1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI)

Product Name: 1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI)
CAS No.: 147081-59-2
Chemical Name: 1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI)
Synonyms: -tert-Butyl 3-(methylamino);1-N-Boc-(S)-(methylamino)-pyrrolidine;1-N-Boc-3-(S)-(Methylamino) pyrrolidine;ert-butyl(3S)-3-(methylamino)pyrrolidine-1-carboxylate;tert-butyl (S)-3-(methylamino)pyrrolidine-1-carboxylate;tert-Butyl-(3S)-3-(methylamino)pyrrolidine-1-carboxylate;(3S)-(Methylamino)pyrrolidine-1-carboxylic acid tert-butyl ester;1,1-Dimethylethyl (3S)-3-(methylamino)-1-pyrrolidinecarboxylate.;(3S)-3-(Methylamino)-1-pyrrolidinecarboxylic acid tert-butyl ester;(3S)-3-(Methylamino)-1-Pyrrolidinecarboxylicacid 1,1-imethylethyl ester
CBNumber: CB41297481
Molecular Formula: C10H20N2O2
Formula Weight: 200.28
MOL File: 147081-59-2.mol

More

Less

1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI) Property

Boiling point:: 269℃
Density: 1.03
Flash point:: 117℃
storage temp.: 2-8°C(protect from light)
pka: 10.02±0.20(Predicted)
Appearance: Colorless to light yellow Liquid

More

Less

Safety

HS Code: 2933998090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

TRC

Product number: B810408
Product name: (S)-tert-Butyl3-(methylamino)pyrrolidine-1-carboxylate
Packaging: 100mg
Price: $45
Updated: 2021/12/16

TRC

Product number: B810408
Product name: (S)-tert-Butyl3-(methylamino)pyrrolidine-1-carboxylate
Packaging: 500mg
Price: $110
Updated: 2021/12/16

TRC

Product number: B810408
Product name: (S)-tert-Butyl3-(methylamino)pyrrolidine-1-carboxylate
Packaging: 1g
Price: $175
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB142634
Product name: (S)-tert-Butyl 3-(methylamino)pyrrolidine-1-carboxylate
Packaging: 250mg
Price: $60
Updated: 2021/12/16

Matrix Scientific

Product number: 122573
Product name: (S)-1-Boc-3-(methylamino)pyrrolidine
Purity: 97.0%
Packaging: 1g
Price: $78
Updated: 2021/12/16

More

Less

1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI) Chemical Properties,Usage,Production

Synthesis

892390-43-1

147081-59-2

To a stirred solution of (3S)-3-(formylamino)pyrrolidine-1-carboxylic acid tert-butyl ester (2.29 g, 10 mmol) in tetrahydrofuran (35 ml) at 0°C was slowly added a tetrahydrofuran solution of 1 M borane (32 ml, 32 mmol). The reaction mixture was stirred at room temperature for 18 h. The reaction was quenched with methanol (10 ml) followed by vacuum concentration. The resulting white solid was redissolved in methanol (30 ml) and heated to reflux for 18 hours. Finally, the solvent was removed by vacuum evaporation to afford (S)-1-Boc-3-(methylamino)pyrrolidine as a light yellow oil (2.45 g, 12.2 mmol, 100% yield). The product was characterized by 1HNMR (400 MHz, CDCl3): δ 1.45 (s, 9H), 1.47-1.77 (m, 2H), 1.71 (m, 1H), 2.03 (m, 1H), 2.43 (s, 3H), 3.04-3.26 (m, 1H), 3.29-3.58 (m, 2H); LRMS m/z ELSD- apci+ 201 [mh]+.

References

[1] Patent: WO2006/64336, 2006, A2. Location in patent: Page/Page column 43-44

1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI) Suppliers

China 98 Europe 1 Germany 1 India 2 Switzerland 1 United Kingdom 3 United States 12 Global 118

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Adamas Reagent, Ltd.

Tel: 400-6009262 16621234537
Fax: 021-64823266
Email: chenyj@titansci.com
Country: China
ProdList: 14101
Advantage: 59

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

China Langchem Inc.

Tel: 0086-21-58956006
Fax: 0086-21-58956100
Country: China
ProdList: 7811
Advantage: 57

Amber MolTech LLC

Tel: 086-010-62176588
Fax: 086-010-62117849
Email: amber@jyamber.com
Country: China
ProdList: 10151
Advantage: 56

NovoChemy Ltd.

Tel: 021-31261262/ 49 (0)17662837245
Fax: (0)21-33250524
Email: sales@novochemy.com
Country: Germany
ProdList: 6328
Advantage: 58

Shanghai T&W Pharmaceutical Co., Ltd.

Tel: +86 21 61551611
Fax: +86 21 50676805
Country: China
ProdList: 9891
Advantage: 58

More

Less

View Lastest Price from 1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI) manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: 1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI) 147081-59-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-26

147081-59-2, 1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI)Related Search:

(S)-tert-butyl 4-(1-aminoethyl)piperidine-1-carboxylate (S)-1-Boc-3-hydroxymethyl-piperazine (S)-1-Boc-3-(hyroxymethyl)piperidine N-Boc-cis-4-Fmoc-Amino-L-proline (1S,4S)-2-BOC-2,5-DIAZABICYCLO[2.2.1]HEPTANE (2S,4S)-BOC-4-(BOC-AMINO)-PROLINE 1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI) (S)-1-BOC-3-N-(PYRIDIN-4-YLMETHYL)-AMINO-PYRROLIDINE (S)-1-BOC-3-ACETAMIDOPYRROLIDINE (S)-(+)-N-BOC-3-N-FMOC-AMINOPYRROLIDINE& (3R,4S)-1-Boc-4-Fmoc-amino-3-pyrrolidinecarboxylic acid (S,S)-3-BOC-3,6-DIAZABICYCLO[3.2.0]HEPTANE (1S,4S)-5-T-BOC-2,5-DIAZABICYCLO[2.2.1]HEPTANE-2-CARBOXAMIDE tert-butyl (3S)-3-[(5-amino-6-chloropyrimidin-4-yl)amino]pyrrolidine-1-carboxylate tert-butyl (3R,4R)-3-hydroxy-4-(methylamino)pyrrolidine-1-carboxylate trans-3-Benzylamino-1-Boc-4-hydroxypyrrolidine (3AS,6AS)-TERT-BUTYL HEXAHYDROPYRROLO[3,2-B]PYRROLE-1(2H)-CARBOXYLATE TERT-BUTYL (3AS,6AS)-HEXAHYDROPYRROLO[3,4-B]PYRROLE-5(1H)-CARBOXYLATE

1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI)

(3S)-3-(Methylamino)-1-Pyrrolidinecarboxylicacid 1,1-imethylethyl ester

tert-Butyl-(3S)-3-(methylamino)pyrrolidine-1-carboxylate

1-N-Boc-3-(S)-(Methylamino) pyrrolidine

1-N-Boc-(S)-(methylamino)-pyrrolidine

-tert-Butyl 3-(methylamino)

1-Pyrrolidinecarboxylicacid,3-(MethylaMino)-,1,1-diMethylethylester,(3S)-

(3S)-3-(Methylamino)-1-pyrrolidinecarboxylic acid tert-butyl ester

tert-butyl (S)-3-(methylamino)pyrrolidine-1-carboxylate

ert-butyl(3S)-3-(methylamino)pyrrolidine-1-carboxylate

1-Pyrrolidinecarboxylicacid,3-(methylamino)-,1,1-dimethylethylester,(3S)-(9CI) USP/EP/BP

(3S)-(Methylamino)pyrrolidine-1-carboxylic acid tert-butyl ester

1,1-Dimethylethyl (3S)-3-(methylamino)-1-pyrrolidinecarboxylate.

147081-59-2

AMINOACID