ChemicalBook > CAS DataBase List > 2-Bromopyridine-4-carboxylic acid

2-Bromopyridine-4-carboxylic acid

Product Name
2-Bromopyridine-4-carboxylic acid
CAS No.
66572-56-3
Chemical Name
2-Bromopyridine-4-carboxylic acid
Synonyms
2-BROMOISONICOTINIC ACID;RARECHEM AL BE 1524;IFLAB-BB F1926-0035;2-BroMoisonicotinic;2-Bromopyridine-4-ca;2-bromoisonicotic acid;2-bromo-4-piconlic acid;2-bromo-4-picolinic acid;2-BroMo-4-carboxy-pyridine;2-Bromopyridine-4-carboxyL
CBNumber
CB3147405
Molecular Formula
C6H4BrNO2
Formula Weight
202.01
MOL File
66572-56-3.mol
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2-Bromopyridine-4-carboxylic acid Property

Melting point:
229-231°C
Boiling point:
447.2±30.0 °C(Predicted)
Density 
1.813±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
2.98±0.10(Predicted)
form 
Crystals or Crystalline Powder
color 
White
BRN 
471895
InChI
InChI=1S/C6H4BrNO2/c7-5-3-4(6(9)10)1-2-8-5/h1-3H,(H,9,10)
InChIKey
YBTKGKVQEXAYEM-UHFFFAOYSA-N
SMILES
C1(Br)=NC=CC(C(O)=O)=C1
CAS DataBase Reference
66572-56-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-36/37
WGK Germany 
3
Hazard Note 
Irritant/Keep Cold
HazardClass 
IRRITANT
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
703990
Product name
2-Bromopyridine-4-carboxylic acid
Purity
97%
Packaging
5g
Price
$92.45
Updated
2025/07/31
Sigma-Aldrich
Product number
703990
Product name
2-Bromopyridine-4-carboxylic acid
Purity
97%
Packaging
1g
Price
$48
Updated
2023/06/20
TCI Chemical
Product number
B3368
Product name
2-Bromoisonicotinic Acid
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$23
Updated
2025/07/31
TCI Chemical
Product number
B3368
Product name
2-Bromoisonicotinic Acid
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$71
Updated
2025/07/31
TRC
Product number
B687923
Product name
2-Bromoisonicotinic Acid
Packaging
10mg
Price
$45
Updated
2021/12/16
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2-Bromopyridine-4-carboxylic acid Chemical Properties,Usage,Production

Chemical Properties

White to light brown powder

Uses

2-Bromoisonicotinic acid (CAS 66572-56-3) is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

Application

2-Bromopyridine-4-carboxylic acid is a kind of Pyridine carboxylic acid compounds, it can be used in medicine synthesis.

Health Hazard

Accidental contact with 2-Bromopyridine-4-carboxylic acid causes skin irritation and serious eye irritation.

Synthesis

4926-28-7

66572-56-3

General procedure for the synthesis of 2-bromo-4-pyridinecarboxylic acid from 2-bromo-4-methylpyridine: To a stirred solution of 29.0 g (69 mmol) of 2-bromo-4-methylpyridine dissolved in 150 mL of concentrated sulfuric acid was added batchwise 67.9 g (231 mmol) of potassium dichromate. The reaction was cooled using an ice bath to maintain a constant temperature. After addition, the reaction mixture was continued to be stirred at room temperature for 2 hours. Subsequently, the reaction mixture was slowly poured into 2 L of ice water and stirred at room temperature for 1 hour. The resulting crystals were collected by filtration, washed with water until the eluent was colorless, and finally dried under vacuum to give 30.0 g (88% yield) of 2-bromo-4-pyridinecarboxylic acid.

References

[1] Patent: US2011/111046, 2011, A1. Location in patent: Page/Page column 17; 18
[2] Patent: WO2011/58473, 2011, A1. Location in patent: Page/Page column 36; 37
[3] Chemical and Pharmaceutical Bulletin, 1990, vol. 38, # 9, p. 2446 - 2458
[4] Patent: US2008/51397, 2008, A1. Location in patent: Page/Page column 9; 24
[5] Polyhedron, 2016, vol. 118, p. 159 - 170

2-Bromopyridine-4-carboxylic acid Preparation Products And Raw materials

Raw materials

2-Bromo-4-methylpyridine Potassium dichromate Potassium permanganate

Preparation Products

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2-Bromopyridine-4-carboxylic acid Suppliers

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View Lastest Price from 2-Bromopyridine-4-carboxylic acid manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
2-Bromopyridine-4-carboxylic acid 66572-56-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-22
Shaanxi Dideu New Materials Co. Ltd
Product
2-Bromopyridine-4-carboxylic acid 66572-56-3
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-03-05
Henan Fengda Chemical Co., Ltd
Product
2-Bromopyridine-4-carboxylic acid 66572-56-3
Price
US $3.00-0.20/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-26

66572-56-3, 2-Bromopyridine-4-carboxylic acidRelated Search:

6-BROMOPYRIDINE-2-CARBOXYLIC ACID 2-Bromo-4-methylpyridine 2-Bromo-3-methylbenzaldehyde 2-Bromo-4-nitroimidazole 2-Bromo-4-fluoropyridine 2-Bromo-5,6-diphenylpyrazine 2-Bromo-3-trifluoromethylpyridine 2-Bromo-4-chloropyridine 2-Bromo-3-fluoropyridine 3-Amino-2-bromopyridine BenzenaMine, 2-broMo-5-fluoro-4-nitro- 2-Bromo-3,5-dichloropyridine Pyridine, 2-bromo-3,5-dichloro-6-methyl- 5-Amino-2-bromo-3-methylpyridine 2-Bromo-3-methyl-5-chloropyridine 2-Bromo-3-methyl-5-nitropyridine 2-Bromo-3-nitropyridine 2-BROMO-3-CHLORO-5-NITROPYRIDINE

  • IFLAB-BB F1926-0035
  • 2-BROMOPYRIDINE-4-CARBOXYLIC ACID
  • 2-BROMOISONICOTINIC ACID
  • 2-BROMO-4-PYRIDINECARBOXYLIC ACID
  • 4-PYRIDINECARBOXYLIC ACID, 2-BROMO-
  • RARECHEM AL BE 1524
  • 2-bromo-4-picolinic acid
  • 2-BROMO-4-PYRIDINECARBOXYLIC ACID / 2-BROMOISONICOTINIC ACID
  • 2-Bromoisonicotinic acid , 2-Bromopyridine-4-carboxylic acid
  • 2-Bromoisonicotinic acid ,98%
  • 2-bromoisonicotic acid
  • 2-bromopyridin-4-carboxylic acid
  • 2-BroMo-4-carboxy-pyridine
  • 2-Bromopyridine-4-carboxylic acid ,98%
  • 2-Bromopyridine-4-ca
  • 2-BroMoisonicotinic
  • 2-BroMo-4-pyridinecorboxylc
  • 2-Bromopyridine-4-carboxylic acid, 2-Bromo-4-carboxypyridine
  • 2-BroMopyridine-4-carboxylic Acid, 97+%
  • 2 - broMide pyridine - 4 - forMic acid
  • 2-Bromopyridine-4-carboxylic acid 97%
  • 2-Bromoisonicotinic Acid &gt
  • 2-Bromopyridine-4-carboxyL
  • 2-Bromopyridine-4-carboxylic acid ISO 9001：2015 REACH
  • TIANFUCHEM--66572-56-3--2-Bromopyridine-4-carboxylic acid
  • 2-bromopyridine-4-carboxylic acid(2-bromoisonicotinic acid)
  • 2-bromo-4-piconlic acid
  • 2-Bromopyridine-4-carboxylicaci
  • 66572-56-3
  • 66592-56-3
  • 6572-56-3
  • C6H4NO2Br
  • Heterocycle-Pyridine series
  • Picolinic acid series
  • blocks
  • Bromides
  • Carboxes
  • Pyridines
  • pyridine derivative
  • pharmacetical
  • Carboxylic Acids
  • Pyridine
  • Carboxylic Acids