4-Benzofurazancarboxaldehyde

Product Name: 4-Benzofurazancarboxaldehyde
CAS No.: 32863-32-4
Chemical Name: 4-Benzofurazancarboxaldehyde
Synonyms: 4-Formylbenzofurazan;benzofurazan-4-carbaldehyde;4-BENZOFURAZANCARBOXALDEHYDE;Benzofurazon-4-Carboxaldehyde;4-FORMYL-2,1,3-BENZOXADIAZOLE;4-Benzofurazone Carboxaldehyde;2,1,3-Benzoxadiazol-4-aldehyde;2,1,3-Benzoxadiazole-4-aldehyde;4-Benzofurazancarboxaldehyde ,97%;4-FORMYL-BENZO[C][1,2,5]OXADIAZOLE
CBNumber: CB3203222
Molecular Formula: C7H4N2O2
Formula Weight: 148.12
MOL File: 32863-32-4.mol

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4-Benzofurazancarboxaldehyde Property

Melting point:: 100-102°C
Boiling point:: 277 °C
Density: 1.417
Flash point:: 121 °C
storage temp.: Inert atmosphere,2-8°C
solubility: Dichloromethane (Slightly), Chloroform (Slightly), Methanol (Slightly)
pka: -1.86±0.45(Predicted)
form: Solid
color: Light Brown
InChI: InChI=1S/C7H4N2O2/c10-4-5-2-1-3-6-7(5)9-11-8-6/h1-4H
InChIKey: YBBRQAXNTWMMFZ-UHFFFAOYSA-N
SMILES: N1=C2C=CC=C(C=O)C2=NO1

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
HazardClass: IRRITANT
HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: B4928
Product name: 2,1,3-Benzoxadiazole-4-carboxaldehyde
Purity: >98.0%(GC)
Packaging: 1g
Price: $138
Updated: 2021/12/16

TRC

Product number: B207680
Product name: 4-Benzofurazancarboxaldehyde
Packaging: 100mg
Price: $100
Updated: 2021/12/16

Matrix Scientific

Product number: 063012
Product name: 2,1,3-Benzoxadiazole-4-carbaldehyde
Packaging: 500mg
Price: $394
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB18218
Product name: 4-Benzofurazancarboxaldehyde
Packaging: 10g
Price: $400
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB18218
Product name: 4-Benzofurazancarboxaldehyde
Packaging: 25g
Price: $650
Updated: 2021/12/16

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4-Benzofurazancarboxaldehyde Chemical Properties,Usage,Production

Chemical Properties

Light Brown Solid

Uses

A synthetic intermediate for the production of Isradipine.

Synthesis

32863-30-2

32863-32-4

General procedure for the synthesis of benzodiazole-4-carbaldehyde from 4-(bromomethyl)benzo[c][1,2,5]oxadiazole: 4-(bromomethyl)benzo[c][1,2,5]oxadiazole (19.7 g, 0.1 mol), dimethylsulfoxide (DMSO, 15 mL), and sodium bicarbonate (10 g, 0.12 mol) were added to the reaction flask sequentially. The reaction mixture was heated to 100-150 °C under nitrogen protection. Upon completion of the reaction, the mixture was cooled to room temperature and subsequently extracted with deionized water and ethyl acetate. The organic layers were combined and washed with saturated sodium chloride solution. The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to remove the solvent to give 10.6 g of a light yellow solid product in 71.6% yield with a melting point of 108-109 °C.

References

[1] Patent: CN102285978, 2016, B. Location in patent: Paragraph 0031
[2] European Journal of Medicinal Chemistry, 1996, vol. 31, # 1, p. 3 - 10

4-Benzofurazancarboxaldehyde Preparation Products And Raw materials

Raw materials

2-CHLORO-3-NITROTOLUENE Sodium azide N-Bromosuccinimide Ethanol 2,2'-Azobis(2-methylpropionitrile) Toluene Potassium carbonate Carbon tetrachloride Dimethyl sulfoxide Triethyl phosphite

Preparation Products

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4-Benzofurazancarboxaldehyde Suppliers

Americas 1 Canada 2 China 152 Europe 2 France 1 Germany 4 India 12 The Netherlands 1 United Kingdom 6 United States 21 Global 202

Jiangsu Magic Biotechnology Co., Ltd

Tel: 13921770081
Email: svp01@magicbiotech.cn
Country: China
ProdList: 500
Advantage: 58

sinopharm

Tel: 13856035343
Email: 1074637616@qq.com
Country: China
ProdList: 20
Advantage: 58

Taizhou Yuxin Biotechnology Co., Ltd.,

Tel: +86-0576--88902229 +86-13968687450
Email: yuxin@yuxchem.com
Country: China
ProdList: 265
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Beijing Donghualituo Techonlogy Development Co.,Ltd.

Tel: 010-88425576
Fax: (+86)-10-88425546
Email: sales@dhltchem.com
Country: China
ProdList: 793
Advantage: 59

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 16075
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
Advantage: 50

Beijing Taiya Jie Technology Development Co., Ltd.

Tel: 021-33690831-8001 13552411790
Fax: 021-33690831
Email: postmaster@tyjchem.cn
Country: China
ProdList: 1542
Advantage: 55

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View Lastest Price from 4-Benzofurazancarboxaldehyde manufacturers

Apeloa production Co.,Limited

Product: 2,1,3-Benzoxadiazole-4-carbaldehyde 32863-32-4
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 1000
Release date: 2024-06-20

Hebei Chuanghai Biotechnology Co,.LTD

Product: 4-Benzofurazancarboxaldehyde 32863-32-4
Price: US $9.00/KG
Min. Order: 1KG
Purity: 99.8%
Supply Ability: 100tons
Release date: 2024-08-15

Jiangsu Magic Biotechnology Co., Ltd

Product: benzo[c][1,2,5]oxadiazole-4-carbaldehyde 32863-32-4
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20tons
Release date: 2023-10-11

32863-32-4, 4-BenzofurazancarboxaldehydeRelated Search:

5-(BROMOMETHYL)-2,1,3-BENZOXADIAZOLE Isopropyl 3-aminocrotonate 4-Methylbenzofurazan 3-oxid Methyl 3-aminocrotonate m-Phthalaldehyde Terephthalaldehyde 1-Nonanal 4-METHYL-BENZO(1,2,5)OXADIAZOLE o-Phthalaldehyde Paraldehyde Albendazole 2,1,3-Benzothiadiazole Benzo[b]thien-2-ylboronic acid Formyl radical 4-Benzofurazancarboxaldehyde DIHYDROXY BENZALDEHYDE phenyldimethanal BUTTPARK 37\04-04

2,1,3-Benzoxadiazole-4-carboxaldehyde (9CI)

2,1,3-BENZOXADIAZOLE-4-CARBOXALDEHYDE

2,1,3-Benzoxadiazole-4-carbaldehyde

4-Benzofurazone Carboxaldehyde

2,1,3-Benzoxadiazole-4-aldehyde

Benzofurazon-4-Carboxaldehyde

4-FORMYL-BENZO[C][1,2,5]OXADIAZOLE

4-Benzofurazancarboxaldehyde ,97%

2,1,3-benzoxadiazole-4-carbaldehyde(SALTDATA: FREE)

2,1,3-benzoxadiazole-7-carbaldehyde

2,1,3-benzoxadiazole-7-carboxaldehyde

benzofurazan-4-carbaldehyde

BENZO[C][1,2,5]OXADIAZOLE-4-CARBALDEHYDE

4-FORMYL-2,1,3-BENZOXADIAZOLE

4-BENZOFURAZANCARBOXALDEHYDE

4-Formylbenzofurazan

4-Benzofurazancarboxaldehyde ISO 9001：2015 REACH

2,1,3-Benzoxadiazol-4-aldehyde

Benzo[c][1,2,5]oxadiazol-4-carbaldehyde

32863-32-4

7318-22-5

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