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Hydrazine monohydrochloride

Product Name
Hydrazine monohydrochloride
CAS No.
2644-70-4
Chemical Name
Hydrazine monohydrochloride
Synonyms
Hydrazinium chloride;HydrazineHCl;HYDRAZINE MONO HCL;Hydrazine,chloride;Hydrazine monohydroc;hydrazinemonochloride;Hydrazine monohydrochL;Adrenaline Impurity 37;HYDRAZINIUM MONOCHLORIDE;HYDRAZINE MONOHYDROCHLORIDE
CBNumber
CB3236358
Molecular Formula
ClH5N2
Formula Weight
68.51
MOL File
2644-70-4.mol
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Hydrazine monohydrochloride Property

Melting point:
89 °C(lit.)
Boiling point:
240°C
Density 
1.500
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
white orthorhombic crystals
color 
White to Almost white
Water Solubility 
370 g/L (20 ºC)
Stability:
Hygroscopic
InChIKey
BIVUUOPIAYRCAP-UHFFFAOYSA-N
CAS DataBase Reference
2644-70-4(CAS DataBase Reference)
EPA Substance Registry System
Hydrazine, monohydrochloride (2644-70-4)
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Safety

Hazard Codes 
T,N
Risk Statements 
45-23/24/25-43-50/53
Safety Statements 
53-45-60-61
RIDADR 
UN 2923 8/PG 2
WGK Germany 
3
RTECS 
MV4625000
HazardClass 
6.1(a)
PackingGroup 
II
HS Code 
28251090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H350May cause cancer

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
216194
Product name
Hydrazine monohydrochloride
Purity
97%
Packaging
5g
Price
$28.62
Updated
2024/03/01
Sigma-Aldrich
Product number
216194
Product name
Hydrazine monohydrochloride
Purity
97%
Packaging
250g
Price
$118
Updated
2024/03/01
TCI Chemical
Product number
H0174
Product name
Hydrazine Monohydrochloride
Purity
>98.0%(T)
Packaging
25g
Price
$47
Updated
2024/03/01
TCI Chemical
Product number
H0174
Product name
Hydrazine Monohydrochloride
Purity
>98.0%(T)
Packaging
500g
Price
$100
Updated
2024/03/01
GFS CHEMICALS
Product number
42212
Product name
HYDRAZINEMONOHYDROCL
Packaging
500g
Price
$119.11
Updated
2021/12/16
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Hydrazine monohydrochloride Chemical Properties,Usage,Production

Chemical Properties

Hydrazine monohydrochloride is white to slightly beige crystals or cryst. powder; melts at 93°C; decomposes around 200°C; very soluble in water (37 g/100mL at 20°C); slightly soluble in alcohol.

Physical properties

White flakes; orthorhombic crystals; density 1.5 g/cm3; melts at 93°C;decomposes around 200°C; very soluble in water (37 g/100mL at 20°C); slightly soluble in alcohol.

Uses

Hydrazine monohydrochloride has been used:

  • as catalyst in the synthesis of titanium oxide polymers via catalytic sol-gel process
  • in fabrication of amorphous titanium dioxide (TiO2) thin films exhibiting high refractive indices and high transparency
  • in preparation of ethyl 3-ethoxy-1H-pyrazole-4-carboxylate

Uses

Hydrazine hydrochloride is used to prepare other hydrazine derivatives.

Preparation

Hydrazine hydrochloride is prepared by the reaction of hydrazine with hydrogen chloride:
N2H4 + HCl → N2H4 •HCl

Hazard

Hydrazine hydrochloride is moderately toxic by all routes of exposure. Theoral LD50in mice is 126 mg/kg.

Purification Methods

Prepare it by dropwise addition of cold conc HCl to cold liquid hydrazine in equimolar amounts. The crystals are harvested from water and are twice recrystallised from absolute MeOH and dried under a vacuum. [Kovack et al. J Am Chem Soc 107 7360 1985.]

Toxicity evaluation

Hydrazine hydrochloride is moderately toxic by all routes of exposure. The oral LD50 in mice is 126 mg/kg.

Hydrazine monohydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

2-(4-BROMOPHENYL)-5-(1-NAPHTHYL)-1,3,4-OXADIAZOLE ETHYL 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLATE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLIC ACID 2,5-BIS(3-METHOXYPHENYL)-1,3,4-OXADIAZOLE 2-(3-BROMOPHENYL)-5-(2-NAPHTHYL)-1,3,4-OXADIAZOLE 2,5-DIPHENYL-1,3,4-OXADIAZOLE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-AMINE 4-BROMO-3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBOXAMIDE 3-(Trifluoromethyl)pyrazole (3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-YL)METHANOL Ethyl 3-methyl-1H-pyrazole-5-carboxylate 2-NAPHTHHYDRAZIDE 2,5-BIS(3-NITROPHENYL)-1,3,4-OXADIAZOLE 2,5-BIS(1-NAPHTHYL)-1,3,4-OXADIAZOLE 1-PHENYL-3-(TRIFLUOROMETHYL)PYRAZOLE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBONITRILE Carboplatin 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-5-CARBOXYLIC ACID (3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-YL)METHANAMINE Pyridaben 4-tert-Butylbenzhydrazide 2,5-BIS(4-BIPHENYLYL)-1,3,4-OXADIAZOLE 2-(4-tert-Butylphenyl)-5-(4-biphenyl)-1,3,4-oxadiazole 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBALDEHYDE
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View Lastest Price from Hydrazine monohydrochloride manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Hydrazine monohydrochloride 2644-70-4
Price
US $40.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-10-10
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Hydrazine monohydrochloride 2644-70-4
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
1000KGS
Release date
2021-07-02
Hebei Mojin Biotechnology Co., Ltd
Product
Hydrazine monohydrochloride 2644-70-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-20

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