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1,3-Dimethyl-2-imidazolidinone

Product Name
1,3-Dimethyl-2-imidazolidinone
CAS No.
80-73-9
Chemical Name
1,3-Dimethyl-2-imidazolidinone
Synonyms
DMI;DMEU;1,3-DIMETHYLIMIDAZOLIDIN-2-ONE;1,3-DIMETHYLIMIDAZOLIDINONE;DIMETHYL IMIDAZOLIDINONE;1,3-Dimethyl-2-imidazolinone;1,3-DMI;rhonite1;Karbomos;Rhonite 1
CBNumber
CB3332975
Molecular Formula
C5H10N2O
Formula Weight
114.15
MOL File
80-73-9.mol
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1,3-Dimethyl-2-imidazolidinone Property

Melting point:
8.2 °C
Boiling point:
224-226 °C (lit.)
Density 
1.056 g/mL at 25 °C (lit.)
vapor pressure 
<1 hPa (20 °C)
refractive index 
n20/D 1.472(lit.)
Flash point:
220 °F
storage temp. 
Store at +5°C to +30°C.
solubility 
toluene: soluble(lit.)
pka
-0.65±0.20(Predicted)
form 
Liquid
color 
Clear
explosive limit
1.3-8.4%(V)
Water Solubility 
freely soluble
Sensitive 
Hygroscopic
Merck 
14,3249
BRN 
108808
InChIKey
CYSGHNMQYZDMIA-UHFFFAOYSA-N
LogP
-0.3 at 25℃
CAS DataBase Reference
80-73-9(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Dimethyl-2-imidazolidinone(80-73-9)
EPA Substance Registry System
N,N'-Dimethylimidazolidinone (80-73-9)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
21/22-38-41-36/38-62-22
Safety Statements 
26-36-36/37/39-36/37
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
3
RTECS 
NJ0660000
3
Autoignition Temperature
305 °C
Hazard Note 
Harmful/Irritant
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
HS Code 
29332990
Toxicity
LD50 orally in Rabbit: 1261 mg/kg LD50 dermal Rabbit 986 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.18212
Product name
1,3-Dimethyl-2-imidazolidinone
Purity
for synthesis
Packaging
100mL
Price
$81.6
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18212
Product name
1,3-Dimethyl-2-imidazolidinone
Purity
for synthesis
Packaging
500mL
Price
$244
Updated
2024/03/01
Sigma-Aldrich
Product number
193453
Product name
1,3-Dimethyl-2-imidazolidinone
Purity
reagent grade
Packaging
25g
Price
$28.5
Updated
2024/03/01
Sigma-Aldrich
Product number
193453
Product name
1,3-Dimethyl-2-imidazolidinone
Purity
reagent grade
Packaging
1kg
Price
$300
Updated
2024/03/01
TCI Chemical
Product number
D1477
Product name
1,3-Dimethyl-2-imidazolidinone
Purity
>99.0%(GC)
Packaging
25mL
Price
$28
Updated
2024/03/01
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1,3-Dimethyl-2-imidazolidinone Chemical Properties,Usage,Production

Description

DMI, a high purity aprotic solvent, is composed of nitrogen containing five membered ring compound and widely recognized as an epoch making solvent. It is a colorless, transparent, high polar solvent with high thermal and chemical stability and non-corrosiveness. The material has a high boiling point of 222° C, a high flash point of 120° C (open method) / 95° C (close method), and a low melting point of 7.5° C.

Chemical Properties

Almost colorless, clear liquid

Uses

1,3-Dimethyl-2-imidazolidinone is used as a high-boiling polar aprotic solvent. It is used as a substitute solvent for toxic hexamethylphosphoramide. It finds application in detergents, dyestuffs, electronic materials and in the manufacture of polymers. It is involved in the preparation of 1,2-bis(trimethylsilyl)benzene. Further, it is utilized as a solvent during alfa-regioselective prenylation of imines. In addition to this, it constitutes the mobile phase during size-exclusion chromatographic analysis of cellulose.

Uses

DMI can be used in a variety of applications including detergents, dyestuffs, electronic materials and in the manufacture of polymers. Its versatility can be attributed to it. Of particular note are its excellent solubility for inorganic and organic compounds and high dielectric constant and solvation effect.

Uses

1,3-Dimethyl-2-imidazolidinone may be used:

  • As substitute solvent for hexamethylphosphoric triamide (HMPA) in the synthesis of 1,2-bis(trimethylsilyl)benzene.
  • As solvent during the α-regioselective prenylation of imine.
  • As component of mobile phase for the size-exclusion chromatographic analysis of cellulose.

Definition

ChEBI: 1,3-Dimethyl-2-imidazolidinon is an imidazolidinone.

General Description

1,3-Dimethyl-2-imidazolidinone (DMI) is an imidazolidine derivative. It is reported to act as a promoter by minimizing the formation of dialkylation byproducts and accelerating the rate of monoalkylation of γ-butyrolactone. Conversion of CO2 to form lower alcohols by homogeneous catalytic hydrogenation using DMI as solvent has been investigated.

Flammability and Explosibility

Non flammable

1,3-Dimethyl-2-imidazolidinone Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1,3-Dimethyl-2-imidazolidinone manufacturers

Jinan Finer Chemical Co., Ltd
Product
1,3-Dimethyl-2-imidazolidinone 80-73-9
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
2000mt/year
Release date
2021-08-31
Henan Fengda Chemical Co., Ltd
Product
1,3-Dimethyl-2-imidazolidinone 80-73-9
Price
US $8.00-0.80/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-22
Qingdao Truelight functional Material Technology Co., Ltd.
Product
1,3-Dimethyl-2-imidazolidinone 80-73-9
Price
US $25.00/kg
Min. Order
200kg
Purity
99
Supply Ability
100TONS
Release date
2023-05-18

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