(-)-CAMPHOR

ChemicalBook > CAS DataBase List > (-)-CAMPHOR

Uses

Product Name: (-)-CAMPHOR
CAS No.: 464-48-2
Chemical Name: (-)-CAMPHOR
Synonyms: Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1S)-;CAMPHORE;(-)-Alcanfor;(1S)-(-)-Camphor 95%;(1S,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one;[1S,4S,(-)]-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one;NSC 26351;(-)-Camphor;(1S)-CAMPHOR;1-(-)CAMPHOR
CBNumber: CB3141094
Molecular Formula: C10H16O
Formula Weight: 152.23
MOL File: 464-48-2.mol

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(-)-CAMPHOR Property

Melting point:: 177-179 °C(lit.)
Boiling point:: 204 °C(lit.)
alpha: -44.8° (20/D)(EtOH)
Density: 0.990
vapor density: 5.24 (vs air)
vapor pressure: 4 mm Hg ( 70 °C)
refractive index: -44 ° (C=20, EtOH)
Flash point:: 148 °F
storage temp.: Sealed in dry,Room Temperature
solubility: DMF: 30 mg/ml; DMSO: 20 mg/ml; Ethanol: 30 mg/ml; Ethanol:PBS (pH 7.2)(1:2): 0.33 mg/ml
form: Adhering Crystals or Crystalline Powder
Specific Gravity: 0.9853 (18℃)
color: White to yellow
Odor: at 10.00 % in dipropylene glycol. camphor
Odor Type: camphoreous
explosive limit: 0.6-4.5%(V)
optical activity: [α]20/D 43°, c = 10 in ethanol
Water Solubility: Soluble in water. (0.34 g/L) at 20°C
Merck: 14,1732
BRN: 4291747
Stability:: Stable. Incompatible with strong reducing agents, strong oxidizing agents, chlorinated solvents. Protect from direct sunlight.
InChIKey: DSSYKIVIOFKYAU-OIBJUYFYSA-N
LogP: 2.089 (est)
CAS DataBase Reference: 464-48-2(CAS DataBase Reference)
EPA Substance Registry System: l-Camphor (464-48-2)

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-36/37/38
Safety Statements: 16-26
RIDADR: UN 2717 4.1/PG 3
WGK Germany: 1
RTECS: EX1250000
Autoignition Temperature: 870 °F
TSCA: Yes
HazardClass: 4.1
PackingGroup: III
HS Code: 29142910

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H228Flammable solid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 21293
Product name: (?)-Camphor
Purity: analytical standard
Packaging: 1g
Price: $75.7
Updated: 2024/03/01

TCI Chemical

Product number: C1251
Product name: (-)-Camphor
Purity: >98.0%(GC)
Packaging: 5g
Price: $49
Updated: 2024/03/01

Alfa Aesar

Product number: B23469
Product name: (1S)-(-)-Camphor, 98%
Packaging: 5g
Price: $48.1
Updated: 2021/12/16

Alfa Aesar

Product number: B23469
Product name: (1S)-(-)-Camphor, 98%
Packaging: 25g
Price: $159
Updated: 2021/12/16

Cayman Chemical

Product number: 23176
Product name: (1S)-(–)-Camphor
Purity: ≥98%
Packaging: 100mg
Price: $108
Updated: 2023/06/20

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(-)-CAMPHOR Chemical Properties,Usage,Production

Uses

(1S,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one also known by its common name as (-)-Camphor is a chiral intermediate of camphor and is used as a flavour additive in foods and sweetners.

Chemical Properties

white crystals

Uses

(1S)-(-)-Camphor is used as chiral intermediate and chiral auxiliary precursor. It is used in the synthesis of high-potency sweeteners. It acts as catalytic agent and petrochemical additive.

Definition

ChEBI: The S-enantiomer of camphor.

General Description

Colorless or white crystals. Fragrant and penetrating odor. Slightly bitter and cooling taste. Odor index at 68°F: 40. Flash point 149°F. Burns with a bright, smoky flame. Sublimes appreciably at room temperature and pressure; 14% sublimes within 60 minutes at 176°F and 12 mm Hg.

Air & Water Reactions

Flammable. Slightly water soluble.

Reactivity Profile

(-)-CAMPHOR may be sensitive to heat and direct sunlight. Incompatible with strong oxidizing agents, strong reducing agents and chlorinated solvents. Also incompatible with potassium permanganate. Salts of any kind should not be added to (-)-CAMPHOR in water. Reacts violently with chromic anhydride .

Fire Hazard

(-)-CAMPHOR is flammable.

Purification Methods

Crystallise it from EtOH, 50% EtOH/water, MeOH, or pet ether or from glacial acetic acid by addition of water. It can be sublimed (50o/14mm) and also fractionally crystallised from its own melt. It is steam volatile. It should be stored in tight containers as it is appreciably volatile at room temperature. The solubility is 0.1% (H2O), 100% (EtOH), 173% (Et2O) and 300%

(-)-CAMPHOR Preparation Products And Raw materials

Raw materials

Preparation Products

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(-)-CAMPHOR Suppliers

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View Lastest Price from (-)-CAMPHOR manufacturers

Wuhan Han Sheng New Material Technology Co.，Ltd

Product: (1s,4s)-(-)-campho 464-48-2
Price: US $3.57/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2023-11-15

Wuhan Han Sheng New Material Technology Co.，Ltd

Product: (-)-Alcanfor 464-48-2
Price: US $3.58/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2023-11-15

Wuhan Han Sheng New Material Technology Co.，Ltd

Product: CAMPHOR 464-48-2
Price: US $3.59/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2023-11-15

464-48-2, (-)-CAMPHORRelated Search:

L(-)-10-Camphorsulfonyl chloride (1R)-(-)-10-Camphorsulfonic acid (2R)-Bornane-10,2-sultam (-)-CAMPHORCARBOXYLIC ACID S-(-)-3-Bromocamphor (1S)-(+)-CAMPHORQUINONE (1S,E)-(-)-Camphorquinone 3-oxime (-)-CAMPHOR PRASEODYM(III)-TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-I-CAMPHORATE] Camphor (1R)-(-)-10-CAMPHORSULFONIC ACID, AMMONIUM SALT (-)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE (7,7-DIMETHYL-2-OXO-BICYCLO[2.2.1]HEPT-1-YL)-METHANESULFONYL CHLORIDE 3-(HEPTAFLUOROBUTYRYL)-I-CAMPHOR CAMPHORQUINONE, -S-(+)-(RG) (-)-CAMPHORACETIC ACID 3-BROMO-7-(BROMOMETHYL)-1,7-DIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE 7-(BROMOMETHYL)-1,7-DIMETHYLBICYCLO[2.2.1]HEPTANE-2,3-DIONE

(-)-Alcanfor

(1s,4s)-(-)-campho

7,7-trimethyl-(1s)-bicyclo(2.2.1)heptan-2-on

7,7-trimethyl-(1s)-bicyclo[2.2.1]heptan-2-on

Camphor, (1S,4S)-(-)-

Camphor, l-, (-)-

CAMPHORE

Levo-(-)-camphor

S-(-)-camphor

CAMPHOR, -(1S)-(-)-

(-)-L-CAMPHOR

(-)-Camphor

(1S)-()-Camphor,()-Camphor, (1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

L(-)-CaMphor, tech. 10GR

(1S)-(-)-CAMPHOR FOR SYNTHESIS

(1S)-(-)-Camphor 95%

L-(-)-CAMPHOR

L-(-)-2-KETO-1,7,7-TRIMETHYLNORCAMPHANONE

L-(-)-2-CAMPHANONE

L-(-)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE

(1S)-(-)-CAMPHOR

(1S)-CAMPHOR

(1S)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE

1-(-)CAMPHOR

CAMPHOR DAB 8

(-)-CAMPHOR, STANDARD FOR GC

(-)-Camphor=Kampfer

L-(-)-Camphor,99%

(1S)-(-)-Camphor,99%

L(-)-Camphor, tech.

Bicyclo2.2.1heptan-2-one, 1,7,7-trimethyl-, (1S,4S)-

CAMPHOR, (-)-(RG)

(1S,4S)-(-)-Camphor

Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1S)-

Camphor, (1S,4S)-(-)- (8CI)

NSC 26351

(-)-Camphor, (1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

(1S,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

[1S,4S,(-)]-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

Camphor Camphor

(-)-Camphor &gt

(-)-Alcanfor

464-48-2

464-48-4

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