4-BROMO-2-FLUOROBENZYLAMINE

Product Name: 4-BROMO-2-FLUOROBENZYLAMINE
CAS No.: 112734-22-2
Chemical Name: 4-BROMO-2-FLUOROBENZYLAMINE
Synonyms: (4-BroMo-2-fluorophenyl)MethanaMine;MINA-002;TIMTEC-BB SBB005778;RARECHEM AL BW 0772;4-BROMO-2-FLUOROBENZYLAMINE;2-FLUORO-4-BROMOBENZYL AMINE;4-Bromo-2-fluorobenzylamine,99%;2-Fluoro-4-Bromobenzylamine HCl;4-Bromo-2-fluorobenzenemethanamine;4-BroMo-2-fluorobenzylaMine, 99% 5GR
CBNumber: CB3443035
Molecular Formula: C7H7BrFN
Formula Weight: 204.04
MOL File: 112734-22-2.mol

More

Less

4-BROMO-2-FLUOROBENZYLAMINE Property

Boiling point:: 244.5±25.0 °C(Predicted)
Density: 1.571±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 8.43±0.10(Predicted)
form: Liquid
Specific Gravity: 1.58
color: Clear colorless to slightly yellow
InChI: InChI=1S/C7H7BrFN/c8-6-2-1-5(4-10)7(9)3-6/h1-3H,4,10H2
InChIKey: RLTFBWCBGIZCDQ-UHFFFAOYSA-N
SMILES: C1(CN)=CC=C(Br)C=C1F
CAS DataBase Reference: 112734-22-2(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: C,Xi
Risk Statements: 34-21/22-36
Safety Statements: 45-36/37/39-26
RIDADR: 2735
Hazard Note: Irritant
HazardClass: 8
PackingGroup: Ⅲ
HS Code: 29214900

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

TRC

Product number: B750228
Product name: 4-Bromo-2-fluorobenzylamine
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB64371
Product name: 4-Bromo-2-fluorobenzyl amine
Packaging: 1g
Price: $50
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB64371
Product name: 4-Bromo-2-fluorobenzyl amine
Packaging: 2g
Price: $70
Updated: 2021/12/16

Matrix Scientific

Product number: 090285
Product name: 4-Bromo-2-fluorobenzyl amine
Purity: 95+%
Packaging: 5g
Price: $72
Updated: 2021/12/16

AK Scientific

Product number: X8114
Product name: 4-Bromo-2-fluorobenzylamine
Packaging: 5g
Price: $89
Updated: 2021/12/16

More

Less

4-BROMO-2-FLUOROBENZYLAMINE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to slightly yellow liquid

Synthesis

105942-08-3

112734-22-2

General procedure for the synthesis of (4-bromo-2-fluorophenyl)methanamine from 4-bromo-2-fluorobenzonitrile: 4-bromo-2-fluorobenzonitrile (5.00 mmol) was dissolved in tetrahydrofuran (THF, 30 mL) and the solution was cooled to 0°C. A solution of borane tetrahydrofuran complex (1 M solution of THF, 15.0 mL) was added slowly and dropwise with stirring. The reaction mixture was continued to be stirred at 0 °C for 20 min, followed by warming to room temperature and stirring for 16 hours. Upon completion of the reaction, methanol (MeOH, 30 mL) was added slowly and dropwise to quench the reaction, followed by concentration of the solution under reduced pressure. The residue was extracted by partitioning with 1 M aqueous sodium hydroxide (NaOH) and ethyl acetate (EtOAc). The organic layer was separated and post-processed to give (4-bromo-2-fluorophenyl)methylamine (5.00 mmol) as a yellow oil.1H NMR (400 MHz, CDCl3) data: δ 7.42-7.27 (m, 1H), 7.25-7.16 (m, 2H), 3.65 (t, J = 6.6 Hz, 2H).

References

[1] Journal of Organic Chemistry, 2008, vol. 73, # 5, p. 1898 - 1905
[2] Journal of Organic Chemistry, 2009, vol. 74, # 5, p. 1964 - 1970
[3] Patent: WO2017/103611, 2017, A1. Location in patent: Paragraph 00336
[4] Patent: WO2018/75871, 2018, A1. Location in patent: Page/Page column 62

4-BROMO-2-FLUOROBENZYLAMINE Preparation Products And Raw materials

Raw materials

Ethanol 4-Bromo-2-fluorobenzonitrile Palladium

Preparation Products

More

Less

4-BROMO-2-FLUOROBENZYLAMINE Suppliers

Belgium 2 China 115 Europe 2 Germany 3 India 3 Japan 2 Ukraine 1 United Kingdom 13 United States 21 Global 162

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Adamas Reagent, Ltd.

Tel: 400-6009262 16621234537
Fax: 021-64823266
Email: chenyj@titansci.com
Country: China
ProdList: 14101
Advantage: 59

Shanghai Harvest Chemical Industrial Co., Ltd.

Tel: 021-31038972,31038973 17321035817
Fax: +86-21-51385350
Email: sales@harvest-chem.com
Country: China
ProdList: 2816
Advantage: 64

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 15883
Advantage: 64

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12984
Advantage: 57

More

Less

View Lastest Price from 4-BROMO-2-FLUOROBENZYLAMINE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-BROMO-2-FLUOROBENZYLAMINE 112734-22-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-BROMO-2-FLUOROBENZYLAMINE 112734-22-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

Career Henan Chemical Co

Product: 4-BROMO-2-FLUOROBENZYLAMINE 112734-22-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000KG
Release date: 2019-12-31

112734-22-2, 4-BROMO-2-FLUOROBENZYLAMINERelated Search:

4-BROMO-2-FLUOROBENZYLAMINE STATIL 4-Bromo-2-fluorobenzylamine hydrochloride Zenarestat 4-BROMO-2-FLUOROBENZAMIDE 5-Bromo-2-fluorobenzylamine hydrochloride 3-BROMO-4-FLUOROBENZAMIDOXIME 2-Bromo-5-fluorobenzylamine 4-Bromobenzylamine 2-Fluorobenzylamine 3-BroMo-4-fluorobenzyl alcohol 4-BROMO-2-FLUOROBENZYLPHTHALIMIDE Minalrestat 4-BROMO-2-FLUORO-BENZAMIDINE HYDROCHLORIDE 3-AMINO-3-(4-BROMO-2-FLUOROPHENYL)PROPANOIC ACID 1-(4-BROMO-2-FLUOROBENZYL)-1,4-DIAZEPANE 5-BROMO-2-FLUOROBENZYLAMINE HCL,5-BROMO-2-FLUOROBENZYLAMINE HYDROCHLORID 2-BROMO-5-FLUOROBENZYLAMINE HYDROCHLORIDE,2-BROMO-5-FLUOROBENZYLAMINE HCL,5-BROMO-2-FLUOROBENZYLAMINE HCL

RARECHEM AL BW 0772

TIMTEC-BB SBB005778

4-BROMO-2-FLUOROBENZYLAMINE

2-FLUORO-4-BROMOBENZYL AMINE

2-Fluoro-4-Bromobenzylamine HCl

4-Bromo-2-fluorobenzylamine,99%

4-BroMo-2-fluorobenzylaMine, 99% 5GR

(4-broMo-2-fluorophenyl)MethanaMine hydrochloride

(4-BroMo-2-fluorophenyl)MethanaMine

Benzenemethanamine, 4-bromo-2-fluoro-

MINA-002

4-Bromo-2-fluorobenzenemethanamine

112734-22-2

Fluorine series

Anilines, Aromatic Amines and Nitro Compounds

Amine