1-(Bromomethyl)naphthalene

Product Name: 1-(Bromomethyl)naphthalene
CAS No.: 3163-27-7
Chemical Name: 1-(Bromomethyl)naphthalene
Synonyms: CL015;1-(Bromomethyl)napht;1-Naphtylmethyl bromide;(1-Naphtyl)bromomethane;1-(Bromomthy)Naphthalene;1-Naphthylmethyl bromide;1-(Bromomethyl)phthalene;1-(Brommethyl)naphthalen;1-broMo Methyl napthalene;1-(Bromomethy)naphthalene
CBNumber: CB3337682
Molecular Formula: C11H9Br
Formula Weight: 221.09
MOL File: 3163-27-7.mol

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1-(Bromomethyl)naphthalene Property

Melting point:: 52-55°C
Boiling point:: 213°C/100mmHg
Density: 1.44
refractive index: 1.6600
storage temp.: Inert atmosphere,2-8°C
form: Powder
color: Off-white
Water Solubility: Slightly soluble in water.
λmax: 292nm(Cyclohexane)(lit.)
CAS DataBase Reference: 3163-27-7(CAS DataBase Reference)
NIST Chemistry Reference: 1-(Bromomethyl)naphthalene(3163-27-7)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36
RIDADR: 3261
HazardClass: 8
PackingGroup: II
HS Code: 29036990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P390Absorb spillage to prevent material damage.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: B4563
Product name: 1-(Bromomethyl)naphthalene
Purity: >98.0%(GC)
Packaging: 5g
Price: $43
Updated: 2025/07/31

TCI Chemical

Product number: B4563
Product name: 1-(Bromomethyl)naphthalene
Purity: >98.0%(GC)
Packaging: 25g
Price: $209
Updated: 2025/07/31

TRC

Product number: B697350
Product name: 1-(Bromomethyl)naphthalene
Packaging: 250mg
Price: $55
Updated: 2021/12/16

TRC

Product number: B697350
Product name: 1-(Bromomethyl)naphthalene
Packaging: 500mg
Price: $65
Updated: 2021/12/16

TRC

Product number: B697350
Product name: 1-(Bromomethyl)naphthalene
Packaging: 100mg
Price: $45
Updated: 2021/12/16

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1-(Bromomethyl)naphthalene Chemical Properties,Usage,Production

Chemical Properties

Off-white powder

Uses

It is employed as a intermediate for organic synthesis and pharmaceutical.

Synthesis

4780-79-4

3163-27-7

The general procedure for the synthesis of 1-bromomethylnaphthalene from 1-naphthalenemethanol: Ethyl α,α-diacetoacetate (0.41 mmol, 1.2 eq.), 1-naphthalenemethanol (0.34 mmol, 1.0 eq.), and triphenylphosphine (0.68 mmol, 2.0 eq.) were added to 3 mL of dichloroethane (DCE) at room temperature and the reaction took place in air. The progress of the reaction was monitored by thin layer chromatography (TLC) during the reaction. Upon completion of the reaction, the reaction was quenched by the addition of 3 mL of water, followed by extraction with ethyl acetate (3 x 3 mL). The organic phases were combined, washed with saturated saline, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography, and the eluent was petroleum ether or a mixed solvent of petroleum ether and ethyl acetate, and the target product 1-bromomethyl naphthalene was finally obtained.

References

[1] Synthetic Communications, 2010, vol. 40, # 11, p. 1646 - 1649
[2] Organic Letters, 2003, vol. 5, # 8, p. 1167 - 1169
[3] Tetrahedron Letters, 2014, vol. 55, # 1, p. 90 - 93
[4] Canadian Journal of Chemistry, 1981, vol. 59, p. 2629 - 2641
[5] Tetrahedron, 2003, vol. 59, # 52, p. 10453 - 10463

1-(Bromomethyl)naphthalene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(Bromomethyl)naphthalene Suppliers

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View Lastest Price from 1-(Bromomethyl)naphthalene manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 1-(Bromomethyl)naphthalene 3163-27-7
Price: US $1.00/Kg
Min. Order: 1Kg
Purity: 98%
Supply Ability: 20T
Release date: 2024-07-08

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-(Bromomthy)Naphthalene 3163-27-7
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-(Bromomthy)Naphthalene 3163-27-7
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-08

3163-27-7, 1-(Bromomethyl)naphthaleneRelated Search:

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Naphthalene, 1-(bromomethyl)-

1-BROMOMETHYL NAPHTHALENE

1-BROMOMETHYL NAPHTHALENE 99.73%

1-(Bromomthy)Naphthalene

1-(Bromomethy)naphthalene

(1-Naphtyl)bromomethane

1-Naphtylmethyl bromide

1-(Bromomethyl)napht

1-broMo Methyl napthalene

CL015

1-(Bromomethyl)naphthalene, 98% off-white powder

1-Naphthylmethyl bromide

1-(Bromomethyl)phthalene

1-(Bromomethyl)naphthalene &gt

1-(Brommethyl)naphthalen

3163-27-7

3136-27-7

3613-27-7

Naphthalene series