Propyl isocyanate Property

Melting point:

-30 °C

Boiling point:

83-84 °C(lit.)

Density 

0.908 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.394(lit.)

Flash point:

32 °F

storage temp. 

Flammables area

form 

Liquid

color 

Clear yellow

Water Solubility 

reacts vigorously

BRN 

1098489

CAS DataBase Reference

110-78-1(CAS DataBase Reference)

NIST Chemistry Reference

Propane, 1-isocyanato-(110-78-1)

EPA Substance Registry System

Propane, 1-isocyanato- (110-78-1)

Safety

Hazard Codes 

F,Xn,T+

Risk Statements 

11-20/21/22-37/38-41-42/43-42-34-26-22-14

Safety Statements 

23-26-36/37/39-45-38-16

RIDADR 

UN 2482 6.1/PG 1

WGK Germany 

1

RTECS 

NR0190000

F 

19

HazardClass 

6.1(a)

PackingGroup 

I

HS Code 

29291090

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Propyl isocyanate Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

General Description

A colorless liquid with a pungent odor. Very toxic by ingestion. May be toxic by skin absorption and inhalation. Insoluble in water but reacts with water to produce a toxic vapor. Flash point 30°F. Used to make other chemicals.

Air & Water Reactions

Highly flammable. May react with water to produce a toxic cyanide vapor. Insoluble in water.

Reactivity Profile

Isocyanates and thioisocyanates, such as PROPYL ISOCYANATE, are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerization reactions in these materials. Some isocyanates react with water to form amines and liberate carbon dioxide.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

Poison by intravenous route. A flammable liquid when exposed to heat or flame, can react vigorously with oxidzing materials. When heated to decomposition it emits toxic fumes of NOx. See also ISOCYANATES.