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ChemicalBook > CAS DataBase List > DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

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Product Name
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
CAS No.
132071-87-5
Chemical Name
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Synonyms
Dichloro [(R);[(R)-BINAP]RUCL2;Dichloro[(R)-(+)-2,2;-2,2'-bis(diphenylphosphino);-1,1'-binaphathyl] ruthenium(II);(R)-(+)-BINAP dichloro Ruthenium (Il);(R) -(+)-BINAP DICHLORO RUTHENIUM (II);Dichlorobisdiphenylphosphinobinaphthylruthenium;R-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium;(R)-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]dichlororutheniuM
CBNumber
CB3114506
Molecular Formula
C44H32Cl2P2Ru
Formula Weight
794.65
MOL File
132071-87-5.mol
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Property

Melting point:
>300 ºC
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange
Sensitive 
air sensitive
InChI
InChI=1S/C44H32P2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2
InChIKey
YEKBVMDAGDTOQB-UHFFFAOYSA-L
SMILES
C1(C2C3C=CC=CC=3C=CC=2P(C2=CC=CC=C2)C2=CC=CC=C2)C2C=CC=CC=2C=CC=1P(C1=CC=CC=C1)C1C=CC=CC=1.[Ru](Cl)Cl
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-36/37
HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3067
Product name
[(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
Packaging
250mg
Price
$296
Updated
2024/03/01
Strem Chemicals
Product number
44-0248
Product name
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
100mg
Price
$90
Updated
2024/03/01
Strem Chemicals
Product number
44-0248
Product name
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
500mg
Price
$200
Updated
2024/03/01
Strem Chemicals
Product number
44-0248
Product name
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
2g
Price
$600
Updated
2024/03/01
TRC
Product number
B675395
Product name
(R)​-​[2,​2''-​Bis(diphenylphosphin​o)​-​1,​1''-​binaphthyl]​dichlororuthenium
Packaging
100mg
Price
$140
Updated
2021/12/16
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties,Usage,Production

Reaction

  1. Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
  2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.

Uses

(R)?-?[2,?2''-?Bis(diphenylphosphin?o)?-?1,?1''-?binaphthyl]?dichlororuthenium is a catalyst used in the synthesis of helicobacter pylori lipopolysaccharide structures displaying anti-inflammatory activiy.

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products

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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Suppliers

Americas 1 China 149 Europe 1 Germany 5 India 4 Japan 1 South Korea 1 Switzerland 1 Ukraine 1 United Kingdom 2 United States 16 Global 182
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) manufacturers

Hangzhou ICH Biofarm Co., Ltd
Product
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) 132071-87-5
Price
US $0.00/kg
Min. Order
1kg
Purity
97%
Supply Ability
200kg
Release date
2023-06-28
Henan Aochuang Chemical Co.,Ltd.
Product
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) 132071-87-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-19
Wuhan LPBchem Technology Co.,Ltd
Product
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 132071-87-5
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-09-28

132071-87-5, DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)Related Search:

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Dichloro(p-cymene)ruthenium(II) dimer [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) [(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Dichloro[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1-binaphthyl]paltinum(II) Dichloro[(S)-(-)-2,2’-bis(diphenylphosphino)-1,1-binaphthyl]paltinum(II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1,1'-BINAPHTHYL Ruthenium(IV) oxide hydrate Ruthenium dioxide Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II)chloride DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE

  • Dichloro〔(R)-(+)-2,2-bis(diphenylphosphino)-1,1-binaphthyl)ruthenium(Ⅱ)
  • Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1, 1'-binaphthyl]ruthenium(II), min. 95%
  • Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II),98% [(R)-BINAP]RuCl2
  • [(R)-BINAP]RUCL2
  • (R)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium(II)
  • [(R)-(+)-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl] ruthenium dichloride
  • Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(R)-BINAP]RuCl2
  • Dichloro [(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphathyl] rutheniuM(II)
  • (R)-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]dichlororutheniuM
  • Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),(R-BINAP)RuCl2
  • [(R)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium
  • (R)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium 95%
  • -1,1'-binaphathyl] ruthenium(II)
  • -2,2'-bis(diphenylphosphino)
  • Dichloro [(R)
  • Dichlorobisdiphenylphosphinobinaphthylruthenium
  • Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II),min.95%
  • [(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
  • DICHLORO[(S)-(-)-,2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
  • DICHLORO[(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER
  • DICHLORO[(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER
  • Ruthenium, [(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]dichloro-, (SP-4-2)- (9CI)
  • DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) ISO 9001：2015 REACH
  • Dichloro[(R)-(+)-2,2
  • (R)-(+)-BINAP dichloro Ruthenium (Il)
  • (R) -(+)-BINAP DICHLORO RUTHENIUM (II)
  • R-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium
  • Dichloro [(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphathyl] ruthenium(II)
  • (R)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium(II)
  • DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
  • DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
  • 132071-87-5
  • RuCl2C44H32P2x
  • C44H32P2Cl2Ru
  • Ru
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Ru (Ruthenium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds