ChemicalBook > CAS DataBase List > Methyl 6-bromohexanoate

Methyl 6-bromohexanoate

Product Name
Methyl 6-bromohexanoate
CAS No.
14273-90-6
Chemical Name
Methyl 6-bromohexanoate
Synonyms
Bromo-6-methylaniline;Methyl 6-bromocaproate;METHYL 6-BROMOHEXANOATE;6-Methyl broMide has been;6-bromo-2-methylhexanoate;6-bromoacetate methyl ester;Methyl 6-bromohexanoate 98%;Methyl 6-bromohexanoate, 96+%;Methyl 6-broMohexanoate, 96+% 5GR;6-BROMOHEXANOIC ACID METHYL ESTER
CBNumber
CB3359495
Molecular Formula
C7H13BrO2
Formula Weight
209.08
MOL File
14273-90-6.mol
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Methyl 6-bromohexanoate Property

Boiling point:
150°C/50mmHg
Density 
1.316
refractive index 
1.46
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Clear colorless to pale yellow
InChI
InChI=1S/C7H13BrO2/c1-10-7(9)5-3-2-4-6-8/h2-6H2,1H3
InChIKey
KYLVAMSNNZMHSX-UHFFFAOYSA-N
SMILES
C(OC)(=O)CCCCCBr
CAS DataBase Reference
14273-90-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
Hazard Note 
Irritant
HS Code 
29159000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S125334
Product name
6-BROMO-HEXANOIC ACID METHYL ESTER
Purity
Aldrich<sup>CPR</sup>
Packaging
1 unit
Price
$185
Updated
2025/07/31
Sigma-Aldrich
Product number
S125334
Product name
6-BROMO-HEXANOIC ACID METHYL ESTER
Purity
Aldrich
Packaging
25mg
Price
$179
Updated
2024/03/01
TCI Chemical
Product number
M3508
Product name
Methyl 6-Bromohexanoate
Purity
min. 98.0 %
Packaging
25G
Price
$72
Updated
2025/07/31
TRC
Product number
M296198
Product name
Methyl6-Bromohexanoate
Packaging
50g
Price
$130
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB55276
Product name
6-Bromohexanoic acid methyl ester
Packaging
25g
Price
$130
Updated
2021/12/16
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Methyl 6-bromohexanoate Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to pale yellow liquid

Synthesis

4224-70-8

14273-90-6

1. Synthesis of methyl 6-bromohexanoate: Dissolve 5.01 g (25.7 mmol) of 6-bromohexanoic acid in 250 mL of methanol and introduce hydrogen chloride gas by vigorous bubbling for 2-3 minutes. The reaction mixture was stirred at 15-25°C for 3 hours. Upon completion of the reaction, the solvent was removed by concentration to give 4.84 g of yellow oily product in 90% yield. The product was characterized by 1H NMR (DMSO-d6): δ 3.58 (3H, s), 3.51 (2H, t), 2.29 (2H, t), 1.78 (2H, pentet), 1.62-1.27 ppm (4H, m).

References

[1] Patent: US2002/15705, 2002, A1
[2] Patent: US4436746, 1984, A
[3] Patent: US4539410, 1985, A
[4] Patent: EP2425861, 2012, A1
[5] Patent: US2012/65367, 2012, A1

Methyl 6-bromohexanoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 6-bromohexanoate manufacturers

Hefei TianRui Pharmaceutical Chemical Co., Ltd.
Product
Methyl 6-bromohexanoate 14273-90-6
Price
US $0.00-0.00/G
Min. Order
1G
Purity
99%HPLC
Supply Ability
20tons
Release date
2025-09-12
R&D Scientific Inc.
Product
Methyl 6-bromohexanoate 14273-90-6
Price
US $530.00/Kg
Min. Order
1Kg
Purity
99
Supply Ability
5000 Kg
Release date
2024-11-18
Hebei Chuanghai Biotechnology Co,.LTD
Product
Methyl 6-bromohexanoate 14273-90-6
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-12

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