ChemicalBook > CAS DataBase List > BENZYL ETHYL ETHER

BENZYL ETHYL ETHER

Product Name
BENZYL ETHYL ETHER
CAS No.
539-30-0
Chemical Name
BENZYL ETHYL ETHER
Synonyms
ETHYL BENZYL ETHER;(Ethoxymethyl)benzene;ethoxymethyl-benzene;(Ethoxymethyl);BENZYL ETHYL ETHER;Benzyl ethyl oxide;Ether, benzyl ethyl;(ethoxymethyl)-benzen;(ethoxymethyl)-Benzene;Benzene, (ethoxymethyl)-
CBNumber
CB3220030
Molecular Formula
C9H12O
Formula Weight
136.19
MOL File
539-30-0.mol
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BENZYL ETHYL ETHER Property

Melting point:
2.5°C
Boiling point:
bp 186°; bp10 65°
Density 
0.949
refractive index 
nD20 1.4955
FEMA 
2144 | BENZYL ETHYL ETHER
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Colorless to light yellow
Odor
at 100.00 %. powerful fruity pineapple tropical
Odor Type
fruity
JECFA Number
1252
Henry's Law Constant
6.7×10-2 mol/(m3Pa) at 25℃, Dupeux et al. (2022)
Dielectric constant
3.9(20℃)
LogP
2.16
EPA Substance Registry System
Benzyl ethyl ether (539-30-0)
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Safety

RIDADR 
UN1993
TSCA 
TSCA listed
HazardClass 
IRRITANT
HS Code 
2909309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Synthonix
Product number
E50267
Product name
(Ethoxymethyl)benzene
Purity
95+%
Packaging
5g
Price
$100
Updated
2026/05/06
Synthonix
Product number
E50267
Product name
(Ethoxymethyl)benzene
Purity
95+%
Packaging
10g
Price
$170
Updated
2026/05/06
Synthonix
Product number
E50267
Product name
(Ethoxymethyl)benzene
Purity
95+%
Packaging
25g
Price
$410
Updated
2026/05/06
ApexBio Technology
Product number
C6556
Product name
(Ethoxymethyl)benzene
Packaging
500mg
Price
$50
Updated
2026/05/06
ApexBio Technology
Product number
C6556
Product name
(Ethoxymethyl)benzene
Packaging
1g
Price
$85
Updated
2026/05/06
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BENZYL ETHYL ETHER Chemical Properties,Usage,Production

Chemical Properties

Benzyl ethyl ether has a pleasant, fruity (pineapple) odor.

Chemical Properties

Colorless, oily liquid; aromatic odor. Volatile in steam; insoluble in water; miscible with alcohol, ether. Combustible.

Occurrence

Reported found in cocoa, American cranberry, litchi (Litchi sinensis Sonn.) and eucalyptus oil.

Uses

Organic synthesis, flavoring.

Preparation

From benzyl chloride and sodium ethylate in alcoholic solution.

Definition

ChEBI: Benzyl ethyl ether is a benzyl ether.

Synthesis Reference(s)

The Journal of Organic Chemistry, 23, p. 1088, 1958 DOI: 10.1021/jo01101a029
Tetrahedron Letters, 37, p. 5159, 1996 DOI: 10.1016/0040-4039(96)01046-5

Hazard

Narcotic in high concentration. May be skin irritant.

Purification Methods

Dry the ether with CaCl2 or NaOH, then fractionally distil it. [Letzinger & Pollart J Am Chem Soc 78 6079 1956, Beilstein 6 III 1454, 6 IV 2229.]

BENZYL ETHYL ETHER Preparation Products And Raw materials

Raw materials

Preparation Products

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