Allylpalladium(II) Chloride Dimer

ChemicalBook > CAS DataBase List > Allylpalladium(II) Chloride Dimer

Allylpalladium(II) Chloride Dimer

Product Name: Allylpalladium(II) Chloride Dimer
CAS No.: 12012-95-2
Chemical Name: Allylpalladium(II) Chloride Dimer
Synonyms: ALLYLPALLADIUM CHLORIDE DIMER;[PdCl(C3H5)]2;[PdCl(allyl)]2;Allylpalladium(II) chloride;allylpaladium;Bis(allyl)dichlorodipalladium;oride dimer;Bis(pi-allylpallad;allyl-chloro-palladium;Allylpalladium chloride
CBNumber: CB4156701
Molecular Formula: C6H10Cl2Pd2
Formula Weight: 365.89
MOL File: 12012-95-2.mol

Less

Allylpalladium(II) Chloride Dimer Property

Melting point:: 120°C (dec.)
storage temp.: 2-8°C
form: Crystals or Crystalline Powder
color: Yellow to green-yellow
Water Solubility: decomposes
Sensitive: Air Sensitive
BRN: 4124623
NIST Chemistry Reference: [Pd(Cl)(C3H5)]2(12012-95-2)

Less

Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-40
Safety Statements: 26-36-36/37
WGK Germany: 3
RTECS: RT3510000
F: 1-10
TSCA: No
HS Code: 28439090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 222380
Product name: Allylpalladium(II) chloride dimer
Purity: 98%
Packaging: 1g
Price: $134
Updated: 2024/03/01

Sigma-Aldrich

Product number: 222380
Product name: Allylpalladium(II) chloride dimer
Purity: 98%
Packaging: 5g
Price: $524
Updated: 2024/03/01

Sigma-Aldrich

Product number: 705020
Product name: Allylpalladium chloride dimer ChemDose™ tablet
Packaging: 10tablets
Price: $91.8
Updated: 2023/06/20

TCI Chemical

Product number: A1479
Product name: Allylpalladium(II) Chloride Dimer
Purity: >97.0%(T)
Packaging: 1g
Price: $345
Updated: 2024/03/01

TCI Chemical

Product number: A1479
Product name: Allylpalladium(II) Chloride Dimer
Purity: >97.0%(T)
Packaging: 500mg
Price: $173
Updated: 2024/03/01

Less

Allylpalladium(II) Chloride Dimer Chemical Properties,Usage,Production

Chemical Properties

Allylpalladium(II) chloride dimer is a yellow powder with the formula [(η3-C3H5)PdCl]2. This compound is an important catalyst used in organic synthesis. It is one of the most widely used transition metal allyl complexes.

Uses

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

Uses

[Pd(allyl)Cl]2 can be used as a catalyst:
For the silylation of organobromides.
To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides.
To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
ChemDose: Convenient Dosing of Catalysts and Reagents

Preparation

Allylpalladium(II) chloride dimer is prepared by purging carbon monoxide through a methanolic aqueous solution of palladium(II) chloride, sodium chloride, and allyl chloride.
2Na2PdCl4 + 2 CH2=CHCH2Cl + 2 CO + 2 H2O → (C3H5)2Pd2Cl2 + 4 NaCl + 2 CO2 + 4 HCl

Reactions

Precatalyst for the enantioselective hydrosilylation of olefins.
Precatalyst for asymmetric allylic alkylation and amination.
Used as a palladium source for cross-coupling reactions.
Can be used with Trost ligands.
Catalyst for the carbostannylation of alkynes.
Used as a precatalyst for "-arylation of aldehydes.

General Description

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.

Purification Methods

It crystallises from benzene and is soluble in MeOH, Et2O and CHCl3. [Hüttel et al. Chem Ber 94 766 1961, Dent et al. J Chem Soc 1585 1964, Armstrong J Org Chem 31 618 1966.]

Allylpalladium(II) Chloride Dimer Preparation Products And Raw materials

Raw materials

Preparation Products

Less

Allylpalladium(II) Chloride Dimer Suppliers

Americas 1 Belgium 4 China 222 Europe 2 France 1 Germany 9 India 13 Italy 1 Japan 3 Switzerland 3 United Kingdom 10 United States 37 Global 306

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2409
Advantage: 58

Shaanxi Rock New Materials Co., Ltd.

Tel: 0917-8888777, 3380777,18691786767; 15619786767
Email: xuya@bjrock.com
Country: China
ProdList: 310
Advantage: 62

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

PharmaBlock Sciences (Nanjing),Inc.

Tel: 025-86918202 4000255188
Fax: 86-025-86918232
Email: sales@pharmablock.com
Country: China
ProdList: 4986
Advantage: 55

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18207
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12390
Advantage: 60

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Sichuan Kulinan Technology Co., Ltd

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11707
Advantage: 57

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9815
Advantage: 79

Hangzhou Yuhao Chemical Technology Co., Ltd

Tel: 0571-82693216
Fax: +86-571-82880190
Email: info@yuhaochemical.com
Country: China
ProdList: 9387
Advantage: 52

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9718
Advantage: 55

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9865
Advantage: 52

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing HuaMeiHuLiBiological Chemical

Tel: 010-56205725
Fax: 010-65763397
Email: waley188@sohu.com
Country: China
ProdList: 12335
Advantage: 58

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9458
Advantage: 58

Yurui (Shanghai) Chemical Co., Ltd.

Tel: 21-50456736 18602143071
Fax: 021-50761379
Email: chen@riyngroup.com
Country: China
ProdList: 1052
Advantage: 30

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19915
Advantage: 55

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 18017383231 18017383231
Fax: qq：2817624287
Email: lyh_antaeus@163.com
Country: China
ProdList: 9347
Advantage: 55

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18209
Advantage: 56

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-400-6206333 18521732826
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Shanghai Raise Chemical Technology Co.,Ltd

Tel: +86-021-50935922
Fax: +86-021-33847795
Country: China
ProdList: 7865
Advantage: 55

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8026
Advantage: 55

BeiJing Greenchem Technology Co.,Ltd.

Tel: 131-21959385 15640741633
Fax: 010-62925455
Email: chemrocking@bjgreenchem.com
Country: China
ProdList: 269
Advantage: 58

Nanjing Pharmaluxury Co., Ltd.

Tel: 025-83726959 15851816062
Fax: 025-8666-0986
Email: goodsalejs@163.com
Country: China
ProdList: 128
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41462
Advantage: 60

Zhengzhou HongSheng Pharmaceutical Co., Ltd.

Tel: 0371-13526885213 15637198702
Fax: 0371-63709726
Email: xpkchem@163.com
Country: China
ProdList: 3978
Advantage: 58

Shanghai Taibao Pharmaceutical Technology Co., Ltd.

Tel: 13816752554
Email: 1745533547@qq.com
Country: China
ProdList: 129
Advantage: 58

Sinocompound Catalysts Co., Ltd.

Tel: 0512-67216630 67216634
Fax: 0512-56316689
Email: sales@sinocompound.com
Country: China
ProdList: 278
Advantage: 64

Wuxi Zhongkun Biochemical Technology Co., Ltd.

Tel: 0510-85629785 18013409632
Fax: 051085625359
Email: sales@reading-chemicals.com
Country: China
ProdList: 15178
Advantage: 58

Suzhou yacoo science co.,Ltd

Tel: 0512-87182056 18013166090
Fax: 0512-87182056
Email: lingling.qi@yacoo.com.cn
Country: China
ProdList: 7295
Advantage: 60

Credit-Chem Co., Ltd.

Tel: 400-821-5857 021-64326257
Fax: 021-64393586 QQ;2798200800
Email: credit-chem@foxmail.com
Country: China
ProdList: 5219
Advantage: 58

Shanghai YuLue Chemical Co., Ltd.

Tel: 021-60345187 13671753212
Fax: 021-34702061
Email: lzz841106@aliyun.com
Country: China
ProdList: 10274
Advantage: 55

Shanghai Boka-chem Tech. Inc.

Tel: 400-026-1533/(021) 6478-0600
Fax: +86 (21) 6459-2060
Email: sales@bokachem.com
Country: China
ProdList: 876
Advantage: 58

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 16166
Advantage: 55

Hangzhou J&H Chemical Co., Ltd.

Tel: 0571-+86-571-87396432
Fax: 0571-87396431
Email: sales@jhechem.com
Country: China
ProdList: 11578
Advantage: 59

LETOPHARM LIMITED

Tel: +86-21-5821 5861
Fax: +86-21-5106 2861
Email: sales@letopharm.com
Country: China
ProdList: 2384
Advantage: 58

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

Watson Biotechnology Co.,Ltd

Tel: 027-59207879 1972026995 18140587686
Fax: QQ：1972026995
Email: sales@3600chem.com
Country: China
ProdList: 4661
Advantage: 55

Chengdu RunZeBenTu Chemical Co., Ltd

Tel: 028-88469284 18000562381
Email: rzbtsj@163.com
Country: China
ProdList: 9951
Advantage: 56

Codow Chemical Co.,Ltd.

Tel: 18620099427
Fax: +86-20-62619665
Email: amy@howeipharm.com
Country: China
ProdList: 17687
Advantage: 55

Wuhan Greatwall chemical Co,.LTD

Tel: 400-027-6116 18086000087
Fax: QQ: 2680733325
Email: sales@chemgreatwall.com
Country: China
ProdList: 1559
Advantage: 55

Less

View Lastest Price from Allylpalladium(II) Chloride Dimer manufacturers

henan kanbei chemical co.,ltd

Product: Allylpalladium(II) Chloride Dimer 12012-95-2
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

Longyan Tianhua Biological Technology Co., Ltd

Product: Allylpalladium chloride dimer 12012-95-2
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-10

Chemwill Asia Co.,Ltd.

Product: Allylpalladium chloride dimer 12012-95-2
Price: US $1.00/kg
Min. Order: 1kg
Purity: Pd 56% Purity:>98%
Supply Ability: High quality purified manufacturer
Release date: 2019-04-04

12012-95-2, Allylpalladium(II) Chloride DimerRelated Search:

Rhodium triiodide Palladium(II) sulfate Gold(III) chloride Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Benzeneruthenium(II) chloride dimer Palladium chloride Stannous chloride dihydrate INDIUM(III) CHLORIDE TETRAHYDRATE PALLADIUM(II) NITRATE HYDRATE Chloro(1,5-cyclooctadiene)methylpalladium(II) 97% CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) Bis(tri-tert-butylphosphine)palladium(0) Bis(tricyclohexylphosphine)palladium(II) Dichloride Tetrakis(triphenylphosphine)platinum PALLADIUM(II) IODIDE Palladium (II) Acetate Palladium(II) oxide

DI-MU-CHLOROBIS[(ETA-ALLYL)PALLADIUM(II)]

ALLYLPALLADIUM CHLORIDE DIMER

ALLYLPALLADIUM(II) CHLORIDE DIMER

allylpaladium

allylpaladiumchloridedimer

Bis(pi-allyl)dichlorodipalladium

Bis(pi-allylpalladium chloride)

Diallyldichlorodipalladium

Di-mu-chlorodi-pi-allyldipalladium

Di-pi-allyldi-mu-chlorodipalladium

Bis(allyl)dichlorodipalladium

Bis(allylchloropalladium)

Palladium, di-m-chlorobis(h3-2-propenyl)di-

(pi-allyl)palladium(II)chloridedimer Can be used to form catalysts in situ by separate addition of ligand. 120 dec.

Allylpalladium chloride dimer,98%

di-μ-chloro-bis(η-allyl)palladium

Allylpalladium chloride dimer, min. 98%

AllylpalladiuM chloride diMer, 98% 500MG

AllylpalladiuM(II) chloride diMer, Pd 56.0% Min

AllylpalladiuM(II) chloride diMer 98%

Allylpalladium(Ⅱ) chloride dimer

[PdCl(allyl)]2

Allylchloropalladium dimer

Bis(allyl)dichloropalladium

Allylpalladium chloride dimer ChemDose? tablet

[PdCl(C3H5)]2

Allylpalladium chloride dimer ChemDose(TM) tablet

Allylpalladium chloride dimer ChemDose<sup>(R)</sup> tablet

Allylpalladium(II) chloride

Bis(allyl)dichlorodipalladium(II)

Di-ì-chlorobis[(?-allyl)palladium(II)]

Allylpalladium(II) chloride dimer (58% Pd) for synthesis

Palladium allyl chloride dimer

Palladium chloride, allyl- (dimer)

Palladium, di-mu-chlorobis(eta3-2-propenyl)di-

Palladium, di-pi-allyldi-mu-chlorodi-

Palladiumchloride,allyl-(dimer)

pi-Allylpalladium chloride

pi-Allylpalladium chloride dimer

di-mu-chloro-bis(eta-allyl)palladium

Allylpalladium(II) chloride dimer,98%

Allylpalladiumchloridedimer,99%

Allylpalladium(II) chloride dimer, Pd 56.5% min

CHLOROALLYLPALLADIUM(II) - DIMER

Diallyldipalladiumdichloride

Bis(pi-allylpallad

Allylpalladium Chloride Dimer ([PdCl(allyl)]2)

bis(chloro(prop-2-en-1-yl)palladium)

oride dimer

Allylpalladium(II) Chloride Dimer &gt

Di-μ-chlorobis[(η-allyl)palladium(Ⅱ)]

Allylpalladium(II) chloride dimer，Pd 58.2%

Allylpalladium chloride dimer ISO 9001：2015 REACH

allyl-chloro-palladium

TIANFU-CHEM --Allylpalladium chloride dimer

Bis(η 3 -allyl)di( μ -chloro)dipalladium(II)

Allylpalladium(II)chloride dimmer

Di-μ-chlorobis(η3-2-propenyl)dipalladium