ChemicalBook > CAS DataBase List > L(-)-10-Camphorsulfonyl chloride

L(-)-10-Camphorsulfonyl chloride

Product Name
L(-)-10-Camphorsulfonyl chloride
CAS No.
39262-22-1
Chemical Name
L(-)-10-Camphorsulfonyl chloride
Synonyms
(1R)-(−(1R)-(-)-10-CamphorsuL;R)-()-10-CaMphorsulfony;L(-)Camphor sulfonyl chloride;(-)-10-CAMPHORSULFONYL CHLORIDE;(-)-10-Camphorsulfonyl Chloride;(-)-CAMPHOR-10-SULFONYL CHLORIDE;L(-)-10-CAMPHORSULFONYL CHLORIDE;L-10- of caMphorsulfonyl chloride;(-)-Camphor-10-sulphonyl chloride
CBNumber
CB0356635
Molecular Formula
C10H15ClO3S
Formula Weight
250.74
MOL File
39262-22-1.mol
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L(-)-10-Camphorsulfonyl chloride Property

Melting point:
66-68 °C(lit.)
alpha 
-33 º (c=3, chloroform)
Boiling point:
349.4±15.0 °C(Predicted)
Density 
1.331±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
optical activity
[α]18/D 33°, c = 3 in chloroform
Water Solubility 
Decomposes
Sensitive 
Moisture Sensitive
BRN 
3205975
InChIKey
BGABKEVTHIJBIW-UHFFFAOYSA-N
CAS DataBase Reference
39262-22-1(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10-21
HazardClass 
8
PackingGroup 
II
HS Code 
29147090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

P390Absorb spillage to prevent material damage.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
301949
Product name
(1R)-(?)-10-Camphorsulfonyl chloride
Purity
97%
Packaging
5g
Price
$80.8
Updated
2021/03/22
TCI Chemical
Product number
C1308
Product name
(-)-10-Camphorsulfonyl Chloride
Purity
>98.0%(T)
Packaging
5g
Price
$33
Updated
2021/03/22
TCI Chemical
Product number
C1308
Product name
(-)-10-Camphorsulfonyl Chloride
Purity
>98.0%(T)
Packaging
25g
Price
$96
Updated
2021/03/22
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L(-)-10-Camphorsulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

A chiral derivative of Camphor

Uses

L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation.

Purification Methods

If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]

L(-)-10-Camphorsulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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L(-)-10-Camphorsulfonyl chloride Suppliers

Shanghai DiBai Chemicals Co., Ltd.
Tel
021-54359730-
Fax
021-54353864
Email
info@chemxyz.com
Country
China
ProdList
4000
Advantage
60
Shanghai Boyle Chemical Co., Ltd.
Tel
Mr Qiu:021-50182298(Demestic market) Miss Xu:021-50180596(Abroad market)
Fax
+86-21-57758967
Email
sales@boylechem.com
Country
China
ProdList
2213
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J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40265
Advantage
62
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30160
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24555
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Energy Chemical
Tel
021-58432009-
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44068
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18227
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Beijing Ouhe Technology Co., Ltd
Tel
010-82967028-
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12282
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078,021-50426030
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
10006
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60
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View Lastest Price from L(-)-10-Camphorsulfonyl chloride manufacturers

Career Henan Chemical Co
Product
L(-)-10-Camphorsulfonyl chloride 39262-22-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KGS
Release date
2019-12-31

39262-22-1, L(-)-10-Camphorsulfonyl chlorideRelated Search:


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  • 39262-22-1
  • C10H15O3Cl
  • Bicyclic Monoterpenes
  • Terpenes
  • for Resolution of Bases
  • for Resolution of Alcohols & Thiols
  • Optical Resolution
  • SULFONYL CHLORIDE
  • Peptide
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Sulfonyl Chlorides
  • chiral
  • Chiral Reagents
  • Bicyclic Monoterpenes
  • Biochemistry
  • for Resolution of Alcohols & Thiols
  • for Resolution of Bases
  • Optical Resolution
  • Synthetic Organic Chemistry
  • Terpenes