1-(Bromomethyl)naphthalene
- Product Name
- 1-(Bromomethyl)naphthalene
- CAS No.
- 3163-27-7
- Chemical Name
- 1-(Bromomethyl)naphthalene
- Synonyms
- CL015;1-(Bromomethyl)napht;1-Naphtylmethyl bromide;(1-Naphtyl)bromomethane;1-(Bromomthy)Naphthalene;1-Naphthylmethyl bromide;1-(Bromomethyl)phthalene;1-(Brommethyl)naphthalen;1-broMo Methyl napthalene;1-(Bromomethy)naphthalene
- CBNumber
- CB3337682
- Molecular Formula
- C11H9Br
- Formula Weight
- 221.09
- MOL File
- 3163-27-7.mol
1-(Bromomethyl)naphthalene Property
- Melting point:
- 52-55°C
- Boiling point:
- 213°C/100mmHg
- Density
- 1.44
- refractive index
- 1.6600
- storage temp.
- Inert atmosphere,2-8°C
- form
- Powder
- color
- Off-white
- Water Solubility
- Slightly soluble in water.
- λmax
- 292nm(Cyclohexane)(lit.)
- CAS DataBase Reference
- 3163-27-7(CAS DataBase Reference)
- NIST Chemistry Reference
- 1-(Bromomethyl)naphthalene(3163-27-7)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36
- RIDADR
- 3261
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29036990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H290May be corrosive to metals
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
- Precautionary statements
-
P234Keep only in original container.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P390Absorb spillage to prevent material damage.
P405Store locked up.
P406Store in corrosive resistant/… container with a resistant inner liner.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B4563
- Product name
- 1-(Bromomethyl)naphthalene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $43
- Updated
- 2025/07/31
- Product number
- B4563
- Product name
- 1-(Bromomethyl)naphthalene
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $209
- Updated
- 2025/07/31
- Product number
- B697350
- Product name
- 1-(Bromomethyl)naphthalene
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- B697350
- Product name
- 1-(Bromomethyl)naphthalene
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- B697350
- Product name
- 1-(Bromomethyl)naphthalene
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
1-(Bromomethyl)naphthalene Chemical Properties,Usage,Production
Chemical Properties
Off-white powder
Uses
It is employed as a intermediate for organic synthesis and pharmaceutical.
Synthesis
4780-79-4
3163-27-7
The general procedure for the synthesis of 1-bromomethylnaphthalene from 1-naphthalenemethanol: Ethyl α,α-diacetoacetate (0.41 mmol, 1.2 eq.), 1-naphthalenemethanol (0.34 mmol, 1.0 eq.), and triphenylphosphine (0.68 mmol, 2.0 eq.) were added to 3 mL of dichloroethane (DCE) at room temperature and the reaction took place in air. The progress of the reaction was monitored by thin layer chromatography (TLC) during the reaction. Upon completion of the reaction, the reaction was quenched by the addition of 3 mL of water, followed by extraction with ethyl acetate (3 x 3 mL). The organic phases were combined, washed with saturated saline, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography, and the eluent was petroleum ether or a mixed solvent of petroleum ether and ethyl acetate, and the target product 1-bromomethyl naphthalene was finally obtained.
References
[1] Synthetic Communications, 2010, vol. 40, # 11, p. 1646 - 1649
[2] Organic Letters, 2003, vol. 5, # 8, p. 1167 - 1169
[3] Tetrahedron Letters, 2014, vol. 55, # 1, p. 90 - 93
[4] Canadian Journal of Chemistry, 1981, vol. 59, p. 2629 - 2641
[5] Tetrahedron, 2003, vol. 59, # 52, p. 10453 - 10463
1-(Bromomethyl)naphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
1-(Bromomethyl)naphthalene Suppliers
- Tel
- --
- Fax
- --
- brunschwig@brunschwig.nl
- Country
- The Netherlands
- ProdList
- 4996
- Advantage
- 67
View Lastest Price from 1-(Bromomethyl)naphthalene manufacturers
- Product
- 1-(Bromomethyl)naphthalene 3163-27-7
- Price
- US $1.00/Kg
- Min. Order
- 1Kg
- Purity
- 98%
- Supply Ability
- 20T
- Release date
- 2024-07-08
- Product
- 1-(Bromomthy)Naphthalene 3163-27-7
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
- Product
- 1-(Bromomthy)Naphthalene 3163-27-7
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-08