Methylboronic acid

Product Name: Methylboronic acid
CAS No.: 13061-96-6
Chemical Name: Methylboronic acid
Synonyms: METHANDROSTENOLONE;CH5BO2;dihydroxy-methyl-borane;Methyboronic Acid;Methylboranic acid;Methyl boric acid;METHYLBORONIC ACID;METHANEBORONIC ACID;METHYLBORON DIHYDROXIDE;Methylboronic acid ,98%
CBNumber: CB3373202
Molecular Formula: CH5BO2
Formula Weight: 59.86
MOL File: 13061-96-6.mol

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Methylboronic acid Property

Melting point:: 91-94 °C (lit.)
Boiling point:: 141.7±23.0 °C(Predicted)
Density: 0.965±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
solubility: DMSO, Water
pka: 9.97±0.43(Predicted)
form: Crystalline Powder
color: White to off-white
Water Solubility: Soluble in water.
Sensitive: Hygroscopic
BRN: 1731087
InChI: InChI=1S/CH5BO2/c1-2(3)4/h3-4H,1H3
InChIKey: KTMKRRPZPWUYKK-UHFFFAOYSA-N
SMILES: CB(O)O
CAS DataBase Reference: 13061-96-6(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 3-10
Hazard Note: Irritant/Keep Cold
HazardClass: IRRITANT
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 165336
Product name: Methylboronic acid
Purity: 97%
Packaging: 1g
Price: $54.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 165336
Product name: Methylboronic acid
Purity: 97%
Packaging: 5g
Price: $117
Updated: 2024/03/01

TCI Chemical

Product number: M1553
Product name: Methylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $41
Updated: 2024/03/01

TCI Chemical

Product number: M1553
Product name: Methylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $102
Updated: 2024/03/01

Alfa Aesar

Product number: L15589
Product name: Methylboronic acid, 97%
Packaging: 1g
Price: $51.5
Updated: 2024/03/01

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Methylboronic acid Chemical Properties,Usage,Production

Chemical Properties

White to light yellow crystal powde

Uses

suzuki reaction

Uses

Methylboronic Acid is a methylated derivative of boronic acid, a building block towards various intermediates in suzuki coupling.

Uses

Methylboronic acid can be used as a reagent:

In the palladium-catalyzed Stille and Suzuki-Miyaura cross-couplings.
In the microwave-heated heterogeneous palladium (Pd)-catalytized reactions.
In ruthenium (Ru)-catalyzed silylation reactions
To prepare bis(aminotropone) titanium (Ti) catalysts for ethylene polymerizations.
In the enantioselective asymmetric bromoaminocyclization and bromoaminocyclization using amino-thiocarbamate catalysts.
To prepare common building blocks for pharmaceuticals and agrochemicals.
To prepare chrysin analogs by Suzuki-Miyaura coupling reactions.
To prepare casein kinase I inhibitors.
In the divergent C-H functionalizations directed by sulfonamide pharmacophores in drug discovery.
In the synthesis of unsymmetrical monosulfides from disulfides via copper-catalyzed coupling with boronic acids.
In a palladium-catalyzed coupling with enol tosylates.
For derivatizing many carbohydrates and biologically active compounds for GLC analysis.

Methylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

2-Nitrophenylboronic acid

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Methylboronic acid Suppliers

Americas 1 China 281 Europe 3 Germany 3 India 10 Japan 3 Jordan 1 Russia 1 South Korea 1 Switzerland 1 United Kingdom 12 United States 35 Global 352

TCI Europe

Tel: 320-37350700
Fax: +32 (0)37350701
Email: sales@tcieurope.eu
Country: Europe
ProdList: 23680
Advantage: 75

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View Lastest Price from Methylboronic acid manufacturers

Henan Bao Enluo International TradeCo.，LTD

Product: Methylboronic acid 13061-96-6
Price: US $30.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 50000tons
Release date: 2023-05-12

Hebei Fengqiang Trading Co., LTD

Product: Methylboronic acid 13061-96-6
Price: US $100.00/bag
Min. Order: 1bag
Purity: 99
Supply Ability: 5000
Release date: 2023-08-30

Hebei Mojin Biotechnology Co., Ltd

Product: Methylboronic acid 13061-96-6
Price: US $100.00/Kg/Drum
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000tons
Release date: 2021-10-08

13061-96-6, Methylboronic acidRelated Search:

Zinc borate Citric acid Hyaluronic acid Folic acid Ethyl 2-(Chlorosulfonyl)acetate Stearic acid Phenylboronic acid 2-Bromo-4-(methoxycarbonyl)-5-methyl-1,3-thiazole 2-Methylsuccinic acid Ascoric Acid 3,5-Bis(trifluoromethyl)benzeneboronic acid 4-Bromophenylboronic acid 3-Aminobenzeneboronic acid hemisulfate salt 4-Chlorophenylboronic acid 3-Nitrophenylboronic acid 3-Methoxyphenylboronic acid Allylboronic acid pinacol ester 1-Naphthylboronic acid

METHYLBORON DIHYDROXIDE

METHYLBORONIC ACID

METHANEBORONIC ACID

CH5BO2

dihydroxy-methyl-borane

Methylboron dihydroxide, GLC Grade

Methylboronic acid ,98%

Methylboranic acid

Methylboronic Acid (contains varying amounts of Anhydride)

METHYLBORONIC ACID FOR GC

METHANDROSTENOLONE

Methylboronic acid CH3B(OH)2

Methylboronic acid(Methaneboronic acid)

Boronic acid, methyl- (9CI)

Methyboronic Acid

Methylboronic acid, 98%, for synthesis

TIANFU CHEM----Methylboronic acid

Methyl boric acid

13061-96-6

13061-96-5

CH5O2B

CH3BOH2

Organometallic Reagents

Acylation

Alkyl

Boronic Acids

Boronic Acids and Derivatives

Piperidines ,Piperazines ,Homopiperidines

Alkyl

API intermediates

Boronic acid

Organoborons

Substituted Boronic Acids

CHIRAL CHEMICALS