESULFONAMIDE CYCLODODECANE VITAMIN K4 Sulfolane butadiene-styrene latex Polyvinylpyrrolidone 4-Vinylcyclohexene dioxide 3-SULFOLENE Captan Menadione Nitrile rubber NBR cis-1,2,3,6-Tetrahydrophthalic anhydride Maleic hydrazide Adiponitrile 1,2,3,4-Tetrabromobutane POLYBUTADIENE DIACRYLATE Hexamethylenediamine 1,2,5,6,9,10-Hexabromocyclododecane Styrene Butadiene Rubber DOWEX(R) 1X8 Dodecanedioic acid 2,4,4-TRIMETHYL-1-PENTENE ABS Resins 2-BUTANOL FUSEL OIL Cyclododeca-1,5,9-triene IRONE butadiene resin emulsion LHYJ-DS50 Ti(Co)Ziegler catalyst 1,4-HEXADIENE N-Hydroxymethyl-3,4,5,6-tetrahydrophthalimide

Less

1,3-Butadiene Suppliers

Americas 1 Australia 2 Belgium 2 Brazil 1 Canada 5 China 116 Czech Republic 1 Egypt 1 Europe 5 France 2 Germany 10 Hungary 1 India 17 Indonesia 1 Iran 1 Italy 2 Japan 6 Malaysia 1 Mexico 1 Poland 2 Russia 1 Saudi Arabia 1 Serbia 1 Singapore 2 South Korea 7 Spain 1 Switzerland 1 Thailand 3 The Netherlands 2 United Kingdom 7 United States 44 Global 248

Wuhan eastop Technology Co., ltd.6

Tel: 027-027-87382885 18086641195
Fax: 027-87382885
Email: service@isotopechina.com
Country: China
ProdList: 155
Advantage: 58

Central China Special Gas (CCSG) Co., Ltd

Tel: 0734-8755555 15674722888
Fax: 0734-8123618
Email: lyq@ccsg.cn
Country: China
ProdList: 281
Advantage: 58

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15848
Advantage: 69

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12426
Advantage: 60

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32344
Advantage: 50

BEST-REAGENT

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11726
Advantage: 57

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9823
Advantage: 79

Spectrum Chemical Manufacturing Corp.

Tel: 021-021-021-67601398-809-809-809 15221380277
Fax: 021-57711696
Email: marketing_china@spectrumchemical.com
Country: China
ProdList: 9664
Advantage: 60

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9725
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22519
Advantage: 55

Wuxi Zhongkun Biochemical Technology Co., Ltd.

Tel: 0510-85629785 18013409632
Fax: 051085625359
Email: sales@reading-chemicals.com
Country: China
ProdList: 15185
Advantage: 58

Shanghai YuLue Chemical Co., Ltd.

Tel: 021-60345187 13671753212
Fax: 021-34702061
Email: lzz841106@aliyun.com
Country: China
ProdList: 10287
Advantage: 55

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 15878
Advantage: 55

Shanghai Song Yuan Chemical Technology Co., Ltd.

Tel: 010-1234567 18521000990
Fax: 86-021-33275113
Email: sonyuanchemical@163.com
Country: China
ProdList: 6490
Advantage: 50

Chizhou Kailong Import and Export Trade Co., Ltd.

Tel
Fax: -
Email: xg01_gj@163.com
Country: China
ProdList: 9503
Advantage: 50

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51471
Advantage: 80

Infinity SCI

Tel: 400-400-1062016 17800804092
Email: admin@infsci.com
Country: China
ProdList: 720
Advantage: 55

Hangzhou Dingyan Chem Co., LTD

Tel: 0571-0571-87157530-8001-8003 18008611859
Fax: 0571-87156470
Email: sales@dingyanchem.com
Country: China
ProdList: 1997
Advantage: 58

Shanghai wechem chemical co., ltd

Tel: 18824865657
Fax: 021-6192 7501
Email: joey.lin@wechem.cn
Country: China
ProdList: 506
Advantage: 58

Grader reagent

Tel: 18221735425
Email: sales@xinpingchem.com
Country: China
ProdList: 9951
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2886750 13927877953
Fax: 0751-2886750
Email: 3005811397@qq.com
Country: China
ProdList: 13374
Advantage: 58

AoboRui (Tianjin) Co., Ltd.

Tel: 022-65675308 18310521067
Fax: QQ:2722718791
Email: 23034325@qq.com
Country: China
ProdList: 100
Advantage: 55

Zibo Zeno Pharmaceutical Technology Co., Ltd.

Tel: 0533-8800999 13515338377
Fax: 0533-7544744
Email: zenuoyiyao@163.com
Country: China
ProdList: 55
Advantage: 58

Shanghai Orgchem Co.,Ltd.

Tel: +86-21-5877 1921
Fax: +86-21-5877 1925
Email: info@chemofchina.com
Country: China
ProdList: 9661
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 021-021-52271985 17721149837
Fax: +86 (21) 52271987
Email: sales@9dingchem.com
Country: China
ProdList: 19806
Advantage: 60

Shanghai BaiShun Biological Technology Co., Ltd

Tel: 021-37581181
Fax: 021-57456066
Email: sales@chem-mall.com
Country: China
ProdList: 10335
Advantage: 58

Jiaxing Deyi Chemical Co., Ltd.

Tel: 86-0573-85866609 13325730825
Fax: 0573-85866609
Email: 945717149@qq.com
Country: China
ProdList: 7928
Advantage: 58

Rhawn Reagent

Tel: 400-400-1332688 18019345275
Fax: 400-133-2688
Email: amy@rhawn.cn
Country: China
ProdList: 15503
Advantage: 58

3A Chemicals

Tel: 400-668-9898
Fax: 010-51582189
Email: service@3achem.com
Country: China
ProdList: 20569
Advantage: 58

GUANGZHOU CHANGTHINKING IMP.&EXP.CO.,LTD

Tel: 020-37651955 13682223272
Fax: 020-87659730
Email: 173901442@qq.com
Country: China
ProdList: 695
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 400-400-400-9004166 18117592386
Email: 3007522982@qq.com
Country: China
ProdList: 52712
Advantage: 58

Hebei Mojin Biotechnology Co., Ltd

Tel: +8613288715578
Email: sales@hbmojin.com
Country: China
ProdList: 12453
Advantage: 58

ANHUI WITOP BIOTECH CO., LTD

Tel: +8615255079626
Email: eric@witopchemical.com
Country: China
ProdList: 23556
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: 0551-65418671
Fax: 0551-65418697
Email: sales@tnjchem.com
Country: China
ProdList: 34572
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: 571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: CHINA
ProdList: 52867
Advantage: 58

Shaanxi Dideu Medichem Co. Ltd

Tel: +86-029-89586680 +86-18192503167
Fax: +86-29-88380327
Email: 1026@dideu.com
Country: China
ProdList: 9507
Advantage: 58

Hebei Qige Biological Technology Co. Ltd

Tel: +86 +8618733132031
Country: CHINA
ProdList: 1313
Advantage: 58

Career Henan Chemica Co

Tel: +86-0371-86658258 15093356674;
Fax: 0371-86658258
Email: laboratory@coreychem.com
Country: China
ProdList: 30255
Advantage: 58

Hubei Jusheng Technology Co.,Ltd.

Tel: 18871490254
Fax: 027-59599243
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 28180
Advantage: 58

Hebei Guanlang Biotechnology Co., Ltd.

Tel: +86-19930503282
Fax: whatapp+8619930503282
Email: alice@crovellbio.com
Country: China
ProdList: 8822
Advantage: 58

Hubei xin bonus chemical co. LTD

Tel: 86-13657291602
Fax: 027-59338440
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 22968
Advantage: 58

Shanghai Yanze Chemical Co., Ltd.

Tel: 021-13773155751 19975071755
Email: 260924549@qq.com
Country: China
ProdList: 8518
Advantage: 58

Shanghai Jiegu Biotechnology Co., Ltd.

Tel: 021-51698675
Email: jiejiegroup@126.com
Country: China
ProdList: 4104
Advantage: 58

Shanghai jingkang bioengineering co., ltd.

Tel: 021-54721350 13524668266
Fax: 021-5
Email: 2881505714@qq.com
Country: China
ProdList: 7878
Advantage: 58

Henan Huawen Chemical Co., Ltd

Tel: 0370-0370-2059268 17550075363
Fax: QQ:2712427897
Email: 1124977392@qq.com
Country: China
ProdList: 1987
Advantage: 58

Shaanxi Dideu Medichem Co. Ltd

Tel: +86-029-81138252 +86-18789408387
Fax: 029-88380327
Email: 1057@dideu.com
Country: China
ProdList: 3734
Advantage: 58

Hubei huizepu Pharmaceutical Technology Co., Ltd

Tel: 0185-0185-07139096 18507139096
Fax: QQ:1925957016
Email: 18507139096@163.com
Country: China
ProdList: 3855
Advantage: 58

Nantong Runfeng Petrochemical Co., Ltd

Tel: 0513-66017690 13912270238
Fax: 0513-55085866
Email: 2143087160@qq.com
Country: China
ProdList: 3700
Advantage: 58

Less

View Lastest Price from 1,3-Butadiene manufacturers

Hebei Dangtong Import and export Co LTD

Product: 1,3-Butadiene 106-99-0
Price: US $50.00-40.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20Tons
Release date: 2023-10-09

Henan Fengda Chemical Co., Ltd

Product: 1,3-Butadiene 106-99-0
Price: US $101.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-28

Hebei Mojin Biotechnology Co., Ltd

Product: Biethylene 106-99-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-28

106-99-0, 1,3-ButadieneRelated Search:

Acrylonitrile acrylonitrile-butadiene rubber 1-METHOXY-1,3-CYCLOHEXADIENE 1,2,3,4,5-Pentamethylcyclopentadiene Colchicine Vitamin A Tetraphenylcyclopentadienone 1,2,3,4-TETRAPHENYL-1,3-CYCLOPENTADIENE 1,3-CYCLOHEXADIENE DIPHENYLFULVENE Retinal Hexachlorocyclopentadiene alpha-Terpinene Irisone Retinoic acid BCP Hexachlor-1,3-butadien,hexachlor-1,3-butadien(czech 1,2,3,4-Tetrachloro-5,5-dimethoxycyclopentadiene

1,3-Butadiene (stabilized with TBC) (in cylinder without valve) [To use this product charged in cylinder, a valve is required which is sold separately (Product Code:V0030)]

alpha-butadiene

Buta-1,3-dieen

Buta-1,3-dien

Butadieen

Butadien

butadien(polish)

1,3-Butadiene solution

1,3-Butadiene (~15% by weight in Toluene)

1,3-Butadiene (ca. 13% in Tetrahydrofuran, ca. 2mol/L)

1,3-Butadiene (ca. 15% in Hexane)

1,3-Butadiene >=99.6%

1,3-Butadiene solution 15 wt. % in hexane

1,3-Butadiene solution 20 wt. % in toluene

1,3-Butadiene (ca. 15% in Toluene)

butadiene(non-specificname)

butadiene-1,3

butadiene-1,3-uninhibited

butadienemonomer

butadienes,inhibited

NCI-C50602

1,3-BUTADIENE

DIVINYL

ERYTHRENE

BIETHYLENE

BUDIENE

BUTADIENE

BIVINYL

PYRROLYLENE

VINYLETHYLENE

(E)-CH2=CHCH=CH2

1-methylallene

a,g-Butadiene

alpha,gamma-Butadiene

trans-Butadiene

Vinylethyleye

1,3-BUTADIENE, STAB., PRESSURE TIN WITH 10 ML

1,3-BUTADIENE, STAB., PRESSURE TIN WITH 250 ML (NET ~155 G)

1,3-BUTADIENE, STAB., CYL. WITH 14 L

1,3-BUTADIENE, 99+%

1,3-BUTADIENE, STAB., PRESSURE TIN WITH 100 ML

1,3-BUTADIENE, STAB., CYL. WITH 26 L (NE T ~12 KG)

1,3-Butadi

1,3-butadine

1,3-Butadien

1,3-BUTADIENE(STABILIZED WITH TBC)(INCYLINDER WITHOUT VALVE)

beithylene

1, 3-Butadiene (loading process after polymerization)

1,3-butadiene buta-1,3-diene

1,3-BUTADIENE (STABILIZED WITH TBC)(IN CYLINDER WITHOUT VALVE) 95+%

1,3-Butadiene (in cylinder without valve) (stabilized with TBC)

1,3-ButadieneSolution,100mg/L,1ml

1,3-ButadieneSolution,200mg/L,1ml

1,3-Butadiene(ca.15%inHexane)&gt

1,3-ButadieneSolution,2,000mg/L,1ml

1,3-ButadieneSolution(SecondSource),2500mg/L,2x0.6ml

1,3-ButadieneSolution,2,000mg/L,2x0.6ml

1,3-ButadieneSolution,1,000mg/L,1ml