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Trimethyl thiazole

Description References
Product Name
Trimethyl thiazole
CAS No.
13623-11-5
Chemical Name
Trimethyl thiazole
Synonyms
FEMA 3325;FEMA NUMBER 3325;TRIMETHYLTHIAZOLE;Thiazole, trimethyl-;2,4,5-TRIMETHYLANILINE;triMethyl-1,3-thiazole;2,4,5-TRIMETHYLTHIAZOLE;2,4,5-trimethyl-thiazol;TRIMETHYL(2,4,5-) THIAZOLE;Thiazole, 2,4,5-trimethyl-
CBNumber
CB4422716
Molecular Formula
C6H9NS
Formula Weight
127.21
MOL File
13623-11-5.mol
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Trimethyl thiazole Property

Melting point:
-32.4°C
Boiling point:
166-167 °C/717 mmHg (lit.)
Density 
1.013 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.509(lit.)
FEMA 
3325 | 2,4,5-TRIMETHYLTHIAZOLE
Flash point:
133 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
pK1:4.55 (25°C,μ=0.1)
form 
liquid
Specific Gravity
1.311.013
color 
Light orange to Yellow to Green
Odor
at 1.00 % in dipropylene glycol. musty nutty vegetable cocoa hazelnut chocolate coffee
Odor Type
chocolate
JECFA Number
1036
BRN 
107148
LogP
2.02
CAS DataBase Reference
13623-11-5(CAS DataBase Reference)
NIST Chemistry Reference
Thiazole, 2,4,5-trimethyl-(13623-11-5)
EPA Substance Registry System
Thiazole, trimethyl- (13623-11-5)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-37/38-41-36/37/38
Safety Statements 
26-39-37/39-36-7/9
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
3.2
PackingGroup 
III
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W332518
Product name
2,4,5-Trimethylthiazole
Purity
≥98%, FG
Packaging
sample-k
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W332518
Product name
2,4,5-Trimethylthiazole
Purity
≥98%, FG
Packaging
25g
Price
$98.1
Updated
2024/03/01
Sigma-Aldrich
Product number
W332518
Product name
2,4,5-Trimethylthiazole
Purity
≥98%, FG
Packaging
100g
Price
$217
Updated
2024/03/01
Sigma-Aldrich
Product number
W332518
Product name
2,4,5-Trimethylthiazole
Purity
≥98%, FG
Packaging
1kg
Price
$1360
Updated
2024/03/01
Sigma-Aldrich
Product number
219185
Product name
2,4,5-Trimethylthiazole
Purity
98%
Packaging
5g
Price
$38.1
Updated
2024/03/01
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Trimethyl thiazole Chemical Properties,Usage,Production

Description

2,4,5-trimethyl thiazole has a cocoa, dark chocolate, nutty, coffee note. It is naturally found in cooked potatoes, cooked meat, coffee, black tea, and herbs. It is used as a flavor ingredient in foods.

References

[1] George A. Burdock, Encyclopedia of Food and Color Additives, Volume 3, 1997
[2] Erich Ziegler and Herta Ziegler, Flavourings: Production, Composition, Applications, Regulations, 1998

Chemical Properties

clear colourless to yellow liquid

Chemical Properties

2,4,5-Trimethyl thiazole has a cocoa, dark chocolate, nutty, coffee taste.

Occurrence

Reported found in kohlrabi, French fried potato, boiled and cooked potato, fried chicken, raw chicken, boiled and cooked beef, grilled and roasted beef, lamb and mutton liver, boiled and cooked cured pork, coffee, black tea, coriander seed, katsuobushi (dried bonito), cooked shrimp and other natural sources.

Uses

2,4,5-Trimethylthiazole was employed as internal standard in the gas chromatographic determination of aldehydes in alcoholic beverages.

Definition

ChEBI: A 1,3-thiazole that is thiazole in which all three hydrogens are replaced by methyl groups. A Maillard reaction product, it is a flavour component in many cooked foods, including cooked meats and potatoes.

Preparation

By decarboxylation of 2,4-dimethylthiazole-5-acetic acid; by reacting acetamide and phosphorous pentasulfide with methyl-α-bromoethyl ketone.

Aroma threshold values

Detection: 50 ppb

Taste threshold values

Taste characteristics at 10 ppm: nutty, cocoa and green vegetative-like with roasted earthy nuances.

General Description

2,4,5-Trimethylthiazole is a volatile oxidant and was isolated during microwave-induced L-cysteine/D-glucose Maillard model system.

Trimethyl thiazole Preparation Products And Raw materials

Raw materials

Preparation Products

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Trimethyl thiazole Suppliers

Shanghai Boyle Chemical Co., Ltd.
Tel
021-50182298 021-50180596
Fax
+86-21-57758967
Email
sales@boylechem.com
Country
China
ProdList
2210
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
Advantage
76
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9984
Advantage
60
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
zhangsn@titansci.com
Country
China
ProdList
14113
Advantage
59
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9816
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
jiliang chemicals
Tel
21-62165282 15801962796;
Fax
021 61153784
Email
bidingchem@163.com
Country
China
ProdList
1165
Advantage
60
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View Lastest Price from Trimethyl thiazole manufacturers

Hebei Guanlang Biotechnology Co,.LTD
Product
Trimethyl thiazole 13623-11-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50 ton
Release date
2021-06-17
Henan Aochuang Chemical Co.,Ltd.
Product
Trimethyl thiazole 13623-11-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-08
Zhuozhou Wenxi import and Export Co., Ltd
Product
Trimethyl thiazole 13623-11-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

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