ChemicalBook > CAS DataBase List > 3,4-Dimethoxy-3-cyclobutene-1,2-dione

3,4-Dimethoxy-3-cyclobutene-1,2-dione

Product Name
3,4-Dimethoxy-3-cyclobutene-1,2-dione
CAS No.
5222-73-1
Chemical Name
3,4-Dimethoxy-3-cyclobutene-1,2-dione
Synonyms
3,4-DIMETHOXYCYCLOBUT-3-ENE-1,2-DIONE;DIMETHYL SQUARATE;diMethoxycyclobut-3-ene-1,2-dione;3,4-Dimethoxy-3-cycl;Squaric acid dimethyl e;SQUARIC ACID DIMETHYL ESTER;3,4-DIMETHOXYCYCLOBUTANE-1,2-DIONE;1,2-Dimethoxycyclobutene-3,4-dione;3,4-DIMETHOXY-3-CYCLOBUTENE-1,2-DIONE;1,2-Dimethoxy-1-cyclobutene-3,4-dione
CBNumber
CB3165164
Molecular Formula
C6H6O4
Formula Weight
142.11
MOL File
5222-73-1.mol
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3,4-Dimethoxy-3-cyclobutene-1,2-dione Property

Melting point:
55-57 °C (lit.)
Boiling point:
219.65°C (rough estimate)
Density 
1.3863 (rough estimate)
refractive index 
1.5800 (estimate)
storage temp. 
2-8°C
solubility 
DMSO, Methanol (Slightly)
form 
Solid
color 
Off-White to Pale Brown
Water Solubility 
Very soluble in water.
InChIKey
SZBNZTGCAMLMJY-UHFFFAOYSA-N
CAS DataBase Reference
5222-73-1(CAS DataBase Reference)
NIST Chemistry Reference
3,4-Dimethoxy-3-cyclobutene-1,2-dione(5222-73-1)
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Safety

Risk Statements 
42/43
Safety Statements 
22-24/25-26-36/37/39
WGK Germany 
3
HS Code 
29145090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
377406
Product name
3,4-Dimethoxy-3-cyclobutene-1,2-dione
Purity
99%
Packaging
1g
Price
$16.5
Updated
2024/03/01
Sigma-Aldrich
Product number
377406
Product name
3,4-Dimethoxy-3-cyclobutene-1,2-dione
Purity
99%
Packaging
5g
Price
$104
Updated
2024/03/01
TCI Chemical
Product number
D2099
Product name
3,4-Dimethoxy-3-cyclobutene-1,2-dione
Purity
>98.0%(GC)
Packaging
1g
Price
$44
Updated
2024/03/01
TCI Chemical
Product number
D2099
Product name
3,4-Dimethoxy-3-cyclobutene-1,2-dione
Purity
>98.0%(GC)
Packaging
5g
Price
$134
Updated
2024/03/01
Alfa Aesar
Product number
A18186
Product name
3,4-Dimethoxy-3-cyclobutene-1,2-dione, 98%
Packaging
1g
Price
$50.65
Updated
2024/03/01
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3,4-Dimethoxy-3-cyclobutene-1,2-dione Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder

Uses

3,4-Dimethoxy-3-cyclobutene-1,2-dione (Dimethyl squarate) finds it uses in the synthesis of chiral squaramides, highly enantioselective catalyst for the Friedel-Crafts reactions of indoles, 3-(hydroxyamino)-4-methoxy-3-cyclobutene-1,2-dione, squarate derivatives of the O-SP-core antigens, methyl squarate derivative of the Ogawa O-SP-core antigen, o-quinodimethanes, benzocyclobutenes, quinones. It is employed as a starting material in the preparation of o-quinodimethanes, benzocyclobutenes, and quinones.

General Description

3,4-Dimethoxy-3-cyclobutene-1,2-dione (Dimethyl squarate) is a cyclobutene derivative. It reacts with hydroxylamine derivatives to afford 3-hydroxyamino-4-methoxy-3-cyclobutene-1,2-diones.

3,4-Dimethoxy-3-cyclobutene-1,2-dione Preparation Products And Raw materials

Raw materials

Preparation Products

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3,4-Dimethoxy-3-cyclobutene-1,2-dione Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
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jkinfo@jkchemical.com
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China
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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021-61259108 18621169109
Fax
86-21-61259102
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market03@meryer.com
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China
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
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saleschina@alfa-asia.com
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China
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TAIYUAN RHF CO.,LTD.
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+86 351 7031519
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+86 351 7031519
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sales@RHFChem.com
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TCI (Shanghai) Development Co., Ltd.
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Sales-CN@TCIchemicals.com
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Energy Chemical
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+86 (0) 571 85 58 67 18
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0086-571-85864795
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Beijing Ouhe Technology Co., Ltd
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010-82967028 13552068683
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+86-10-82967029
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Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956
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0573-85285100
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isenchem@163.com
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China
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Accela ChemBio Co.,Ltd.
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021-50795510 4000665055
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021-50795055
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sales@accelachem.com
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View Lastest Price from 3,4-Dimethoxy-3-cyclobutene-1,2-dione manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
3,4-Dimethoxy-3-cyclobutene-1,2-dione 5222-73-1
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-30
Henan Aochuang Chemical Co.,Ltd.
Product
3,4-Dimethoxy-3-cyclobutene-1,2-dione 5222-73-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-19
Career Henan Chemical Co
Product
3,4-Dimethoxy-3-cyclobutene-1,2-dione 5222-73-1
Price
US $7.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2018-12-14

5222-73-1, 3,4-Dimethoxy-3-cyclobutene-1,2-dioneRelated Search:


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  • SQUARIC ACID DIMETHYL ESTER
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  • 3,4-DIMETHOXYCYCLOBUT-3-ENE-1,2-DIONE
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  • Dimethyl squarate, Squaric acid dimethyl ester
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  • 3.4-diMethoxycyclobutane-1.2-dione. DiMethyl squarate
  • 8,9-dimethoxy-2-[[2-(4-morpholinyl)ethylamino]-oxomethyl]-5,6-dihydropyrrolo[2,1-a]isoquinoline-3-carboxylic acid
  • 3,4-Dimethoxy-3-cyclobutene-1,2-dione&gt
  • 5222-73-1
  • CH3O2C4O2
  • C6H6O4
  • Ketones
  • Organic Building Blocks
  • C3 to C6
  • Simple 4-Membered Ring Compounds
  • Cyclobutanes & Cyclobutenes
  • Carbonyl Compounds
  • Building Blocks
  • Cyclobutanes & Cyclobutenes
  • Simple 4-Membered Ring Compounds
  • Ring Systems
  • Aluminium foil bag/Fluoride bottle or on your request
  • Pyrimidines