(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

Reaction

Product Name: (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
CAS No.: 112022-81-8
Chemical Name: (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
Synonyms: (S)-2-METHYL-CBS-OXAZABOROLIDINE;(S)-1-METHYL-3,3-DIPHENYLHEXAHYDROPYRROLO[1,2-C][1,3,2]OXAZABOROLE;(S)-ME CBS;(S)-Me-CBS Catalyst;(S)-2-METHYL-CBS-OXAZABOROL;(S)-(-)-2-METHYL-CBS-OXAZABOROLIDINE;(s)-(-)-2-methyl-cbs-oxazaborolidine solution;(S)-5,5-DIPHENYL-2-METHYL-3,4-PROPANO-1,3,2-OXAZABOROLIDINE;(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine;(s)-methyl
CBNumber: CB3106062
Molecular Formula: C18H20BNO
Formula Weight: 277.17
MOL File: 112022-81-8.mol

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(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Property

Melting point:: 115-117°C
Boiling point:: 111 °C
Density: 0.93 g/mL at 20 °C(lit.)
refractive index: -68 ° (C=1, MeOH)
Flash point:: 40 °F
storage temp.: room temp
form: Liquid
pka: 1.02±0.40(Predicted)
color: Colorless to amber
Water Solubility: Hydrolyzes in water.
Sensitive: Air & Moisture Sensitive
BRN: 8492123
Exposure limits: ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)
InChIKey: VMKAFJQFKBASMU-KRWDZBQOSA-N
CAS DataBase Reference: 112022-81-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn,F
Risk Statements: 36/37/38-67-65-63-48/20-11-19-40
Safety Statements: 26-62-36/37-33-29-16
RIDADR: UN 1294 3/PG 2
WGK Germany: 3
F: 10-21
HazardClass: 3
PackingGroup: II
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 457701
Product name: (S)-(?)-2-Methyl-CBS-oxazaborolidine solution
Purity: 1 M in toluene
Packaging: 5ml
Price: $98.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 457701
Product name: (S)-(?)-2-Methyl-CBS-oxazaborolidine solution
Purity: 1 M in toluene
Packaging: 25ml
Price: $345
Updated: 2024/03/01

TCI Chemical

Product number: D2131
Product name: (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine
Purity: >98.0%(T)
Packaging: 1g
Price: $84
Updated: 2024/03/01

TCI Chemical

Product number: D2131
Product name: (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine
Purity: >98.0%(T)
Packaging: 5g
Price: $331
Updated: 2024/03/01

Alfa Aesar

Product number: L09219
Product name: (S)-2-Methyl-CBS-oxazaborolidine monohydrate, 94%
Packaging: 1g
Price: $272
Updated: 2021/12/16

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(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Chemical Properties,Usage,Production

Reaction

Convenient catalyst for the enantioselective borane reduction of ketones at ambient temperatures.
Asymmetric synthesis of α-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines.
Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes and triarylmethanes.
Enantioselective reduction of prochiral ketones with NaBH4/Me2SO4/(S)-Me-CBS.

Chemical Properties

Colorless to yellow liquid

Uses

(S)-2-Methyl-CBS-oxazaborolidine is used as an oxazaborolidine catalyst. It is also employed in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2-symmetrical ferrocenyl diols and propargyl alcohols. It is an anhydrous catalyst for 'CBS' reduction reaction.

Uses

suzuki reaction

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Preparation Products And Raw materials

Raw materials

Trimethylboroxine PHENYLMAGNESIUM BROMIDE L-Proline Tetrahydrofuran Dichloromethane Thionyl chloride

Preparation Products

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(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Suppliers

Americas 1 Belgium 1 China 197 Europe 2 Germany 5 India 16 Japan 4 Russia 2 Slovakia 1 Switzerland 2 The Netherlands 1 United Kingdom 10 United States 32 Global 274

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

Nisso Shoji Co. Ltd.

Tel: --
Fax: --
Email: sekiya@nissoshoji.co.jp
Country: Japan
ProdList: 40
Advantage: 58

TCI Japan

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Fax: --
Email: @TCIchemicals.com
Country: Japan
ProdList: 2741
Advantage: 58

Hattori Corporation

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Email: info@hattoricorp.com
Country: Japan
ProdList: 1254
Advantage: 58

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View Lastest Price from (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole 112022-81-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: (S)-()-2-Methyl-CBS-oxazaborolidine solution 112022-81-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole 112022-81-8
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: as request
Release date: 2018-12-23

112022-81-8, (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaboroleRelated Search:

(4S)-(+)-4-Benzyl-3-propionyl-2-oxazolidinone Phosphorus trichloride 4-Methoxybenzoic acid Lithium hydride Tetrahydrofuran CATECHOLBORANE (S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol L-(+)-Prolinol Methylboronic acid (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole (R)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99% (R)-Phenyl oxazaborolidine (S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& (S)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99% (S)-Phenyl oxazaborolidine (S)-CBS-BORANE COMPLEX (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole (R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&

(S)-1-METHYL-3,3-DIPHENYL-TETRAHYDRO-PYRROLO[1,2C][1,3,2]OXAZABOROLE

α,α-diphenyl-l-prolinol methylboronic acid cycl-amide-ester

(S)-(+)-Methyl-CBS-oxazaborolidine

(S)-1-METHYL-3,3-DIPHENYLHEXAHYDROPYRROLO[1,2-C][1,3,2]OXAZABOROLE

(S)-5,5-DIPHENYL-2-METHYL-3,4-PROPANO-1,3,2-OXAZABOROLIDINE 98+%

(S)-METHYL-CBS-OXAZABOROLIDINE,1M SOLN.IN TOLUENE

(S)-Me-CBS Catalyst

(S)-Methyl oxazaborolidine, in toluene, 1M solution

(S)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-3H-P YRROLO-OXAZABOROLE

(S)-2-METHYL-CBS-OXAZABOROLIDINE, 1M SOL UTION IN TOLUENE

(S)-2-METHYL-CBS-OXAZABOROLIDINE, 1M IN&

(S)-Methyloxazaborolidine,1-1.5Mintoluene[(S)-MeCBS]CoreyCatalyst

(s)-(-)-2-methyl-cbs-oxazaborolidine solution

(s)-2-methyl-cbs-oxazaborolidine, 1m soln. in toluene

(S)-1-Methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2c][1,3,2]oxazaborole, (S)-3,3-Diphenyl-1-methyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole, (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, α,α-Diphenyl-L-prolinol methylboronic acid cycl-amide ester

(S)-Tetrahydro-1-methyl-3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 1-1.5M in toluene [(S)-Methyl oxazaborolidine] Corey Catalyst

(3aS)-1-Methyl-3,3-diphenyl-3aβ,4,5,6-tetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole

(3aS)-1-Methyl-3,3-diphenyl-tetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole

(3aS)-3,3aβ,4,5-Tetrahydro-1-methyl-3,3-diphenyl-6H-1-bora-2-oxa-6a-azapentalene

(3aS)-3,3-Diphenyl-1-methyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole

(3aS)-3aβ,4,5,6-Tetrahydro-1-methyl-3,3-diphenyl-3H-pyrrolo[1,2-c][1,3,2]oxazaborole

(S)-()-2-Methyl-CBS-oxazaborolidine solution 1 M in THF

(S)-2-Methyl-CBS-oxazaborolidine (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

(S)-(-)-2-Methyl-CBS-oxazaborolidine >=95.0%

(S)-(-)-2-Methyl-CBS-oxazaborolindine

(S)-2-methyl-CBS-oxazaborolidine(1mol/L)

(S)-2-methyl-CBS-oxazaborolidine(solid)

(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine

(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine] (S)-CBS Catalyst

(3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole

(S)-(-)-2-Methyl-CBS-oxazaborolidine, 1.0 M solution in toluene, J&KSeal

(S)-2-METHYL-CBS-OXAZABOROL

(S)-(-)-2-MethyL

(S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine - 1.0M in toluene

(3aβ)-1-Methyl-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole

1-(S)-methyl CBS oxazaborolidine

(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole,0.9-1.1Mintoluene[(S)-Methyloxazaborolidine]CoreyCatalyst

(S)-(-)-2-METHYL-CBS-[1,3,2]OXAZABOROLIDINE IN,TOLUENE

(S)-2-Methyl-CBS-oxazaborolidine ,98%

ALPHA,ALPHA-DIPHENYL-L-PROLINOL METHYLBORONIC ACID CYCL-AMIDE ESTER

(S)-(-)-2-Methyl-CBS-oxazaborolidine, 1M solution in toluene, AcroSeal

1-Methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole

(S)-5,5-DIPHENYL-2-METHYL-3,4-PROPANO-1,3,2-OXAZABOROLIDINE

(S)-(-)-2-METHYL-CBS-OXAZABOROLIDINE

(S)-2-METHYL-CBS-OXAZABOROLIDINE

(S)-2-METHYL-CBS-OXAZABOROLIDINE MONOHYDRATE

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

(S)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-1H,3H-PYRROLO[1,2-C][1,3,2]OXAZABOROLE

(S)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-3H-PYRROLO-[1,2-C][1,3,2]OXAZABOROLE

(S)-ME CBS

(S)-METHYL OXAZABOROLIDINE

(S)-TETRAHYDRO-1-METHYL-3,3-DIPHENYL-1H,3H PYRROLO[1,2-C][1,3,2] OXAZABOROLE

(s)-methyl

(s)-methyloxazaborolidine,(s)-mecbs,in

(s)-methyloxazaborolidine,(s)-mecbs,intoluene

(S)-Methyloxazaborolidine,1-1.5Mintoluene[(S)-MeCBS]

(S)-Tetrahydro-1-Methyl-3

0.9-1.1Mintoluene[(S)-Methyloxazaborolidine]CoreyCatalyst