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1-Bromo-2,4-dimethoxybenzene

Product Name
1-Bromo-2,4-dimethoxybenzene
CAS No.
17715-69-4
Chemical Name
1-Bromo-2,4-dimethoxybenzene
Synonyms
1-Bromo-2,4-dimethox;3-Methoxy-4-bromoanisole;2,4-DIMETHOXYBROMOBENZENE;2,4-diMethoxylbroMophenol;2,4-Dimethoxyphenyl bromide;1,3-Dmethoxy-4-bromobenzene;1,3-DIMETHOXY-4-BROMOBENZENE;1-BROMO-2,4-DIMETHOXYBENZENE;4-Bromo-1,3-dimethoxybenzene;Benzene, 1-bromo-2,4-dimethoxy-
CBNumber
CB3137482
Molecular Formula
C8H9BrO2
Formula Weight
217.06
MOL File
17715-69-4.mol
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1-Bromo-2,4-dimethoxybenzene Property

Melting point:
25-26 °C(lit.)
Boiling point:
153-155 °C18 mm Hg(lit.)
Density 
1.507 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.572(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
form 
Liquid
Specific Gravity
1.507
color 
Clear slightly yellow
Water Solubility 
insoluble
BRN 
1867593
InChI
InChI=1S/C8H9BrO2/c1-10-6-3-4-7(9)8(5-6)11-2/h3-5H,1-2H3
InChIKey
NIUZVSQOXJIHBL-UHFFFAOYSA-N
SMILES
C1(Br)=CC=C(OC)C=C1OC
CAS DataBase Reference
17715-69-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-bromo-2,4-dimethoxy-(17715-69-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
157554
Product name
1-Bromo-2,4-dimethoxybenzene
Purity
97%
Packaging
25g
Price
$25.55
Updated
2025/07/31
TCI Chemical
Product number
B1481
Product name
1-Bromo-2,4-dimethoxybenzene
Purity
>97.0%(GC)
Packaging
5g
Price
$41
Updated
2025/07/31
TCI Chemical
Product number
B1481
Product name
1-Bromo-2,4-dimethoxybenzene
Purity
>97.0%(GC)
Packaging
25g
Price
$120
Updated
2025/07/31
Usbiological
Product number
409175
Product name
1-Bromo-2,4-dimethoxybenzene
Packaging
500mg
Price
$305
Updated
2021/12/16
TRC
Product number
B689043
Product name
1-Bromo-2,4-dimethoxybenzene
Packaging
500mg
Price
$45
Updated
2021/12/16
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1-Bromo-2,4-dimethoxybenzene Chemical Properties,Usage,Production

Chemical Properties

clearslightlyyellowliqui

Uses

1-Bromo-2,4-dimethoxybenzene was used in the synthesis of 2,3-disubstituted benzo[b]furans. It was also used in the synthesis of dendrimer Si[CH2CH2Si(Me)2-2,4-(MeO)2-C6H3]4.

Synthesis

151-10-0

17715-69-4

Carbon tetrabromide (0.075 mmol), AQN-2-CO2H (0.03 mmol) and anhydrous ethanol (5 mL) were added to a Pyrex test tube using 1,3,5-trimethoxybenzene (1a, 0.3 mmol) as the raw material. The reaction mixture was irradiated and stirred in air for 20 h at room temperature using a 21 W fluorescent lamp. Upon completion of the reaction, the mixture was concentrated in vacuum, quenched with sodium thiosulfate (Na2S2O3) solution and extracted with ethyl acetate (EtOAc). The organic layers were combined and dried with anhydrous magnesium sulfate (MgSO4), followed by vacuum concentration to remove the solvent. Purification of the residue by rapid chromatography on silica gel (eluent ratio hexane/ethyl acetate = 6:1) afforded the target product 2-bromo-1,3,5-trimethoxybenzene (2a) (66.8 mg, 90% yield) as a white solid.

References

[1] Synthetic Communications, 2007, vol. 37, # 2, p. 323 - 328
[2] Journal of Organic Chemistry, 2013, vol. 78, # 20, p. 10360 - 10368
[3] Bulletin of the Chemical Society of Japan, 1989, vol. 62, # 2, p. 591 - 593
[4] Canadian Journal of Chemistry, 2009, vol. 87, # 2, p. 440 - 447
[5] Tetrahedron Letters, 1997, vol. 38, # 25, p. 4415 - 4416

1-Bromo-2,4-dimethoxybenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Bromo-2,4-dimethoxybenzene Suppliers

Americas 1 Belgium 3 CHINA 257 Europe 2 Germany 6 India 10 Japan 6 South Korea 1 Switzerland 2 The Netherlands 1 Ukraine 2 United Kingdom 20 United States 51 Global 362
Brunschwig chemie
Tel
--
Fax
--
Email
brunschwig@brunschwig.nl
Country
The Netherlands
ProdList
4996
Advantage
67
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View Lastest Price from 1-Bromo-2,4-dimethoxybenzene manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
1-Bromo-2,4-dimethoxybenzene 17715-69-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-20
Henan Aochuang Chemical Co.,Ltd.
Product
1-Bromo-2,4-dimethoxybenzene 17715-69-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Shaanxi Dideu Medichem Co. Ltd
Product
1-Bromo-2,4-dimethoxybenzene 17715-69-4
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000 tons
Release date
2020-01-06

17715-69-4, 1-Bromo-2,4-dimethoxybenzeneRelated Search:

Dimethyldimethoxysilane 2,2-Dimethoxypropane DIMETHYL METHOXYMALONATE 1,1-Dimethoxyethane Dimethyl ether 4-Bromoanisole Bromoxynil Dimethoxymethane Bromine 1-BROMO-3,4-DIMETHOXYBENZENE,4-BROMO-1,2-DIMETHOXYBENZENE,1-BROMO-3,4-DIMETHOXYBENZENE / 4-BROMOVERATROLE 3-BROMO-5-CHLORO-2,6-DIMETHOXYBENZOIC ACID 1,5-Dibromo-2,4-dimethoxybenzene METHYL 3,5-DIBROMO-2,4-DIMETHOXY-6-METHYLBENZOATE 3-BROMO-5-CHLORO-2,6-DIMETHOXYBENZAMIDE 3-BROMO-2,6-DIMETHOXYBENZOIC ACID 1-BROMO-3 5-DIMETHOXYBENZENE 97,1-Bromo-3,5-dimethoxybenzene 5-Bromo-1,4-dimethoxybenzene,2-Bromo-1,4-dimethoxybenzene,1-BROMO-2,5-DIMETHOXYBENZENE,1-Bromo-2,5-dimethoxybenzene,98%,1-BROMO-2,5-DIMETHOXYBENZENE 98% 1-BROMO-2,6-DIMETHOXYBENZENE

  • 1-BROMO-2,4-DIMETHOXYBENZENE
  • 1,3-DIMETHOXY-4-BROMOBENZENE
  • 1-BROMO-2 4-DIMETHOXYBENZENE 96%
  • 2,4-DIMETHOXYBROMOBENZENE
  • 4-BROMORESOCINOL DIMETHYL ETHER
  • 4-BROMORESORCINOL DIMETHYL ETHER
  • 2,4-Dimethoxyphenyl bromide
  • 4-Bromo-1,3-dimethoxybenzene
  • 1-Bromo-2,4-dimethoxybenzene, GC 98%
  • Benzene, 1-bromo-2,4-dimethoxy-
  • 3-Methoxy-4-bromoanisole
  • 1-Bromo-2,4-dimethoxybenzene,98%
  • 1,3-Dmethoxy-4-bromobenzene
  • 1-Bromo-2,4-dimethox
  • 2,4-diMethoxylbroMophenol
  • 1-BroMo-2,4-diMethoxybenzene, 98% 5ML
  • 1-broMo -2,4- twoMethoxybenzene
  • 1-Bromo-2,4-dimethoxybenzene &gt
  • 1-Bromo-2,4-dimethoxybenzene ISO 9001：2015 REACH
  • 17715-69-4
  • 17775-69-4
  • 11715-69-4
  • 17715-69-1
  • 17717-69-4
  • C8H9BrO2
  • Building Blocks
  • ARYL HALIDE
  • Oxygen Compounds
  • Organic Building Blocks
  • Ethers
  • Alcohol& Phenol& Ethers
  • Benzene derivates
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Bromine Compounds
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
  • Aromatic Ethers
  • Anisole
  • bc0001