ChemicalBook > CAS DataBase List > L(-)-10-Camphorsulfonyl chloride

L(-)-10-Camphorsulfonyl chloride

Product Name
L(-)-10-Camphorsulfonyl chloride
CAS No.
39262-22-1
Chemical Name
L(-)-10-Camphorsulfonyl chloride
Synonyms
((1R,4S)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride;(1R)-(-)-10-CamphorsuL;R)-()-10-CaMphorsulfony;L(-)Camphor sulfonyl chloride;(-)-10-CAMPHORSULFONYL CHLORIDE;(-)-10-Camphorsulfonyl Chloride;(-)-CAMPHOR-10-SULFONYL CHLORIDE;L(-)-10-CAMPHORSULFONYL CHLORIDE;(+)-camphor-10-sulfonyl chloride;L-(-)-1-Camphorsulfonyl chloride
CBNumber
CB0356635
Molecular Formula
C10H15ClO3S
Formula Weight
250.74
MOL File
39262-22-1.mol
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L(-)-10-Camphorsulfonyl chloride Property

Melting point:
66-68 °C(lit.)
alpha 
-33 º (c=3, chloroform)
Boiling point:
349.4±15.0 °C(Predicted)
Density 
1.331±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Acetone, Dichloromethane, Ethyl Acetate, Methanol
form 
Solid
color 
White
optical activity
[α]18/D 33°, c = 3 in chloroform
Water Solubility 
Decomposes
Sensitive 
Moisture Sensitive
BRN 
3205975
InChIKey
BGABKEVTHIJBIW-UHFFFAOYSA-N
CAS DataBase Reference
39262-22-1(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10-21
HazardClass 
8
PackingGroup 
II
HS Code 
29147090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
301949
Product name
(1R)-(?)-10-Camphorsulfonyl chloride
Purity
97%
Packaging
5g
Price
$65.6
Updated
2023/01/07
TCI Chemical
Product number
C1308
Product name
(-)-10-Camphorsulfonyl Chloride
Purity
>98.0%(T)
Packaging
5g
Price
$42
Updated
2024/03/01
TCI Chemical
Product number
C1308
Product name
(-)-10-Camphorsulfonyl Chloride
Purity
>98.0%(T)
Packaging
25g
Price
$168
Updated
2024/03/01
TRC
Product number
C175070
Product name
(1R)-(?)-10-Camphorsulfonyl chloride
Packaging
10g
Price
$415
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0415093
Product name
(1R)-(-)-CAMPHOR-10-SULFONYL CHLORIDE
Purity
95.00%
Packaging
2G
Price
$825
Updated
2021/12/16
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L(-)-10-Camphorsulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

A chiral derivative of Camphor.

Uses

L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation.

Purification Methods

If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]

L(-)-10-Camphorsulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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L(-)-10-Camphorsulfonyl chloride Suppliers

Shanghai Chang-Gen Chemical Technology Co., Ltd.
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021-69106814 13917161715
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3007500651@qq.com
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China
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Shanghai Boyle Chemical Co., Ltd.
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021-50182298 021-50180596
Fax
+86-21-57758967
Email
sales@boylechem.com
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China
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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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86-10-82849933
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jkinfo@jkchemical.com
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006608290; 18621169109
Fax
86-21-61259102
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market03@meryer.com
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China
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Alfa Aesar
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400-6106006
Fax
021-67582001/03/05
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saleschina@alfa-asia.com
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China
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
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021-67121385
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Sales-CN@TCIchemicals.com
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China
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Energy Chemical
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021-58436166
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Capot Chemical Co., Ltd
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+86 (0) 571 85 58 67 18
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0086-571-85864795
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Beijing Ouhe Technology Co., Ltd
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010-82967028 13552068683
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+86-10-82967029
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2355560935@qq.com
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China
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JinYan Chemicals(ShangHai) Co.,Ltd.
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13817811078
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86-021-50426522,50426273
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sales@jingyan-chemical.com
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China
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View Lastest Price from L(-)-10-Camphorsulfonyl chloride manufacturers

Hebei Mojin Biotechnology Co., Ltd
Product
L(-)-10-Camphorsulfonyl chloride 39262-22-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-31
Hebei Guanlang Biotechnology Co., Ltd.
Product
L(-)-10-Camphorsulfonyl chloride 39262-22-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-09-01
Zhuozhou Wenxi import and Export Co., Ltd
Product
L(-)-10-Camphorsulfonyl chloride 39262-22-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

39262-22-1, L(-)-10-Camphorsulfonyl chlorideRelated Search:


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  • (7,7-Dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonyl chloride
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  • (-)-10-Camphorsulfonyl Chloride
  • 39262-22-1
  • C10H15O3Cl
  • Bicyclic Monoterpenes
  • Terpenes
  • for Resolution of Bases
  • for Resolution of Alcohols & Thiols
  • Optical Resolution
  • SULFONYL CHLORIDE
  • Peptide
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Sulfonyl Chlorides
  • chiral
  • Chiral Reagents
  • Bicyclic Monoterpenes
  • Biochemistry
  • for Resolution of Alcohols & Thiols
  • for Resolution of Bases
  • Optical Resolution
  • Synthetic Organic Chemistry
  • Terpenes