(S)-1-CBZ-3-PYRROLIDINOL 95

Product Name: (S)-1-CBZ-3-PYRROLIDINOL 95
CAS No.: 100858-32-0
Chemical Name: (S)-1-CBZ-3-PYRROLIDINOL 95
Synonyms: CAS:100858-32-0;(S)-1-Cbz-3-pyrrolodonol95;(S)-1-CBZ-3-PYRROLIDINOL 95;(S)-N-Cbz-3-hydroxypyrroline;(S)-(+)-1-Cbz-3-pyrrolidinol;N-Cbz-3(S)-hydroxypyrrolidine;S-1-N-CBZ-3- hydroxy-pyrroline;(S)-1-Cbz-3-hydroxypyrrolidine;(S)-N-CBZ-3-HYDROXYPYRROLIDINE;(S)-(+)-1-Cbz-3-pyrrolidinol 98%
CBNumber: CB3505445
Molecular Formula: C12H15NO3
Formula Weight: 221.25
MOL File: 100858-32-0.mol

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(S)-1-CBZ-3-PYRROLIDINOL 95 Property

Melting point:: 71-77 °C
Boiling point:: 370.7±42.0 °C(Predicted)
Density: 1.263±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: solid
pka: 14.72±0.20(Predicted)
Appearance: White to off-white Solid
optical activity: [α]20/D +21°, c = 1 in chloroform
InChI: InChI=1S/C12H15NO3/c14-11-6-7-13(8-11)12(15)16-9-10-4-2-1-3-5-10/h1-5,11,14H,6-9H2/t11-/m0/s1
InChIKey: MBLJFGOKYTZKMH-NSHDSACASA-N
SMILES: N1(C(OCC2=CC=CC=C2)=O)CC[C@H](O)C1

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Safety

Hazard Codes: T
Risk Statements: 25-36/37/38
Safety Statements: 26-36-45-25
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
HazardClass: 6.1
HS Code: 29339900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 654663
Product name: (S)-(+)-1-Cbz-3-pyrrolidinol
Purity: 95%
Packaging: 1g
Price: $69.2
Updated: 2023/01/07

Sigma-Aldrich

Product number: 654663
Product name: (S)-(+)-1-Cbz-3-pyrrolidinol
Purity: 95%
Packaging: 5g
Price: $259
Updated: 2023/01/07

TCI Chemical

Product number: C2453
Product name: (S)-1-Carbobenzoxy-3-pyrrolidinol
Purity: >97.0%(GC)
Packaging: 1g
Price: $16
Updated: 2021/12/16

TCI Chemical

Product number: C2453
Product name: (S)-1-Carbobenzoxy-3-pyrrolidinol
Purity: >97.0%(GC)
Packaging: 5g
Price: $48
Updated: 2021/12/16

TRC

Product number: B194225
Product name: (S)-(+)-1-Benzyloxycarbonyl-3-hydroxypyrrolidine
Packaging: 250mg
Price: $55
Updated: 2021/12/16

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(S)-1-CBZ-3-PYRROLIDINOL 95 Chemical Properties,Usage,Production

Chemical Properties

White to off-white crystal powder or solid

Synthesis

130312-02-6

100858-32-0

General procedure for the synthesis of benzyl (S)-3-hydroxypyrrolidine-1-carboxylate using N-Cbz-3-pyrrolidone as starting material: a reaction mixture containing 200 mM substrate, 1 mM NAD+, 5% (v/v) 2-propanol, and 10 mg of the crude enzyme READH was prepared in 1 mL of potassium phosphate buffer (100 mM, pH 7.0) and warmed at 50 °C. For ChKRED20, 40% (v/v) 2-propanol was used and the reaction was carried out at 40°C. The reaction progress was monitored by TLC and the reaction was terminated by extraction with methyl tert-butyl ether (1 mL). The organic phase was dried over anhydrous sodium sulfate and concentrated. Samples were analyzed by chiral HPLC to determine conversion and enantiomeric excess. The final product was purified by silica gel column chromatography and the structure was confirmed by NMR, spin determination and mass spectrometry.

References

[1] Process Biochemistry, 2017, vol. 56, p. 90 - 97

(S)-1-CBZ-3-PYRROLIDINOL 95 Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-1-CBZ-3-PYRROLIDINOL 95 Suppliers

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View Lastest Price from (S)-1-CBZ-3-PYRROLIDINOL 95 manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: (S)-1-CBZ-3-PYRROLIDINOL 95 100858-32-0
Price: US $9.00/KG
Min. Order: 1KG
Purity: 99.9
Supply Ability: 1 ton
Release date: 2024-08-21

Career Henan Chemical Co

Product: (S)-1-CBZ-3-PYRROLIDINOL 95 100858-32-0
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-18

100858-32-0, (S)-1-CBZ-3-PYRROLIDINOL 95Related Search:

(R)-1-CBZ-3-PYRROLIDINOL 5-DIMETHYLAMINO-1-NAPHTHALENESULFONIC ACID HYDRATE N-Cbz-Nortropinone (R)-(-)-3-Pyrrolidinol hydrochloride (R)-3-AMINO-1-CBZ-PYRROLIDINE 3-Pyrrolidinol Benzyl formate N-CBZ-TRANS-4-HYDROXY-D-PROLINE METHYL ESTER 1,4-DIOXA-7-AZA-SPIRO[4.4]NONANE-7-CARBOXYLIC ACID BENZYL ESTER N-(BENZYLOXYCARBONYL)-5-ANTI-ACETOXY-3-EXO-PHENYL-2-AZABICYCLO-[2.1.1]HEXANE Z-CIS-HYP-OH trans-3-Benzylamino-1-Cbz-4-hydroxypyrrolidine (2R,4S)-N-ALPHA-CARBOBENZOXY-4-HYDROXYPYRROLIDINE-2-CARBOXYLIC ACID CIS-ZHPROME (S)-1-CBZ-3-PYRROLIDINOL 95 benzyl (3S)-3-(pyridin-4-yloxy)pyrrolidine-1-carboxylate

(S)-(+)-1-Cbz-3-pyrrolidinol 98%

(S)-3-hydroxy-1-pyrrolidinecarboxylic acid phenylmethyl ester

S-1-N-CBZ-3- hydroxy-pyrroline

(S)-1-Cbz-3-pyrrolidinol (S)-1-Carbobenzoxy-3-hydroxypyrrolidine

(S)-(-)-1-Benzyloxycarbonyl-3-hydroxypyrrolidine, 95%

(S)-(+)-1-Cbz-3-pyrrolidinol, 98%, ee: 98%

(S)-(+)-1-Cbz-3-pyrrolidinol, ee: 98%

1-Pyrrolidinecarboxylic acid, 3-hydroxy-, phenylmethyl ester, (3S)-

(S)-N-Cbz-3-hydroxypyrroline

(S)-N-Cbz-3-hydroxypyrroline,99%e.e.

(S)-1-CBZ-3-PYRROLIDINOL 95

(S)-N-CBZ-3-HYDROXYPYRROLIDINE

N-Cbz-3(S)-hydroxypyrrolidine

(S)-1-Benzyloxycarbonyl-3-pyrrolidinol, (S)-1-Carbobenzoxy-3-pyrrolidinol, (S)-N-Z-3-Pyrrolidinol

(S)-1-Cbz-3-hydroxypyrrolidine

benzyl (3S)-3-hydroxypyrrolidine-1-carboxylate

(S)-3-Hydroxy-pyrrolidine-1-carboxylic acid benzyl ester

(S)-(+)-1-Cbz-3-pyrrolidinol

(S)-1-Carbobenzoxy-3-pyrrolidinol &gt

(S)-1-Carbobenzoxy-3-hydroxypyrrolidine

(S)-(3-hydroxypyrrolidin-1-yl)(phenyl)methanone

Benzyl (S)-3-hydroxypyrrolidine-1-carboxylate

Phenylmethyl (3S)-3-hydroxy-1-pyrrolidinecarboxylate

(S)-1-Cbz-3-pyrrolodonol95

CAS:100858-32-0

(<i>S</i>)-(+)-1-Cbz-3-pyrrolidinol

(S)-1-Cbz-3-hydroxypyrrolidine - [H12296]

100858-32-0

Pyrrole&Pyrrolidine&Pyrroline