ChemicalBook > CAS DataBase List > RockPhos Pd G3
RockPhos Pd G3
Reaction- Product Name
- RockPhos Pd G3
- CAS No.
- 2009020-38-4
- Chemical Name
- RockPhos Pd G3
- Synonyms
- RockPhos Pd G3;Methanesulfonato[2-(di-t-butylphosphino)-3-methoxy-6-methyl-2’,4’,6’-tri-i-propylbiphenyl](2’-amino-2-biphenylyl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2'',4'',6''-tri-i-propyl-1,1''-biphenyl)(2''-amino-1,1''-biphenyl-2-yl)palladium(II);Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (RockPhos Pd G3);2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3-METHOXY-6-METHYL-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ROCKPHOSPALLADACYCLEGEN.3]
- CBNumber
- CB33357113
- Molecular Formula
- C44H63NO4PPdS-
- Formula Weight
- 839.434081
- MOL File
- 2009020-38-4.mol
More
Less
RockPhos Pd G3 Property
- Melting point:
- 220-250 °C
- form
- Powder
- color
- brown
- InChI
- InChI=1S/C31H49OP.C12H10N.CH4O3S.Pd/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;
- InChIKey
- QAHMIRGGAFFMDS-UHFFFAOYSA-N
- SMILES
- [Pd].S(C([H])([H])[H])(=O)(=O)O[H].P(C1=C(C([H])=C([H])C(C([H])([H])[H])=C1C1C(=C([H])C(C([H])(C([H])([H])[H])C([H])([H])[H])=C([H])C=1C([H])(C([H])([H])[H])C([H])([H])[H])C([H])(C([H])([H])[H])C([H])([H])[H])OC([H])([H])[H])(C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H].N([H])([H])C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([H])C([H])=[C-]1
- CAS DataBase Reference
- 2009020-38-4
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 773905
- Product name
- RockPhos Pd G3
- Packaging
- 100MG
- Price
- $112
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 773905
- Product name
- RockPhos Pd G3
- Packaging
- 500MG
- Price
- $532
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 773905
- Product name
- RockPhos Pd G3
- Packaging
- 5G
- Price
- $3950
- Updated
- 2023/06/20
Strem Chemicals
- Product number
- 46-0335
- Product name
- Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]
- Packaging
- 100mg
- Price
- $103
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 46-0335
- Product name
- Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle Gen. 3]
- Packaging
- 500mg
- Price
- $426
- Updated
- 2024/03/01
More
Less
RockPhos Pd G3 Chemical Properties,Usage,Production
Reaction
- Palladium precatalyst used for the arylation of an aliphatic alcohol.
- Palladium precatalyst used for the synthesis of diaryl ethers under mild conditions.
- Palladium precatalyst used for the intermolecular C-O bond formation with secondary and primary alcohols.
Uses
Buchwald 3rd Generation Pd Precatalyst containing bulk RockPhos ligand. This system has been shown to be effective for cross-coupling reactions like the arylation of aliphatic alcohols.
Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands
RockPhos Pd G3 Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
RockPhos Pd G3 Suppliers
- Tel
- 1-516-6625404
- Fax
- 1-516-927-0118
- support@alfa-chemistry.com
- Country
- United States
- ProdList
- 9171
- Advantage
- 60
- Tel
- (+1)-858-699-3322
- Fax
- (+1)-858-876-1948
- info@accelachem.com
- Country
- United States
- ProdList
- 19965
- Advantage
- 58
- Tel
- +16313385890
- info@protheragen-ing.com
- Country
- United States
- ProdList
- 1091
- Advantage
- 58
- Tel
- +1-833-552-7181
- sales@aladdinsci.com
- Country
- United States
- ProdList
- 52927
- Advantage
- 58
2009020-38-4, RockPhos Pd G3Related Search:
Palladacycle Gen. 3
SPhos Palladacycle Gen. 4
MorDalPhos Pd G4
XPhos Pd G4
Xantphos Pd G3
BrettPhos Pd G3
t-BuXphos Palladacycle Gen. 4
Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-dimethylamino)biphenyl(2′-amino-1,1′-biphenyl-2-yl) palladium(II)
Methanesulfonate(2-Dicyclohexylphosphino-2'-methyl)(2'-Amino-1,1'-Biphenyl-2-Yl)Palladium(II)
(Mephos Pd G3)
QPhos Pd G3
VPhos Pd G4
RuPhos Palladacycle Gen. 4
t-BuBrettPhos Palladacycle Gen. 3
SPhos Pd G3
cataCXium A Pd G3
EPhos Pd G4
XantPhos Pd G4
Methanesulfonato(triphenylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
(PPH3 PD G3)