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3-Aminopropionitrile

Product Name
3-Aminopropionitrile
CAS No.
151-18-8
Chemical Name
3-Aminopropionitrile
Synonyms
3-AMINOPROPANENITRILE;BAPN;β-aminopropionitrile;beta-Aminopropionitrile;AMINOPROPIONITRILE;2-CYANOETHYLAMINE;beta-Alaninenitrile;B-AMINOPROPIONITRILE;BETA-AMINOPROPIONONITRILE;e (stabiL
CBNumber
CB3853135
Molecular Formula
C3H6N2
Formula Weight
70.09
MOL File
151-18-8.mol
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3-Aminopropionitrile Property

Melting point:
<25 °C
Boiling point:
185 °C
Density 
0.9584
refractive index 
1.4365-1.4395
Flash point:
79-81°C/16mm
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
solubility 
Chloroform, Methanol
form 
Liquid
pka
7.80(at 20℃)
color 
Clear colorless to yellow
Water Solubility 
Soluble in water.
Sensitive 
Air & Moisture Sensitive
Merck 
14,469
BRN 
1698848
InChIKey
AGSPXMVUFBBBMO-UHFFFAOYSA-N
CAS DataBase Reference
151-18-8(CAS DataBase Reference)
EPA Substance Registry System
Propanenitrile, 3-amino- (151-18-8)
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Safety

Hazard Codes 
Xn,C
Risk Statements 
20/21/22-34-22-63
Safety Statements 
36/37-45-36/37/39-26
RIDADR 
3276
RTECS 
UG0350000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29269090
Hazardous Substances Data
151-18-8(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H227Combustible liquid

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H361Suspected of damaging fertility or the unborn child

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CDS007521
Product name
3-amino-propionitrile
Purity
AldrichCPR
Packaging
1G
Price
$201
Updated
2023/06/20
TCI Chemical
Product number
A0408
Product name
3-Aminopropionitrile (stabilized with K2CO3)
Purity
>98.0%(GC)(T)
Packaging
25mL
Price
$123
Updated
2024/03/01
Alfa Aesar
Product number
A13043
Product name
3-Aminopropionitrile, 98%, stab. with potassium carbonate
Packaging
1g
Price
$37.65
Updated
2024/03/01
Alfa Aesar
Product number
A13043
Product name
3-Aminopropionitrile, 98%, stab. with potassium carbonate
Packaging
5g
Price
$102.65
Updated
2024/03/01
Alfa Aesar
Product number
A13043
Product name
3-Aminopropionitrile, 98%, stab. with potassium carbonate
Packaging
25g
Price
$353.65
Updated
2024/03/01
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3-Aminopropionitrile Chemical Properties,Usage,Production

Chemical Properties

clear colourless to yellow liquid. 3-Aminopropionitrile, [151-18-8], 3-aminopropanenitrile, b-aminopropionitrile, H2N – CH2 – CH2CN, Mr 70.09, bp 185℃ (101.3 kPa), n20D 1.4396, is a colorless liquid which tends to slowly polymerize if stored in the presence of air. 3-Aminopropionitrile is prepared by the reaction of acrylonitrile with ammonia and is mainly used as an intermediate in the manufacture of b-alanine and pantothenic acid [48].

Uses

Production of β-alanine and pantothenic acid.

Uses

3-Aminopropionitrile is used for organic synthesis and as pharmaceutical intermediates. As an intermediate used in the manufacture of beta-alanine and pantothenic acid.

Definition

ChEBI: 3-Aminopropionitrile is an aminopropionitrile carrying an amino group at the beta-position. It has a role as a plant metabolite, an antineoplastic agent, an antirheumatic drug and a collagen cross-linking inhibitor. It is a conjugate base of a beta-ammoniopropionitrile.

Safety Profile

Moderately toxic by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. Nitriles usually have cyanide-like effects. See also CYANIDE. Easily oxidized and unstable. A storage hazard; it polymerizes to an explosive yellow solid. When heated to decomposition it emits toxic fumes of CNand NO,. For fire and explosion hazards see CYANIDE.

Metabolism

3-Aminopropionitrile is the compound present in some Lathyms species (Leguminosae), especially sweet-pea seeds (L. odoratus), causing osteolathyrism in man and animals. Although 3-aminopropionitrile is generally present in the fresh plant as the gama-glutamyl derivative, only the free amine is an effective lathyrogen.
Osteolathyrogens cause skeletal deformations due to interference with the cross-linking between polypeptide chains in the connective tissue components, elastin and collagen. This interference is partly due to inhibition of the synthesis of desmosine and isodesmosine, amino acids which effect the cross-linking in elastin. Cross-linking interference of collagen can be prevented in chicks by feed- ing excess calcium.
It is possible that 3-aminopropionitrile is adegradation product of 3-cyano-alanine, although in many plants the latter compound is converted to asparagine and it has not been detected in Lathyms species.

References

[1] CHAO HAN . Nitrilase-catalyzed hydrolysis of 3-aminopropionitrile at high concentration with a tandem reaction strategy for shifting the reaction to β-alanine formation[J]. Journal of Molecular Catalysis B-enzymatic, 2015, 115: Pages 113-118. DOI:10.1016/j.molcatb.2015.02.007.
[2] C. RICHARD . Rotational spectrum of 3-aminopropionitrile and searches for it in Sagittarius B2(N)[J]. Journal of Molecular Spectroscopy, 2018, 345: Pages 51-59. DOI:10.1016/j.jms.2017.12.003.
[3] MSIEDEEN A A. Conformational Stability of 3-aminopropionitrile: DFT and Ab initio Calculations.[J]. Acta Chimica Slovenica, 2024, 71 2: 244-255. DOI:10.17344/acsi.2023.8486.
[4] A.L.G. ALVES PHD1. Effects of beta-aminopropionitrile fumarate and exercise on equine tendon healing: Gross and histological aspects[J]. Journal of Equine Veterinary Science, 2001, 21 7: Pages 335-340. DOI:10.1016/S0737-0806(01)70076-7.

3-Aminopropionitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Aminopropionitrile Suppliers

Carbosynth
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Molekula Limited
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Fisher Scientific Uk Ltd.
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Manchester Organics
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United Kingdom
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CARBONE SCIENTIFIC CO.,LTD
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Leancare Ltd.
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MOLEKULA Ltd.
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ARIAC - Armenian Institute of Applied Chemistry
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VWR International
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View Lastest Price from 3-Aminopropionitrile manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
3-Aminopropionitrile 151-18-8
Price
US $990.00-800.00/ton
Min. Order
1ton
Purity
99%
Supply Ability
5000
Release date
2024-08-19
Hebei Chuanghai Biotechnology Co,.LTD
Product
3-Aminopropionitrile 151-18-8
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23
Shaanxi Dideu Medichem Co. Ltd
Product
3-Aminopropionitrile 151-18-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG
Release date
2024-07-16

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