DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

Description

Product Name: DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
CAS No.: 12148-71-9
Chemical Name: DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
Synonyms: [Ir(OMe)(1,5-cod)]2;Bis(1,5-cyclooctadiene)dimethoxydiiridium;(1,5-Cyclooctadiene)(methoxy)iridium dimer;DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM;Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I);Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I);5-cod)]2;[Ir(OMe)(1;Methoxy(cycL;Di-μ-methoxobis
CBNumber: CB3287961
Molecular Formula: C18H22Ir2O2
Formula Weight: 654.81
MOL File: 12148-71-9.mol

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DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Property

Melting point:: 154-179 °C (D)
storage temp.: -20°C
form: Powder
color: yellow
Sensitive: Light, Air & Moisture Sensitive
InChIKey: WLPGZWOTJGJODI-SXGOCSEPSA-N

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
TSCA: No
HS Code: 2843909000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 685062
Product name: (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
Packaging: 1g
Price: $214
Updated: 2024/03/01

Sigma-Aldrich

Product number: 685062
Product name: (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
Packaging: 25g
Price: $3800
Updated: 2024/03/01

TCI Chemical

Product number: C2662
Product name: (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
Packaging: 1g
Price: $606
Updated: 2024/03/01

TCI Chemical

Product number: C2662
Product name: (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
Packaging: 200mg
Price: $122
Updated: 2024/03/01

Alfa Aesar

Product number: 044967
Product name: Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%
Packaging: 1g
Price: $429
Updated: 2023/06/20

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DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Chemical Properties,Usage,Production

Description

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.

Chemical Properties

yellow solid

Uses

Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Suppliers

Americas 1 Belgium 2 China 199 Europe 1 France 2 Germany 4 India 9 Japan 3 South Korea 1 Switzerland 1 The Netherlands 1 United Kingdom 8 United States 36 Global 268

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View Lastest Price from DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer 12148-71-9
Price: US $0.00/G
Min. Order: 10G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-02

henan kanbei chemical co.,ltd

Product: DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) 12148-71-9
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

Zhuozhou Wenxi import and Export Co., Ltd

Product: (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer 12148-71-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

12148-71-9, DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)Related Search:

1,2-Dibromoethane Phenylboronic acid CHLOROETHANE Tetrahydrofuran Hexane 1-Propanol Glycerol 1,10-Phenanthroline hydrate Iridium 1,5-Cyclooctadiene DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I),min.98%

[Ir(OMe)(1,5-cod)]2

BIS(1,5-CYCLOOCTADIENE) DI-MU-METHOXYDII

[Ir(OMe)(1

5-cod)]2

(1,5-Cyclooctadiene)(methoxy)iridium dimer

Bis(1,5-cyclooctadiene)dimethoxydiiridium

Bis[(1,5-cyclooctadiene)(methanolato)iridium]

-methoxy)iridium(I) dimer

(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer

Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)

Methoxy(cyclooctadiene)iridium(I) dimer

Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I), min. 98%

Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%

Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I),98%

Di-mu-methoxobis(1,5-cycloo

Bis(1,5-cyclooctadiene) di-u-methoxydiiridium

Di-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)

Di-mu-methoxobis(1,5-cyclooctadiene)diiridium (I), min. 98%

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM

(Cycloocta-1,5-diene)(methoxy)iridium(I) dimer

Bis(cycloocta-1,5-diene) di-u-methoxydiiridium

Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),98% [Ir(COD)(OMe)]2

IridiuM, bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-M-Methoxydi-

Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),[Ir(COD)(OMe)]2

[Ir(Ome)(1,5-cod)Cl]2

(Cycloocta-1,5-diene)(methoxy)iridium(I) dimer 97%

Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(Ⅰ)

Methoxy(cycL

ooctadiene)iridium(I) dimer

Methoxy(cyclooctadiene)iridium(I)dimer,Irnominally58%

Methoxy(cyclooctadiene)iridium(I) dimerIr nominally

Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I)

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) ISO 9001：2015 REACH

5-CYCLOOCTADIENE)DIIRIDIUM(I)

DI-MU-METHOXOBIS(1

Bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-m- methoxydi-iridium

Di-(μ-methoxy)bis(1,5-cyclooctadiene)diiridium(I)

Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium

(1,5-Cyclooctadiene)(methoxy)iridium(I)dimer,Bis(1,5-cyclooctadiene)di-u-methoxydiiridium

(1,5-Cyclooctadiene)(methoxy)iridium(I)

Di-μ-methoxobis

bis((1Z,5Z)-cycloocta-1,5-diene) dimethyl-2,4-dioxa-1,3-diiridabicyclo[1.1.0]butane-2,4-diium-1,3-diuide

Di-u-methoxobis(1,5-cyclooctadiene)diiridium (I)

Tetrakis(acetonitrle)palladium(I)tetrafluoroborate

12148-71-9

121148-71-9

2C8H12C2H6Ir2O2

IrOCH3C8H122

C18H30Ir2O2

C22H42Ir2O2

organometallic complex

Metal Catalysts

Ir