1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride
- Product Name
- 1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride
- CAS No.
- 156028-26-1
- Chemical Name
- 1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride
- Synonyms
- 5,6,12,13-TetrachL;tetrakis(forMic acid);1,6,7,12-Terachloro-3,4,9,10-teraanhydrideperylene;(1,6,7,12-tetrachloroperylen-2-yl)carbonyl forMate;TETRACHLOROPERYLENE TETRACARBOXYLIC ACID DIANHYDRIDE;12-Tetrachloroperylene tetracarboxylic acid dianhydride;1,6,7,12-TETRACHLORO-3,4,9-PERYLENE TETRACARBOXYLIC ACID;TETRACHLOROPERYLENE TETRACARBOXYLIC ACID DIANHYDRIDE: TECH.;6,7,12,13-Tetrachloro-3,4,9,10-perylene tetracarboxylic acid;1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydrid
- CBNumber
- CB3316841
- Molecular Formula
- C24H4Cl4O6
- Formula Weight
- 530.1
- MOL File
- 156028-26-1.mol
1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride Property
- Boiling point:
- 757.1±55.0 °C(Predicted)
- Density
- 1.962±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- DMSO (Slightly, Heated)
- form
- Solid
- color
- Red
- Stability:
- Moisture Sensitive
- InChI
- InChI=1S/C24H4Cl4O6/c25-9-1-5-13-6(22(30)33-21(5)29)2-11(27)17-18-12(28)4-8-14-7(23(31)34-24(8)32)3-10(26)16(20(14)18)15(9)19(13)17/h1-4H
- InChIKey
- YGRXZLAMYLGXMF-UHFFFAOYSA-N
- SMILES
- C1(=O)OC(=O)C2=CC(Cl)=C3C4=C2C1=CC(Cl)=C4C1=C2C4=C(C=C1Cl)C(=O)OC(=O)C4=CC(Cl)=C32
- CAS DataBase Reference
- 156028-26-1(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
N-Bromosuccinimide Price
- Product number
- T889865
- Product name
- 1,6,7,12-TetrachloroperyleneTetracarboxylicAcidDianhydride
- Packaging
- 100mg
- Price
- $70
- Updated
- 2021/12/16
- Product number
- 078512
- Product name
- 1,6,7,12-Tetrachloroperylenetetracarboxylic acid dianhydride
- Packaging
- 1g
- Price
- $30
- Updated
- 2021/12/16
- Product number
- CS-W018796
- Product name
- 5,6,12,13-Tetrachloroanthra[2,1,9-def:6,5,10-d'e'f']diisochromene-1,3,8,10-tetraone
- Packaging
- 5g
- Price
- $39
- Updated
- 2021/12/16
- Product number
- CS-W018796
- Product name
- 5,6,12,13-Tetrachloroanthra[2,1,9-def:6,5,10-d'e'f']diisochromene-1,3,8,10-tetraone
- Packaging
- 10g
- Price
- $71
- Updated
- 2021/12/16
- Product number
- 078512
- Product name
- 1,6,7,12-Tetrachloroperylenetetracarboxylic acid dianhydride
- Packaging
- 5g
- Price
- $90
- Updated
- 2021/12/16
1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride Chemical Properties,Usage,Production
Uses
1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride is a perylene derivative used in the preparation of fluorofluorescent perylene bisimides for use in perfluorinated liquids. The fluorescence of 1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride has made it a viable target for use as fluorescent liquid crystals.
Synthesis
128-69-8
156028-26-1
3,4,9,10-tetracarboxylic dianhydride (3.30 g, 8.41 mmol) was used as a raw material, mixed with chlorosulfonic acid (20 mL, 300 mmol) and iodine (0.56 g, 2.20 mmol), and the reaction was stirred for 30 hours at 65 °C. Upon completion of the reaction, the mixture was cooled to room temperature and subsequently added slowly dropwise to an ice-water mixture. The precipitated red solid product was collected by filtration in a yield of 4.14 g in 92% yield. The product was analyzed by 1H NMR (d-DMSO, ppm) showing: 8.75 (s, 4H, aryl proton). 13C NMR (d-DMSO, ppm) analysis showed: 119.75, 125.29, 129.5, 134.88, 136.22, 158.16, 168.53. mass spectral (EI) analysis showed: m/z 532.
References
[1] Journal of the American Chemical Society, 2008, vol. 130, # 26, p. 8271 - 8279
[2] Synlett, 2018, vol. 29, # 19, p. 2509 - 2514
[3] Journal of the American Chemical Society, 2015, vol. 137, # 15, p. 5210 - 5224
[4] ACS Combinatorial Science, 2016, vol. 18, # 12, p. 723 - 739
[5] Polymer, 2014, vol. 55, # 23, p. 6058 - 6068
1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride manufacturers
- Product
- 1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride 156028-26-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10
- Release date
- 2024-11-22
- Product
- 6,7,12,13-Tetrachloro-3,4,9,10-perylene tetracarboxylic acid 156028-26-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 97.2%
- Supply Ability
- 100 tons
- Release date
- 2022-02-08
- Product
- 1,6,7,12-Tetrachloroperylene tetracarboxylic acid dianhydride 156028-26-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1
- Release date
- 2018-08-06