4-AMINO-3-BROMOBENZOIC ACID

Uses

Product Name: 4-AMINO-3-BROMOBENZOIC ACID
CAS No.: 6311-37-1
Chemical Name: 4-AMINO-3-BROMOBENZOIC ACID
Synonyms: CL228;NSC43549;ZR BE DVQ;BUTTPARK 35\03-06;RARECHEM AL BO 1227;4-Amino-3-Bromobenzoic;4-AMINO-3-BROMOBENZOIC ACID;4-AMINO-3-BROMOBENZIOC ACID;4-azanyl-3-bromo-benzoic acid;Benzoic acid, 4-amino-3-bromo-
CBNumber: CB3186561
Molecular Formula: C7H6BrNO2
Formula Weight: 216.03
MOL File: 6311-37-1.mol

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4-AMINO-3-BROMOBENZOIC ACID Property

Melting point:: 211-215 °C
Boiling point:: 368.5±32.0 °C(Predicted)
Density: 1.793±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: powder to crystal
pka: 4.47±0.10(Predicted)
color: White to Light yellow to Light orange
InChI: InChI=1S/C7H6BrNO2/c8-5-3-4(7(10)11)1-2-6(5)9/h1-3H,9H2,(H,10,11)
InChIKey: BFIVZIVVJNFTIQ-UHFFFAOYSA-N
SMILES: C(O)(=O)C1=CC=C(N)C(Br)=C1
CAS DataBase Reference: 6311-37-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36-37/38-36/37/38-22
Safety Statements: 26-37/39-36
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
Hazard Note: Irritant
HazardClass: 6.1
PackingGroup: Ⅲ
HS Code: 29224999

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 663484
Product name: 4-Amino-3-bromobenzoic acid
Purity: 97%
Packaging: 1g
Price: $25
Updated: 2023/06/20

Sigma-Aldrich

Product number: 663484
Product name: 4-Amino-3-bromobenzoic acid
Purity: 97%
Packaging: 10g
Price: $238
Updated: 2023/01/07

TCI Chemical

Product number: A1969
Product name: 4-Amino-3-bromobenzoic Acid
Purity: >98.0%(T)
Packaging: 5g
Price: $84
Updated: 2025/07/31

TRC

Product number: A602493
Product name: 4-Amino-3-bromobenzoic acid
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA55495
Product name: 4-Amino-3-bromobenzoic acid
Packaging: 25g
Price: $50
Updated: 2021/12/16

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4-AMINO-3-BROMOBENZOIC ACID Chemical Properties,Usage,Production

Uses

4-Amino-3-bromobenzoic acid is a useful research chemical.

Chemical Properties

White to light yellow crystal powder

Uses

peptide synthesis

reaction suitability

reaction type: solution phase peptide synthesis

Synthesis

150-13-0

6311-37-1

General procedure for the synthesis of 3-bromo-4-aminobenzoic acid from 4-aminobenzoic acid: 4-aminobenzoic acid (100 mmol) was dissolved in N,N-dimethylformamide (DMF, 50 mL), followed by the addition of N-bromosuccinimide (NBS, 100 mmol). The reaction mixture was stirred at room temperature for 18 hours. Upon completion of the reaction, the mixture was poured into water (100 mL) and a solid was precipitated. The product was collected by filtration, washed with water and dried under vacuum to afford the target compound 4-amino-3-bromobenzoic acid in 70% yield. The structure of the product was confirmed by 1H NMR (D6-DMSO): δ 6.10 (s, 2H), 6.78 (d, 1H), 7.63 (dd, 1H), 7.89 (d, 1H), 12.39 (br s, 1H).

References

[1] Russian Journal of Applied Chemistry, 2009, vol. 82, # 9, p. 1570 - 1576
[2] Journal of the American Chemical Society, 2010, vol. 132, # 6, p. 1734 - 1735
[3] Tetrahedron Letters, 2009, vol. 50, # 9, p. 1007 - 1009
[4] Journal of the Brazilian Chemical Society, 2010, vol. 21, # 3, p. 496 - 501
[5] Tetrahedron Letters, 2000, vol. 41, # 13, p. 2083 - 2085

4-AMINO-3-BROMOBENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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4-AMINO-3-BROMOBENZOIC ACID Suppliers

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View Lastest Price from 4-AMINO-3-BROMOBENZOIC ACID manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 4-AMINO-3-BROMOBENZOIC ACID 6311-37-1
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-03-08

Career Henan Chemical Co

Product: 4-AMINO-3-BROMOBENZOIC ACID 6311-37-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-12

6311-37-1, 4-AMINO-3-BROMOBENZOIC ACIDRelated Search:

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BUTTPARK 35\03-06

4-AMINO-3-BROMOBENZIOC ACID

4-AMINO-3-BROMOBENZOIC ACID

RARECHEM AL BO 1227

4-Amino-3-Bromobenzoic

NSC43549

4-Amino-3-bromobenzoic acid 97%

4-AMINO-3-BROMOBENZOIC ACID, 98.0%+(T)

4-azanyl-3-bromo-benzoic acid

CL228

4-Amino-3-bromobenzoic Acid &gt

Benzoic acid, 4-amino-3-bromo-

4-AMINO-3-BROMOBENZOIC ACID USP/EP/BP

ZR BE DVQ

6311-37-1

6311-28-1

Peptide Synthesis

Specialty Synthesis

Unnatural Amino Acid Derivatives

Aromatic Amino Acids

Carboxylic Acids

Phenyls & Phenyl-Het

Aromatic Amino Acids

Peptide Synthesis

Unnatural Amino Acid Derivatives

Carboxylic Acids

Phenyls & Phenyl-Het

Benzoic acid

Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts