4'-Hydroxy-3'-methoxypropiophenone
- Product Name
- 4'-Hydroxy-3'-methoxypropiophenone
- CAS No.
- 1835-14-9
- Chemical Name
- 4'-Hydroxy-3'-methoxypropiophenone
- Synonyms
- Propioguaiacone;PROPIOVANILLONE;Eugenol Impurity 21;4-HYDROXY-3-METHOXYPROPIOPHENONE;3-METHOXY-4-HYDROXYPROPIOPHENONE;4'-hydroxy-3'-methoxypropiophenone;Propiophenone, 4'-hydroxy-3'-methoxy;1-(4-hydroxy-3-methoxyphenyl)-1-propanone;1-Propanone, 1-(4-hydroxy-3-methoxyphenyl)-;1-(4-HYDROXY-3-METHOXY-PHENYL)-PROPAN-1-ONE
- CBNumber
- CB3205110
- Molecular Formula
- C10H12O3
- Formula Weight
- 180.2
- MOL File
- 1835-14-9.mol
4'-Hydroxy-3'-methoxypropiophenone Property
- Melting point:
- 61-62 °C
- Boiling point:
- 180-185 °C(Press: 15 Torr)
- Density
- 1.126±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- form
- Solid
- pka
- 8.92±0.31(Predicted)
- color
- White to Dark Beige
- LogP
- 2.020 (est)
- CAS DataBase Reference
- 1835-14-9(CAS DataBase Reference)
- NIST Chemistry Reference
- 1-(4-hydroxy-3-methoxyphenyl)propanone(1835-14-9)
- EPA Substance Registry System
- 1-Propanone, 1-(4-hydroxy-3-methoxyphenyl)- (1835-14-9)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- H947600
- Product name
- 1-(4-Hydroxy-3-methoxyphenyl)-1-propanone
- Packaging
- 50mg
- Price
- $185
- Updated
- 2021/12/16
- Product number
- Q284
- Product name
- 3-Methoxy-4-hydroxypropiophenone
- Packaging
- 250mg
- Price
- $118
- Updated
- 2021/12/16
- Product number
- 126754
- Product name
- 1-(4-Hydroxy-3-methoxyphenyl)propan-1-one
- Purity
- >95%
- Packaging
- 1g
- Price
- $252
- Updated
- 2021/12/16
- Product number
- APN0000263
- Product name
- 4-HYDROXY-3-METHOXYPROPIOPHENONE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $278.25
- Updated
- 2021/12/16
- Product number
- 95813
- Product name
- 1-(4-Hydroxy-3-methoxyphenyl)-1-propanone
- Packaging
- 10mg
- Price
- $450
- Updated
- 2021/12/16
4'-Hydroxy-3'-methoxypropiophenone Chemical Properties,Usage,Production
Uses
1-(4-Hydroxy-3-methoxyphenyl)-1-propanone is a derivative of Guaiacol, a precursor to various flavorants, such as eugenol and vanillin.
Preparation
Preparation by Fries rearrangement of 2-methoxyphenyl propionate, (b.p.20 140–143°)
with aluminium chloride in nitrobenzene, first at 60–80° for 1 h, then at r.t. overnight, at 60° for 1 h or at 50° for 5 h (44%) ;
with aluminium chloride (2 mol) in nitromethane at r.t. for 24 h (65%)
with aluminium chloride in carbon disulfide
with titanium tetrachloride (2 mol) in nitromethane at r.t. for 24 h (62%)
with stannic chloride (2 mol) in nitromethane at r.t. for 24 h (69%)
with antimony pentachloride (2 mol) in nitromethane at r.t. for 24 h (28%) with formation of important tars.
Synthesis Reference(s)
The Journal of Organic Chemistry, 15, p. 227, 1950 DOI: 10.1021/jo01148a001
4'-Hydroxy-3'-methoxypropiophenone Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4'-Hydroxy-3'-methoxypropiophenone manufacturers
- Product
- 4'-Hydroxy-3'-methoxypropiophenone 1835-14-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 200kg
- Release date
- 2019-08-29