Tributyl borate

Product Name: Tributyl borate
CAS No.: 688-74-4
Chemical Name: Tributyl borate
Synonyms: TRI-N-BUTYL BORATE;BORIC ACID TRIBUTYL ESTER;AI311060;borester2;AI3 11060;AI3-11060;Borester 2;n-Butoxide;(n-C4H9O)3B;Buty borate
CBNumber: CB4145842
Molecular Formula: C12H27BO3
Formula Weight: 230.16
MOL File: 688-74-4.mol

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Tributyl borate Property

Melting point:: -70 °C (lit.)
Boiling point:: 114-115 °C/12 mmHg (lit.) 230-235 °C (lit.)
Density: 0.853 g/mL at 25 °C (lit.)
vapor density: 7.95 (vs air)
vapor pressure: 3.79hPa at 25℃
refractive index: n20/D 1.409(lit.)
Flash point:: 200 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Methanol,Benzene,Ethanol
form: Liquid
Specific Gravity: 0.853
color: Clear colorless
Water Solubility: decomposes
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
BRN: 1703865
Stability:: Stables, but reacts rapidly with moisture, water. Reacts vigorously with oxidizing agents. Incompatible with strong acids.
InChIKey: LGQXXHMEBUOXRP-UHFFFAOYSA-N
LogP: 1 at 25℃
CAS DataBase Reference: 688-74-4(CAS DataBase Reference)
NIST Chemistry Reference: Boric acid, tributyl ester(688-74-4)
EPA Substance Registry System: Tributyl borate (688-74-4)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38-36/38
Safety Statements: 26-36/37/39-37/39
RIDADR: 3272
WGK Germany: 3
RTECS: ED4900000
F: 21
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29209090
Hazardous Substances Data: 688-74-4(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 90795
Product name: Tributyl borate
Purity: ≥99.0% (T)
Packaging: 100ml
Price: $103
Updated: 2024/03/01

Sigma-Aldrich

Product number: 90795
Product name: Tributyl borate
Purity: ≥99.0% (T)
Packaging: 500ml
Price: $158
Updated: 2024/03/01

TCI Chemical

Product number: B0518
Product name: Tributyl Borate
Purity: >99.0%(T)
Packaging: 25mL
Price: $19
Updated: 2024/03/01

TCI Chemical

Product number: B0518
Product name: Tributyl Borate
Purity: >99.0%(T)
Packaging: 100mL
Price: $41
Updated: 2024/03/01

Alfa Aesar

Product number: A19322
Product name: Tri-n-butyl borate, 98%
Packaging: 100ml
Price: $50.65
Updated: 2024/03/01

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Tributyl borate Chemical Properties,Usage,Production

Chemical Properties

Water-white liquid. Distillation range, 85% distills between 135C and 140C (40 mm Hg). Hydrolyzes rapidly; miscible with common organic liquids. Combustible.

Uses

Welding fluxes, intermediate in preparation of borohydrides, flame retardant for textiles (with boric acid).

Uses

Tri-n-butyl Borate is used as a catalyst in the formation of dihydropyrimidinones under solvent-free microwave-assisted conditions.

Air & Water Reactions

Rapidly decomposes in water.

Reactivity Profile

Borates behave similarly to esters in that they react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters/borates with alkali metals and hydrides. Reacts vigorously with oxidizing materials. .

Health Hazard

ACUTE/CHRONIC HAZARDS: Toxic; may emit toxic fumes when heated to decomposition or on contact with acid or acid fumes, local irritant.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. An eye irritant. Flammable when exposed to heat, flame, or oxiduers. To fight fire, use foam, CO2, dry chemical. When heated to decomposition or on contact with acid or acid fumes it can emit toxic fumes; on contact with oxidizing materials it can react vigorously. See also BORANES and BORON COMPOUNDS.

Purification Methods

The chief impurities are n-butyl alcohol and boric acid (from hydrolysis). It must be handled in a dry-box and can readily be purified by fractional distillation, under reduced pressure. [O’Brien Aust J Chem 10 91 1957, Gerrard & Lappert J Chem Soc 2545, 2547 1951, Beilstein 1 IV 1544.]

Tributyl borate Preparation Products And Raw materials

Raw materials

Orthoboric acid 1-Butanol

Preparation Products

4-((N,N-DIMETHYLAMINO)METHYL)PHENYLBORONIC ACID PINACOL ESTER HYDROCHLORIDE QUINOLINE-4-BORONIC ACID BENZOFURAN-5-BORONIC ACID 2-Formylthiophene-3-boronic acid 2-ETHOXYPHENYLBORONIC ACID 2-Aminoethoxydiphenyl borate Curcumin 3-Furanboronic acid Indole-4-boronic acid L-Selenomethionine 6-(2-THIENYL)-2-PYRIDINECARBOXALDEHYDE 5-METHYLFURAN-2-BORONIC ACID

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Tributyl borate Suppliers

Americas 1 Belgium 3 China 312 Europe 2 France 1 Germany 6 Hungary 1 India 27 Japan 5 Russia 2 Singapore 1 Switzerland 2 United Kingdom 13 United States 38 Global 414

CMS Chemicals Limited

Tel: --
Fax: --
Email: cms.marketing@cms-chemicals.com
Country: United Kingdom
ProdList: 3708
Advantage: 60

Melrob Ltd (part of Nordmann)

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Email: nquiries@melrob.com
Country: United Kingdom
ProdList: 3065
Advantage: 58

Biosynth Carbosynth

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Email: ales@carbosynth.com
Country: United Kingdom
ProdList: 2598
Advantage: 58

Fisher Scientific Uk Ltd.

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Email: .international@thermofisher.com
Country: United Kingdom
ProdList: 2932
Advantage: 58

Molekula Limited

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Email: o@molekula.com
Country: United Kingdom
ProdList: 6127
Advantage: 58

Manchester Organics

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Email: info@manchesterorganics.com
Country: United Kingdom
ProdList: 6834
Advantage: 67

Carbosynth Limited

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Email: sales@carbosynth.com
Country: United Kingdom
ProdList: 6581
Advantage: 61

Leancare Ltd.

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Email: enquiry@leancare.co.uk
Country: United Kingdom
ProdList: 6446
Advantage: 42

MOLEKULA Ltd.

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Fax: --
Email: kevinbanks@molekula.com
Country: United Kingdom
ProdList: 6140
Advantage: 66

ARIAC - Armenian Institute of Applied Chemistry

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Fax: --
Email: ariac@web.am
Country: United Kingdom
ProdList: 2466
Advantage: 46

Eurolabs Limited

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Fax: --
Country: United Kingdom
ProdList: 6309
Advantage: 46

VWR International

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Fax: --
Email: solutions@vwr.com
Country: United Kingdom
ProdList: 6548
Advantage: 82

Ubichem plc

Tel: --
Fax: --
Email: sales@ubichem.com
Country: United Kingdom
ProdList: 1567
Advantage: 65

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View Lastest Price from Tributyl borate manufacturers

Hebei Longbang Technology Co., Ltd

Product: Tributyl borate 688-74-4
Price: US $5.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20TONS
Release date: 2024-05-27

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Tributyl borate 688-74-4
Price: US $45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000kg/week
Release date: 2024-05-31

HebeiShuoshengImportandExportco.,Ltd

Product: Tributyl borate 688-74-4
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-05

688-74-4, Tributyl borateRelated Search:

Trimethyl borate Triethyl borate 1-TRIBUTYLSTANNYL-2-TRIMETHYLSILYLACETYLENE TRIBUTYL PHOSPHITE TRIBUTYLSILANE Orthoboric acid Trioctyl borate DL-MENTHYL BORATE Tributyl borate Boric acid BORIC ACID TRI-N-HEXYL ESTER TRICYCLOHEXYL BORATE BORIC ACID TRIOCTADECYL ESTER TRI-N-AMYLBORATE BORIC ACID TRI-N-DECYL ESTER TRIBUTYL BORATE-10B, 98 ATOM % 10B BORIC ACID TRI-N-HEXADECYL ESTER BORIC ACID TRI-N-TETRADECYL ESTER

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(n-C4H9O)3B

Borane, tributoxy-

borane,tributoxy

Borester 2

tributylesterkyselinyborite

tributylorthoborate

tris(1-butyl)borate

Tris(butoxy)borane

N-BUTYLBORATE

BORON N-BUTOXIDE

BORIC ACID TRI-N-BUTYL ESTER

BORIC ACID TRIBUTYL ESTER

BUTYL BORATE

TRI-N-BUTOXYBORANE

TRI-N-BUTYL BORATE

TRIBUTYL BORATE-11B

TRIBUTOXYBORANE

TRIBUTOXYBORANE-11B

Buty borate

Boric acid tri-n-butyl ester~n-Butyl borate

Trinbutylboratecolorlessliq

Triutyl borate

Tri-n-butylborate,98%

n-Butoxide

Tri-n-butylborate,99%

TRI-N-BUTYLBORANEOXIDE

borester2

Boric acid (H3BO3), tributyl ester

boricacid(h3bo3),tributylester

boricacid,(h3bo3)tributylester

Boron tributoxide

borontributoxide

Butyl borate, (BuO)3 B

Butyl borate, tri-

tributoxy-boran

tributoxyborine

Tributoxyboron

Tributyl orthoborate

tri-butylborat

Tributylester kyseliny borite

Tributyl borate, 99%, for synthesis

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Tribuytl Borate

AI3 11060

AI311060

AI3-11060