2-Nitrobiphenyl

Product Name: 2-Nitrobiphenyl
CAS No.: 86-00-0
Chemical Name: 2-Nitrobiphenyl
Synonyms: 2-NITROBIPHENYL;Onb;cp368;Nitrodiphenyl;2-Nitrobiphneyl;o-Nitrobiphenyl;O-NITRODIPHENYL;2-NITROBIPHENYL;2-NITRODIPHENYL;2-nitro-bipheny
CBNumber: CB2854478
Molecular Formula: C12H9NO2
Formula Weight: 199.21
MOL File: 86-00-0.mol

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2-Nitrobiphenyl Property

Melting point:: 36-38 °C(lit.)
Boiling point:: 320 °C
Density: 1.44
vapor density: 5.9 (vs air)
vapor pressure: 2 mm Hg ( 140 °C)
refractive index: 1.613-1.615
Flash point:: >230 °F
form: powder to lump
color: White to Yellow to Green
Water Solubility: Insoluble
Merck: 14,6591
InChI: InChI=1S/C12H9NO2/c14-13(15)12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9H
InChIKey: YOJKKXRJMXIKSR-UHFFFAOYSA-N
SMILES: C1(C2=CC=CC=C2)=CC=CC=C1[N+]([O-])=O
CAS DataBase Reference: 86-00-0(CAS DataBase Reference)
NIST Chemistry Reference: 1,1'-Biphenyl, 2-nitro-(86-00-0)
EPA Substance Registry System: o-Nitrobiphenyl (86-00-0)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-40-68-22
Safety Statements: 2-7-36-45-36/37
WGK Germany: 3
RTECS: DV5530000
HS Code: 2904.20.5000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: N0194
Product name: 2-Nitrobiphenyl
Purity: >98.0%(GC)
Packaging: 25g
Price: $23
Updated: 2025/07/31

TCI Chemical

Product number: N0194
Product name: 2-Nitrobiphenyl
Purity: >98.0%(GC)
Packaging: 500g
Price: $218
Updated: 2024/03/01

TRC

Product number: N495803
Product name: 2-Nitrobiphenyl
Packaging: 2.5g
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 172523
Product name: 2-Nitrobiphenyl
Packaging: 25g
Price: $100
Updated: 2021/12/16

AK Scientific

Product number: Q969
Product name: 2-Nitrobiphenyl
Packaging: 5g
Price: $34
Updated: 2021/12/16

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2-Nitrobiphenyl Chemical Properties,Usage,Production

Chemical Properties

Clear yellow liquid after melting. Insoluble in water, soluble in methanol, ethanol, acetone, dimethylformamide, and tetrahydrofurfuryl alcohol.

Uses

2-Nitrobiphenyl is used as a plasticizer for resins, cellulose acetate, cellulose nitrate, and polystyrenes; as a fungicide for textiles; as a wood preservative; and as a dye intermediate.

Synthesis Reference(s)

Tetrahedron Letters, 36, p. 6567, 1995 DOI: 10.1016/0040-4039(95)01327-E

General Description

Gold to tan crystals or brown solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Aromatic nitro compounds, such as 2-Nitrodiphenyl, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

Fire Hazard

2-Nitrodiphenyl is combustible.

Purification Methods

Crystallise it from EtOH (seeding required). Sublime it under vacuum. [Beilstein 5 H 582, 5 I 273, 5 II 487, 5 III 1750.]

References

[1] A. SEKINE. 2-nitrobiphenyl and 2,2’-dinitrobiphenyl[J]. Acta crystallographica. Section C, Crystal structure communications, 1994, 26 1: 1101-1104. DOI:10.1107/S0108270194001009.
[2] YOST Y. Carbazole from o-biphenylhydroxylamine and from 2-nitrobiphenyl and phenylmagnesium bromide[J]. Journal of Heterocyclic Chemistry, 1972, 9 1: 151-152. DOI:10.1002/jhet.5570090128.
[3] EVA HORAKOVA. Voltammetric Determination of 2-Nitrobiphenyl and 4-Nitrobiphenyl Using a Mercury Meniscus Modified Silver Solid Amalgam Electrode[J]. International Journal of Electrochemical Science, 2015, 10 3: Pages 2155-2169. DOI:10.1016/S1452-3981(23)04837-X.
[4] JIRO HIGUCHI. Electron paramagnetic resonance study on the triplet species produced from 2-nitrobiphenyl derivatives by UV irradiation[J]. Journal of Photochemistry and Photobiology A-chemistry, 1999, 124 1: Pages 53-65. DOI:10.1016/S1010-6030(99)00075-1.

2-Nitrobiphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

2-Aminobiphenyl

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2-Nitrobiphenyl Suppliers

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View Lastest Price from 2-Nitrobiphenyl manufacturers

Kindchem(Nanjing)Co.,Ltd

Product: 2-Nitrodiphenyl 86-00-0
Price: US $0.00-0.00/kgkg
Min. Order: 0.1kgkg
Purity: 98%
Supply Ability: 2000kg
Release date: 2023-06-08

Career Henan Chemical Co

Product: 2-Nitrodiphenyl 86-00-0
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100KG
Release date: 2018-12-18

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86-00-0

C6H5C6H4NO2

Plasticizer

Camphor, etc. (Plasticizer)

Nitro Compounds

Organic Building Blocks

Nitrogen Compounds

Building Blocks

Camphor, etc. (Plasticizer)

Functional Materials

Plasticizer