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Diethylene glycol divinyl ether

Product Name
Diethylene glycol divinyl ether
CAS No.
764-99-8
Chemical Name
Diethylene glycol divinyl ether
Synonyms
Dvedeg;DEGDVE;Divinylcarbitol;1,1’-[Oxybis(2,1;Bis(2-vinyloxyethyl)ether;ether,bis(2-vinyloxyethyl);1,5-Divinyloxy-3-oxapentane;DIETHYLENGLYCOLDIVINYLETHER;divinyletherdiethylenglykolu;Ether, bis[2-(vinyloxy)ethyl]
CBNumber
CB3730649
Molecular Formula
C8H14O3
Formula Weight
158.2
MOL File
764-99-8.mol
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Diethylene glycol divinyl ether Property

Melting point:
-21°C
Boiling point:
198-199 °C (lit.)
Density 
0.968 g/mL at 25 °C (lit.)
vapor pressure 
17Pa at 20℃
refractive index 
n20/D 1.446(lit.)
Flash point:
160 °F
storage temp. 
Store below +30°C.
form 
clear liquid
color 
Colorless to Almost colorless
Water Solubility 
Insoluble in water.
Sensitive 
Light Sensitive
BRN 
1752316
InChIKey
SAMJGBVVQUEMGC-UHFFFAOYSA-N
LogP
1.8 at 23℃
CAS DataBase Reference
764-99-8(CAS DataBase Reference)
NIST Chemistry Reference
Ethene, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-(764-99-8)
EPA Substance Registry System
Ethene, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- (764-99-8)
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Safety

Risk Statements 
36/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
KN3850000
TSCA 
Yes
HS Code 
2909 19 90
Toxicity
LD50 oral in rat: 3730mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.40144
Product name
Diethylene glycol divinyl ether
Purity
for synthesis
Packaging
50mL
Price
$187
Updated
2024/03/01
Sigma-Aldrich
Product number
139548
Product name
Di(ethylene glycol) divinyl ether
Purity
99%
Packaging
50ml
Price
$156
Updated
2024/03/01
TCI Chemical
Product number
D0498
Product name
Diethylene Glycol Divinyl Ether (stabilized with KOH)
Purity
>98.0%(GC)
Packaging
25mL
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
D0498
Product name
Diethylene Glycol Divinyl Ether (stabilized with KOH)
Purity
>98.0%(GC)
Packaging
100mL
Price
$211
Updated
2024/03/01
Alfa Aesar
Product number
L12501
Product name
Diethylene glycol divinyl ether, 98%, stab. 0.1% potassium hydroxide
Packaging
10g
Price
$46.65
Updated
2024/03/01
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Diethylene glycol divinyl ether Chemical Properties,Usage,Production

Chemical Properties

diethylene glycol divinyl ether is monomeric in character and is used as a chemical intermediate or as a crosslinking agent. Addition of isocyanic acid produces secondary diisocyanates. Divinyl ethers hydrolyze to the glycol and acetaldehyde. Chlorine or bromine add to the double bonds. Reaction with an alcohol in the presence of water produces a diacetal. Polymerization of divinyl ether of diethylene glycol with acidic catalysts produce crosslinked gels. Unsaturated polyesters, crosslinked with styrene, have been made noncorrosive to metals through use of divinyl ethers to reduce hydroxyl ond acid numbers.

Chemical Properties

Diethylene glycol divinyl ether (DEGDVE) is a colorless and transparent liquid with a boiling point of 198 °C under atmospheric pressure. It is miscible with alcohol, ether, ester and aromatic hydrocarbon, but only slightly soluble in water. Both DEGMVE and DEGDVE are chemical active and easy to be polymerized, and a small amount of NaOH is often added as a polymerization inhibitor.

Uses

Diethylene glycol divinyl ether is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Application

Diethylene glycol divinyl ether (DEGDVE) has attracted much attention due to the homopolymerization and structural diversity of copolymerization products, and it is often used as a cross-linking agent in various functional materials. Hydrogels are hydrophilic network polymers that absorb large amounts of water but are insoluble in water. The properties of high water content and insolubility in water make the materials widely used in biomedical fields such as drug delivery systems, biosensors, contact lenses, catheters, and wound dressings. Using DEGDVE as a cross-linking agent and 60Co as γ-radiation light source, hydrogels were prepared by radiation copolymerization of hydrophilic ethylene glycol monovinyl ether, hydrophobic BVE, and acidic acrylic acid. The resulting hydrogels were pH- and temperature-sensitive functional materials.
Using DEGDVE as a cross-linking agent, 2-acrylamido-2-methylpropanesulfonic acid and sodium styrene sulfonate as monomers, a plugging agent with high-temperature resistance and salt resistance was synthesized by emulsion polymerization, which has practical significance in solving the problem of water production in oil wells and plays a vital role in improving oil recovery ratio.
A three-dimensional substance with a special space structure can be synthesized by cross-linking copolymerization with DEGDVE and used as a modified substrate material. For example, cross-linking copolymerization of methyl vinyl sulfide with DEGDVE gave a solid polymer with a crown structure, which was modified and used as active matrices of solid superbases for ethynylation of acetone and vinylation of diethylene glycol or ethylene glycol.

Flammability and Explosibility

Non flammable

Synthesis

Acetylene reacts with diethylene glycol in the presence of a catalyst such as potassium hydroxide or potassium diethylene glycol to yield DEGMVE and Diethylene glycol divinyl ether (DEGDVE):

Diethylene glycol divinyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Diethylene glycol divinyl ether manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Diethylene glycol divinyl ether 764-99-8
Price
US $20.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-13
Career Henan Chemical Co
Product
Diethylene glycol divinyl ether 764-99-8
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-21

764-99-8, Diethylene glycol divinyl etherRelated Search:


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