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Trimethyl-pyrazine

Product Name
Trimethyl-pyrazine
CAS No.
14667-55-1
Chemical Name
Trimethyl-pyrazine
Synonyms
Pyrazine, trimethyl-;2,3,5-TRIMETHYLPYRAZINE;TRIMETHYLPYRAZINE;2,3,5-TriMethylpyrazine 99%;FEMA 3244;FEMA NUMBER 3244;Compound Fr14500;trimethyl-pyrazin;2.3.5-Methyl pyrazine;TRIMETHYLPYRAZINE,2,3,5
CBNumber
CB3105641
Molecular Formula
C7H10N2
Formula Weight
122.17
MOL File
14667-55-1.mol
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Trimethyl-pyrazine Property

Melting point:
156 °C
Boiling point:
171-172 °C (lit.)
Density 
0.979 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.5040(lit.)
FEMA 
3244 | 2,3,5-TRIMETHYLPYRAZINE
Flash point:
130 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly)
pka
2.69±0.10(Predicted)
Specific Gravity
0.979
color 
Colorless to Light yellow to Light orange
Odor
roasted odor, reminiscent of coffee and cocoa
Odor Type
nutty
JECFA Number
774
BRN 
2423
InChIKey
IAEGWXHKWJGQAZ-UHFFFAOYSA-N
LogP
1.10
CAS DataBase Reference
14667-55-1(CAS DataBase Reference)
NIST Chemistry Reference
Pyrazine, trimethyl-(14667-55-1)
EPA Substance Registry System
Trimethylpyrazine (14667-55-1)
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Safety

Hazard Codes 
Xn
Risk Statements 
10-22-36/37/38
Safety Statements 
16-26-36/37/39
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
RTECS 
UQ3907000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29339900
Toxicity
rat,LD50,oral,806mg/kg (806mg/kg),Drug and Chemical Toxicology. Vol. 3, Pg. 249, 1980.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W324426
Product name
2,3,5-Trimethylpyrazine
Purity
natural, ≥95%, FG
Packaging
100g
Price
$490
Updated
2024/03/01
Sigma-Aldrich
Product number
W324426
Product name
2,3,5-Trimethylpyrazine
Purity
natural, ≥95%, FG
Packaging
1kg
Price
$4530
Updated
2024/03/01
Sigma-Aldrich
Product number
W324418
Product name
2,3,5-Trimethylpyrazine
Purity
≥99%, FCC, FG
Packaging
100g
Price
$78.2
Updated
2024/03/01
Sigma-Aldrich
Product number
W324418
Product name
2,3,5-Trimethylpyrazine
Purity
≥99%, FCC, FG
Packaging
1kg
Price
$316
Updated
2024/03/01
Sigma-Aldrich
Product number
W324418
Product name
2,3,5-Trimethylpyrazine
Purity
≥99%, FCC, FG
Packaging
5kg
Price
$1110
Updated
2024/03/01
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Trimethyl-pyrazine Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW LIQUID

Chemical Properties

2,3,5-Trimethylpyrazine has a baked potato or roasted nut aroma.

Occurrence

Reported present in bakery products, roasted barley, cocoa products, coffee, dairy products, meat, peanuts, filberts, pecans, popcorn, potato products, rum and whiskey, soy products, raw asparagus, baked potato, wheaten bread, crispbread, Swiss cheese, coffee, black tea, green tea, roasted barley, roasted filbert, heated beef, roasted peanut, soybean, raw beans, coriander seed, scallop, guava, kohlrabi, bell pepper, blue, Swiss and Gruyere cheese, boiled egg, fatty fish, beer, sherry, barley, peanut, oat products, coconut, beans, mushroom, trassi, almond, macadamia nut, sesame seed, coriander seed, rice, licorice, sweet corn, malt, peated malt, wort, krill, fermented shrimp, crab, okra, crayfish, clam, scallop and squid.

Uses

Trimethylpyrazine is a key aroma compound of dark chocolates differing in organoleptic properties.

Uses

2,3,5-Trimethylpyrazine can be used as a flavor ingredient in food industries.

Definition

ChEBI: Trimethylpyrazine is a member of the class of pyrazines that is pyrazine in which three hydrogens at positions 2, 3 and 5 have been replaced by methyl groups. It has a role as a plant metabolite, a flavouring agent, a bacterial metabolite, an animal metabolite and a pheromone.

Preparation

From 2,5-dimethylpyrazine by ring alkylation with MeLi; by condensing propylenediamine with 2,3-butanedione.

Aroma threshold values

Detection: 400 ppb to 9 ppm (9 ppm in water)

Taste threshold values

Taste characteristics at 80 ppm: raw, musty, nutty and potato.

General Description

2,3,5-Trimethylpyrazine is present in brown cheese.

Safety Profile

Moderately toxic by ingestion. Combustible liquid. When heated to decomposition emits toxic fumes of NOx.

Trimethyl-pyrazine Preparation Products And Raw materials

Raw materials

Preparation Products

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Trimethyl-pyrazine Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15848
Advantage
69
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1998
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
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View Lastest Price from Trimethyl-pyrazine manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Trimethyl-pyrazine 14667-55-1
Price
US $25.00-15.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-02-23
Hebei Mojin Biotechnology Co., Ltd
Product
Trimethyl-pyrazine 14667-55-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-06-29
Hebei Mojin Biotechnology Co., Ltd
Product
Trimethyl-pyrazine 14667-55-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-06-29

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