Aluminium isopropoxide Property

Melting point:

128-133 °C (lit.)

Boiling point:

125-130 °C (38 mmHg)

Density 

1.035 g/mL at 25 °C (lit.)

vapor pressure 

0.13 hPa (21 °C)

refractive index 

1.0346

Flash point:

46 °C

storage temp. 

Store below +30°C.

solubility 

REACTS

form 

Crystalline Powder (May Contain Chunks)

color 

White

Specific Gravity

1.035

explosive limit

2%(V)

Water Solubility 

REACTS

Sensitive 

Moisture Sensitive

Hydrolytic Sensitivity

8: reacts rapidly with moisture, water, protic solvents

Merck 

14,347

BRN 

3910275

Exposure limits

ACGIH: TWA 1 mg/m3

InChIKey

SMZOGRDCAXLAAR-UHFFFAOYSA-N

LogP

0.05 at 25℃

CAS DataBase Reference

555-31-7(CAS DataBase Reference)

NIST Chemistry Reference

Aluminum isopropoxide(555-31-7)

EPA Substance Registry System

2-Propanol aluminum salt (555-31-7)

Safety

Hazard Codes 

F

Risk Statements 

11

Safety Statements 

8-16-2017/8/16

RIDADR 

UN 3181 4.1/PG 2

WGK Germany 

1

RTECS 

BD0975000

TSCA 

Yes

HazardClass 

4.1

PackingGroup 

II

HS Code 

29051900

Hazardous Substances Data

555-31-7(Hazardous Substances Data)

Toxicity

LD50 orally in rats: 11.3 g/kg (Smyth)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

Aluminium isopropoxide Chemical Properties,Usage,Production

Description

Aluminium isopropoxide is usually described with the formula Al(O-i-Pr)3, where i-Pr is the isopropyl group (CH(CH3)2). This colourless solid is a useful reagent in organic synthesis. The structure of this compound is complex, possibly time dependent, and may depend on the solvent. It is primarily used in the oil and gas industry in combination with phosphate esters to form an anionic association polymer in which the aluminium as the cross-linking agent. Such gelling agents are used as fluid loss control additives in drilling operations.

Chemical Properties

Aluminum isopropoxide on the market is mostly white translucent block, cylindrical small block solid or powder, soluble in isopropanol, ethanol, toluene, benzene, carbon tetrachloride, chloroform and other organic solvents (easy to dissolve when heated to 70 °C), decomposed when it meets water, has strong water absorption, and is easily decomposed into aluminum hydroxide and isopropanol.)

Uses

It is used in a number of organic syntheticreactions and in the manufacture of manytypes of products, including aluminum soaps,paints, and waterproofing finishes.

Uses

Alkyl phosphate esters in conjunction with aluminium isopropoxide have been used as fluid loss additives in drilling fluid compositions. It is important for drilling fluids to efficiently and quickly form a filter cake to minimise fluid loss and allow flow of fluids into the wellbore during production. In the alkyl phosphate ester case, it is cross‐linked with the aluminium compound to form a complex anionic polymer, which acts as a gelling agent to prevent fluid loss.

Uses

Meerwein-Ponndorf reactions; alcoholysis and ester exchange; synthesis of higher alkoxides, chelates, and acylates; formation of aluminum soaps, formulation of paints; waterproofing finishes for textiles.

Preparation

Aluminum isopropoxide is synthesized by the reaction of isopropanol and aluminum under the catalysis of alumina. Raw material consumption quota: isopropyl alcohol 1255kg/t, aluminum 166kg/t.

Fire Hazard

The flash point of this compound is 26°C (79°F) (Bretzinger and Josten). It is less flammable than the sec- and tert-alkoxides of alkali metals. Ignition may occur when this compound is heated in moist air.It decomposes in water. The reaction is exothermic, producing isopropanol. It may decompose when heated to 250°C (482°F), producing highly flammable isopropyl ether.

Purification Methods

Redistil it under vacuum. Hygroscopic. [Robinson & Peak J Phys Chem 39 1127 1935, Beilstein 1 IV 1468.]