ChemicalBook > CAS DataBase List > PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)-

PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)-

Product Name
PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)-
CAS No.
84611-43-8
Chemical Name
PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)-
Synonyms
2-Chloro-5-benzyloxypyridine;5-(benzyloxy)-2-chloropyridine;2-CHLORO-5-(PHENYLMETHOXY)-PYRIDINE;PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)-
CBNumber
CB42468048
Molecular Formula
C12H10ClNO
Formula Weight
219.67
MOL File
84611-43-8.mol
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PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)- Property

Density 
1.225
storage temp. 
2-8°C
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H319Causes serious eye irritation

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P322Specific measures (see …on this label).

P330Rinse mouth.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B285973
Product name
5-(Benzyloxy)-2-chloropyridine
Packaging
500mg
Price
$200
Updated
2021/12/16
TRC
Product number
B285973
Product name
5-(Benzyloxy)-2-chloropyridine
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
4504AQ
Product name
2-chloro-5-phenylmethoxypyridine
Packaging
5g
Price
$735.2
Updated
2021/12/16
Chemenu
Product number
CM128886
Product name
5-(benzyloxy)-2-chloropyridine
Purity
98%
Packaging
5g
Price
$1047
Updated
2021/12/16
Crysdot
Product number
CD11047494
Product name
5-(Benzyloxy)-2-chloropyridine
Purity
98%
Packaging
5g
Price
$1120
Updated
2021/12/16
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PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)- Chemical Properties,Usage,Production

Synthesis

41288-96-4

100-39-0

84611-43-8

The reaction was carried out with 2-chloro-5-hydroxypyridine (6-chloropyridin-3-ol, 1.0 g) and benzyl bromide (benzyl bromide, 1.5 g) as raw materials in the presence of potassium carbonate (2.4 g) at 60 °C for 18 h with stirring in N,N-dimethylformamide (DMF, 40 mL). After completion of the reaction, the reaction mixture was filtered and the solvent in the filtrate was removed by distillation under reduced pressure to obtain the crude product. The crude product was purified by silica gel column chromatography (eluent: hexane-ethyl acetate gradient) to afford the target compound 2-chloro-5-benzyloxypyridine (3-(benzyloxy)-2-chloro pyridine, 1.3 g) in quantitative yield.

References

[1] Patent: JP2017/171619, 2017, A. Location in patent: Paragraph 0233; 0235
[2] Patent: US2003/162790, 2003, A1
[3] Patent: US2002/169166, 2002, A1
[4] Patent: US2002/169167, 2002, A1
[5] Patent: US2004/127504, 2004, A1

PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)- Preparation Products And Raw materials

Raw materials

Preparation Products

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PYRIDINE, 2-CHLORO-5-(PHENYLMETHOXY)- Suppliers

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