Julolidine

Product Name: Julolidine
CAS No.: 479-59-4
Chemical Name: Julolidine
Synonyms: JULOLIDINE;Julolidine>Julolidine,98%;Julolidine, 98% 25GR;Julolidine USP/EP/BP;Julolidine>97.0%(GC&T);5h-benzo[ij]quinolizine,2,3,6,7-tetrahydro-1;2,3,6,7-TETRAHYDRO-1H,5H-BENZO[IJ]QUINOLIZINE;1,2,3,5,6,7-Hexahydropyrido[3,2,1-ij]quinoline;2,3,6,7-Tetrahydro-1H,5H-benzop[ij]quinolizine
CBNumber: CB3167092
Molecular Formula: C12H15N
Formula Weight: 173.25
MOL File: 479-59-4.mol

More

Less

Julolidine Property

Melting point:: 34-36 °C(lit.)
Boiling point:: 170-173°C 31mm
Density: 1.0030
refractive index: 1.5680
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
pka: 6.54±0.20(Predicted)
form: Liquid After Melting
color: Clear yellow to orange-brown
Water Solubility: Soluble in toluene. Insoluble in water.
Sensitive: Air Sensitive
BRN: 139925
InChIKey: DZFWNZJKBJOGFQ-UHFFFAOYSA-N
CAS DataBase Reference: 479-59-4(CAS DataBase Reference)
NIST Chemistry Reference: Julolidine(479-59-4)
EPA Substance Registry System: 1H,5H-Benzo[ij]quinolizine, 2,3,6,7-tetrahydro- (479-59-4)

More

Less

Safety

Risk Statements: 52/53
Safety Statements: 24/25-61
WGK Germany: 3
TSCA: Yes
HS Code: 29339900

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: J1001
Product name: Julolidine
Purity: 97%
Packaging: 5g
Price: $81
Updated: 2024/03/01

Sigma-Aldrich

Product number: J1001
Product name: Julolidine
Purity: 97%
Packaging: 25g
Price: $415
Updated: 2023/06/20

TCI Chemical

Product number: J0007
Product name: Julolidine
Purity: >97.0%(GC)(T)
Packaging: 5g
Price: $95
Updated: 2024/03/01

TCI Chemical

Product number: J0007
Product name: Julolidine
Purity: >97.0%(GC)(T)
Packaging: 25g
Price: $443
Updated: 2024/03/01

Alfa Aesar

Product number: B22976
Product name: Julolidine, 98%
Packaging: 1g
Price: $27.65
Updated: 2024/03/01

More

Less

Julolidine Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW TO ORANGE-BROWN LIQUID AFTER MELTING

Uses

Julolidine used as amine building block and in chemoluminescent dye. Also used in photoconductive materials, chemiluminescence substances, chromogenic substrates in analytical redox reactions, dye intermediates, potential antidepressants and tranquilizers, nonlinear optical materials, high sensitivity photopolymerizable materials, and for improving color stability in photography.

Purification Methods

Purify julolidine by dissolving it in dilute HCl, steam is bubbled through the solution and the residual acidic solution is basified with 10N NaOH, extracted with Et2O, washed with H2O, dried (NaOH pellets), filtered, evaporated and distilled in vacuo. The distillate crystallises on cooling (m 39-40o). It develops a red colour on standing in contact with air for several days. The colour can be removed by distilling or dissolving in 2-3 parts of hexane, adding charcoal, filtering and cooling in an Me2CO/Dry-ice bath when julolidine crystallises out (85-90% yield m 39-40o). The hydrobromide [83646-41-7] has m 218o (239-242o), the picrate has m 174o(165o) and the methiodide crystallises from MeOH, with m 186o [Glass & Weisberger Org Synth Coll Vol III 504 1955, Smith & Yu J Org Chem 17 1285 1952, Beilstein 20 H 332, 20 I 133, 20 II 214, 20 III/IV 3281.] Highly TOXIC.

Julolidine Preparation Products And Raw materials

Raw materials

Tetrahydroquinoline 1-Bromo-3-chloropropane

Preparation Products

More

Less

Julolidine Suppliers

Americas 1 Belgium 3 China 83 Europe 1 Germany 6 India 7 Japan 3 Slovakia 1 Switzerland 5 The Netherlands 1 United Kingdom 12 United States 25 Global 148

Tianjin Nuokang Pharmaceutical Technology Co., Ltd.

Tel: 022-23989838 13810451150
Email: 44766350@qq.com
Country: China
ProdList: 1918
Advantage: 58

Yantai ShengKailun Chemical Technology Co., Ltd.

Tel: 13356901049
Fax: QQ：1025383091
Email: 3119594100@qq.com
Country: China
ProdList: 7964
Advantage: 55

Yantai Shengkailun Chemical Technology Co., Ltd.

Tel: 15552437730
Email: 1701654643@qq.com
Country: China
ProdList: 9167
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3572
Advantage: 66

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

More

Less

View Lastest Price from Julolidine manufacturers

Career Henan Chemical Co

Product: Julolidine 479-59-4
Price: US $1.00/KG
Min. Order: 1g
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-10

Nanjing jinheyou Trading Co., Ltd.

Product: Julolidine 479-59-4
Price: US $0.00/g
Min. Order: 1g
Purity: 99.5%min
Supply Ability: 20kg/week
Release date: 2019-10-31

479-59-4, JulolidineRelated Search:

MEQUITAZINE Hydrochlorothiazide Benzo[b]thien-2-ylboronic acid Coumarin 337 8-HYDROXYJULOLIDINE SULFORHODAMINE 101 9-Formyl-8-hydroxy-1,1,7,7-tetramethyljulolidine Coumarin 314T Coumarin 314 Coumarin 106 Coumarin 338 Coumarin 334 Coumarin 343 Coumarin 102 2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizine-9-carboxaldehyde Coumarin 153 SULFORHODAMINE 101 ACID CHLORIDE RHODAMINE 101 INNER SALT

JULOLIDINE

2,3,6,7-TETRAHYDRO-1H,5H-BENZO[IJ]QUINOLIZINE

2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3.2.1-IJ]QUINOLINE

1H,5H-BENZO[IJ]QUINOLIZINE, 2,3,6,7-TETRAHYDRO-

5h-benzo[ij]quinolizine,2,3,6,7-tetrahydro-1

Julolidine,98%

2,3,6,7-Tetrahydro-1H,5H-benzop[ij]quinolizine

Julolidine, 98% 25GR

1,2,3,5,6,7-Hexahydropyrido[3,2,1-ij]quinoline

Julolidine&gt

Julolidine>97.0%(GC&T)

Julolidine USP/EP/BP

479-59-4

Miscellaneous Natural Products