ChemicalBook > CAS DataBase List > (S)-4-(anthracen-9-yl)-3-(te
rt-butyl)-2,3-dihydrobenzo
[d][1,3]oxaphosphole
(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
- Product Name
- (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
- CAS No.
- 1807740-34-6
- Chemical Name
- (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
- Synonyms
- ZJ-0024;(S)-AntPhos;(S)-AntPhos;99% ee) [(S)-AntPhos];(3S)-4-(9-anthryl)-3-tert-butyl-2H-1,3-benzoxaphosphole;(S)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole;(S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole;(S)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole;(S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,99+% (>
- CBNumber
- CB33340409
- Molecular Formula
- C25H23OP
- Formula Weight
- 370.42
- MOL File
- 1807740-34-6.mol
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(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole Property
- Boiling point:
- 525.7±50.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- light yellow
- Sensitive
- air sensitive, store cold
- InChI
- InChI=1S/C25H23OP/c1-25(2,3)27-16-26-22-14-8-13-21(24(22)27)23-19-11-6-4-9-17(19)15-18-10-5-7-12-20(18)23/h4-15H,16H2,1-3H3/t27-/m1/s1
- InChIKey
- HKAWVLHXUZNLPP-HHHXNRCGSA-N
- SMILES
- O1C2=CC=CC(C3C4=CC=CC=C4C=C4C=3C=CC=C4)=C2[P@](C(C)(C)C)C1
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Safety
- HS Code
- 2931499090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-1967
- Product name
- (S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,99+% (>99% ee) [(S)-AntPhos]
- Packaging
- 100mg
- Price
- $77
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1967
- Product name
- (S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,99+% (>99% ee) [(S)-AntPhos]
- Packaging
- 500mg
- Price
- $309
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1967
- Product name
- (S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,99+% (>99% ee) [(S)-AntPhos]
- Purity
- 99+% (>99% ee) [(S)-AntPhos]
- Packaging
- 2g
- Price
- $925
- Updated
- 2024/03/01
ChemScene
- Product number
- CS-0020504
- Product name
- (S)-AntPhos
- Purity
- ≥97.0%
- Packaging
- 250mg
- Price
- $141
- Updated
- 2021/12/16
ChemScene
- Product number
- CS-0020504
- Product name
- (S)-AntPhos
- Purity
- ≥97.0%
- Packaging
- 1g
- Price
- $468
- Updated
- 2021/12/16
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(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole Chemical Properties,Usage,Production
Uses
(S)-AntPhos is a P-chiral monophosphorus ligand used for the asymmetric Suzuki-Miyaura and Miyaura borylation reactions. This ligand is uniquely effective for sterically hindered cross-coupling reactions.
Reactions
1. Ligand/palladium catalyst for general Miyaura borylation reactions.
2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
3. Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
4. Ligand/nickel catalyst for intramolecular reductive cyclization’
5. Ligand/palladium catalyst for Dearomative cyclization’
reaction suitability
reagent type: ligand
(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole Preparation Products And Raw materials
Raw materials
Preparation Products
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(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole Suppliers
- Tel
- tp@aladdinsci.com
- Country
- United States
- ProdList
- 57505
- Advantage
- 58
- Tel
- --
- Fax
- --
- info@strem.com
- Country
- United States
- ProdList
- 4910
- Advantage
- 86
1807740-34-6, (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphospholeRelated Search:
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4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d]
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