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2-AMINO-4-METHOXY-BENZOIC ACID

Product Name
2-AMINO-4-METHOXY-BENZOIC ACID
CAS No.
4294-95-5
Chemical Name
2-AMINO-4-METHOXY-BENZOIC ACID
Synonyms
2-Amino-p-anisic acid;4-METHOXYANTHRANILIC ACID;2-AMino-4-Metnoxybenzoic acid;2-amine-4-methoxybenzoic acid;m-Anisidine-6-carboxylic acid;4-METHOXY-2-AMINO-BENZOIC ACID;2-AMINO-4-METHOXY-BENZOIC ACID;2-azanyl-4-methoxy-benzoic acid;Benzoic acid, 2-amino-4-methoxy-;2-Amino-4-methoxybenzoic acid 97%
CBNumber
CB4244440
Molecular Formula
C8H9NO3
Formula Weight
167.16
MOL File
4294-95-5.mol
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2-AMINO-4-METHOXY-BENZOIC ACID Property

Melting point:
175-180 °C
Boiling point:
339.8±27.0 °C(Predicted)
Density 
1.303±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
powder to crystal
pka
5.21±0.10(Predicted)
color 
White to Light yellow to Light orange
InChI
InChI=1S/C8H9NO3/c1-12-5-2-3-6(8(10)11)7(9)4-5/h2-4H,9H2,1H3,(H,10,11)
InChIKey
HHNWXQCVWVVVQZ-UHFFFAOYSA-N
SMILES
C(O)(=O)C1=CC=C(OC)C=C1N
CAS DataBase Reference
4294-95-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36/37/39-37
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29225090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
A2319
Product name
2-Amino-4-methoxybenzoic Acid
Purity
>97.0%(HPLC)(T)
Packaging
1g
Price
$56
Updated
2025/07/31
TCI Chemical
Product number
A2319
Product name
2-Amino-4-methoxybenzoic Acid
Purity
>97.0%(HPLC)(T)
Packaging
5g
Price
$223
Updated
2025/07/31
TRC
Product number
A585020
Product name
2-Amino-4-methoxybenzoic Acid
Packaging
5g
Price
$75
Updated
2021/12/16
TRC
Product number
A585020
Product name
2-Amino-4-methoxybenzoic Acid
Packaging
10g
Price
$110
Updated
2021/12/16
AK Scientific
Product number
V1366
Product name
2-Amino-4-methoxybenzoic Acid
Packaging
1g
Price
$14
Updated
2021/12/16
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2-AMINO-4-METHOXY-BENZOIC ACID Chemical Properties,Usage,Production

Chemical Properties

Yellow powder

Uses

2-Amino-4-methoxybenzoic Acid, is an organic building block used in the synthesis of various chemical compounds.

Synthesis

33844-21-2

4294-95-5

The general procedure for the synthesis of 2-amino-4-methoxybenzoic acid from 4-methoxy-2-nitrobenzoic acid is as follows: Intermediate 113: Synthesis of 2-amino-4-methoxybenzoic acid 4-Methoxy-2-nitrobenzoic acid (3 g, 16.4 mmol) was dissolved in methanol (80 mL) and 10% palladium carbon catalyst (300 mg) was added. The hydrogenation reaction was carried out at room temperature and atmospheric pressure for 18 hours. Upon completion of the reaction, the reaction mixture was filtered through diatomaceous earth to remove the catalyst and the filtrate was concentrated to dryness under reduced pressure to give 2.50 g (100% yield) of 2-amino-4-methoxybenzoic acid as a colorless solid. 1H NMR (DMSO-d6) δ: 3.70 (s, 3H); 6.09 (dd, 1H); 6.23 (d, 1H); 7.59 (d, 1H).

References

[1] Patent: WO2006/134378, 2006, A1. Location in patent: Page/Page column 112
[2] Patent: WO2010/123975, 2010, A1. Location in patent: Page/Page column 101-102
[3] Patent: US2013/281398, 2013, A1. Location in patent: Paragraph 0493; 0494
[4] Patent: US5599814, 1997, A
[5] Patent: WO2007/71963, 2007, A2. Location in patent: Page/Page column 52

2-AMINO-4-METHOXY-BENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-4-METHOXY-BENZOIC ACID Suppliers

Americas 1 Canada 1 China 225 Europe 1 Germany 2 India 16 Japan 1 Switzerland 1 United Kingdom 10 United States 32 Global 290
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from 2-AMINO-4-METHOXY-BENZOIC ACID manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2-AMINO-4-METHOXY-BENZOIC ACID 4294-95-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
2-AMINO-4-METHOXY-BENZOIC ACID 4294-95-5
Price
US $150.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5ton
Release date
2024-04-22
Hebei Yanxi Chemical Co., Ltd.
Product
2-AMINO-4-METHOXY-BENZOIC ACID 4294-95-5
Price
US $30.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-20

4294-95-5, 2-AMINO-4-METHOXY-BENZOIC ACIDRelated Search:

2-Amino-4,5-dimethoxybenzoic acid ETHYL 2-AMINO-4,5-DIMETHOXYBENZOATE ETHYL 4,5-DIMETHOXY-2-NITROBENZOATE Methyl 2-amino-3,4,5-trimethoxybenzoate D-ribo-Hexanoic acid, 3-deoxy-, γ-lactone Methyl 2-nitro-3,4,5-trimethoxybenzoate 2-AMINO-3,4,5-TRIMETHOXYBENZOIC ACID Methyl 2-amino-4,5-dimethoxybenzoate Methyl 3-amino-4-methoxybenzoate 2-Amino-6-methoxybenzoic acid Methyl 4-acetamido-2-methoxybenzoate Methyl 4-amino-2-methoxybenzoate 4-Amino-3-methoxybenzoic acid 2-Amino-5-methoxybenzoic acid 4-AMINO-2-METHOXYBENZOIC ACID 3-Amino-4-methoxybenzoic acid 2-AMINO-3-METHOXYBENZOIC ACID METHYL 2-AMINO-5-METHOXYBENZOATE

  • 2-AMINO-4-METHOXY-BENZOIC ACID
  • 4-METHOXY-2-AMINO-BENZOIC ACID
  • 4-METHOXYANTHRANILIC ACID
  • 2-AMINO-4-METHOXYBENZOIC ACID ---OFF-WHITE POWDER, 99%---
  • 2-amine-4-methoxybenzoic acid
  • 2-azanyl-4-methoxy-benzoic acid
  • 4-Methoxyanthranilic acid, 2-Carboxy-5-methoxyaniline, 3-Amino-4-carboxyanisole
  • 4-METHOXY-2-AMINO-BENZOIC ACID(or 4-METHOXYANTHRANILIC ACID)
  • 4-Methoxyanthranilic Acid m-Anisidine-6-carboxylic Acid 2-Amino-p-anisic Acid
  • 2-AMino-4-Metnoxybenzoic acid
  • Benzoic acid, 2-amino-4-methoxy-
  • 2-Amino-4-methoxybenzoic acid 97%
  • 2-Amino-p-anisic acid
  • m-Anisidine-6-carboxylic acid
  • 2-Amino-4-methoxybenzoic Acid &gt
  • 4-Methoxyanthranilic acid, CAS 4294-95-5
  • 4294-95-5
  • pharmacetical