BISMUTH(III) FLUORIDE

Product Name: BISMUTH(III) FLUORIDE
CAS No.: 7787-61-3
Chemical Name: BISMUTH(III) FLUORIDE
Synonyms: BISMUTH TRIFLUORIDE;BISMUTH FLUORIDE;Bismuthfluoride1;trifluoro-bismuthin;trifluorobismuthane;trifluoro-Bismuthine;Bismuth(Ⅲ) Fluoride;BISMUTH(III) FLUORIDE;Bismuthine, trifluoro-;BISMUTH(III) TRIFLUORIDE
CBNumber: CB3196539
Molecular Formula: BiF3
Formula Weight: 265.98
MOL File: 7787-61-3.mol

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BISMUTH(III) FLUORIDE Property

Melting point:

727 °C

Boiling point:

900°C

Density

8.3 g/mL at 25 °C(lit.)

refractive index

1.74

solubility

H2O: insoluble(lit.)

form

Powder

Specific Gravity

5.32

color

white-gray cubic crystals, crystalline

Water Solubility

Insoluble in water. Soluble in HF.

Crystal Structure

YF3 type

Sensitive

Hygroscopic

Merck

14,1265

crystal system

Nogata

Space group

Pnma

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.656	0.702	0.484	90	90	90	0.2228

Exposure limits

ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3

CAS DataBase Reference

7787-61-3(CAS DataBase Reference)

EPA Substance Registry System

Bismuthine, trifluoro- (7787-61-3)

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3260 8/PG 2
WGK Germany: 3
F: 10-21
Hazard Note: Corrosive
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 28261990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 401528
Product name: Bismuth(III) fluoride
Purity: ≥99.99% trace metals basis
Packaging: 5g
Price: $84.7
Updated: 2024/03/01

Alfa Aesar

Product number: 013075
Product name: Bismuth(III) fluoride, anhydrous, 99%
Packaging: 100g
Price: $117.65
Updated: 2024/03/01

Alfa Aesar

Product number: 013075
Product name: Bismuth(III) fluoride, anhydrous, 99%
Packaging: 25g
Price: $50.1
Updated: 2023/06/20

Strem Chemicals

Product number: 83-3000
Product name: Bismuth(III) fluoride (99.99+%-Bi) PURATREM
Packaging: 10g
Price: $71
Updated: 2024/03/01

Strem Chemicals

Product number: 83-3000
Product name: Bismuth(III) fluoride (99.99+%-Bi) PURATREM
Packaging: 50g
Price: $282
Updated: 2024/03/01

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BISMUTH(III) FLUORIDE Chemical Properties,Usage,Production

Chemical Properties

White Crystal or crystalline powder

Physical properties

Bismuth fluoride is a heavy, white (gray if impure) crystalline powder, practically insoluble in water. M.p. 725-730°C; d. 8.3. Cubic (dimorphous).

Uses

Bismuth fluoride is used in the manufacturing of bismuth pentafluoride. It is an attractive reagent and catalyst in organic synthesis owing to its low cost, and ease of handling. It is also used in polarography.

Uses

In the preparation of bismuth pentafluoride, q.v.

Preparation

The preparation method of Bismuth fluoride: Freshly precipitated bismuth hydroxide is evaporated to dryness several times in a Pt dish, using an excess of hydrofluoric acid. It is then calcined in a covered Pt crucible until the HF has completely evaporated.

BISMUTH(III) FLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BISMUTH(III) FLUORIDE Suppliers

Belgium 1 China 38 France 1 Germany 3 India 8 Japan 1 Russia 1 Switzerland 1 United Kingdom 11 United States 25 Global 90

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VWR International

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7787-61-3, BISMUTH(III) FLUORIDERelated Search:

BISMUTH TITANATE Triphenylbismuth Bismuth nitrate pentahydrate Bismuth trioxide BISMUTH SULFIDE BISMUTH NEODECANOATE Bismuth trichloride BISMUTH ACETATE BISMUTH(III) IODIDE BISMUTH TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) BISMUTH TELLURIDE BISMUTH(III) BROMIDE Bismuth Bismuth pentafluoride BISMUTH(III) FLUORIDE Bismuth (III) Fluoride Oxide,BISMUTH FLUORIDE, BASIC BISMUTH POTASSIUM FLUORIDE BISMUTH(III) FLUORIDE 99.9

BISMUTH(III) FLUORIDE

BISMUTH FLUORIDE

BISMUTH(III) TRIFLUORIDE

BISMUTH TRIFLUORIDE

Bismuthine, trifluoro-

trifluoro-bismuthin

trifluoro-Bismuthine

Bismuth(III) fluoride anhydrous

Bismuthfluoride1

Bismuthfluorideanhydrousoffwhitepowder

Bismuthfluoridewhitegrayxtl

Bismuth(III) fluoride 99.99

BISMUTH(III) FLUORIDE 98%

Bismuth(III)fluoride,anhydrous,99%

BISMUTH FLUORIDE, 99.999%

Bismuth(III)fluoride(99.99+%-Bi)PURATREM

Bismuth(III) fluoride 99.999%

Bismuth(III) trifluoride 99.5%

BISMUTH(III) FLUORIDE: (99.999%-BI) PURATREM

Bismuth(III) fluoride, 99.999% (metals basis)

Bismuth(III) fluoride 99.5%

Bismuth(III) fluoride >=99.99% trace metals basis

Bismuth(III) fluoride, 99.999% trace metals basis

Bismuth(III) fluoride,98%

Bismuth(Ⅲ) Fluoride

BISMUTH TRIFLUORIDE, ANH

Bismuth(III) fluoride, anhydrous 99.99%

Bismuth fluoride, ≥99.99%

trifluorobismuthane

7787-61-3

Bi3F

Bi1F3

Catalysis and Inorganic Chemistry

metal halide

Bismuth Salts

BismuthMetal and Ceramic Science

Catalysis and Inorganic Chemistry

Chemical Synthesis

Crystal Grade Inorganics

Salts