ChemicalBook > CAS DataBase List > (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

Reaction

Product Name: (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
CAS No.: 158923-11-6
Chemical Name: (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
Synonyms: JOSIPHOS SL-J009-1;(R)-(S)-cy2PF-PtBu2;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine;(2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene;CyPFt-Bu;(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE;(R)-1-[(S;SL-J009-1;(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t...
CBNumber: CB4258744
Molecular Formula: C32H52FeP2 10*
Formula Weight: 554.55
MOL File: 158923-11-6.mol

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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Property

Melting point:: 118-120oC
alpha: -185° ±10° (c 0.5, CHCl3)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Chloroform (Slightly), Methanol (Very Slightly)
form: Powder
color: orange
InChIKey: FFFWTQLOUUWUJJ-MGIYCFTINA-N
SMILES: [Fe].[CH]1[CH][CH][C](P(C2CCCCC2)C2CCCCC2)[C]1[C@H](P(C(C)(C)C)C(C)(C)C)C.[CH]1[CH][CH][CH][CH]1 |&1:19,r,^1:1,2,3,4,18,30,31,32,33,34|

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 88733
Product name: (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Purity: ≥97%
Packaging: 1g
Price: $682
Updated: 2025/07/31

Sigma-Aldrich

Product number: 88733
Product name: (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Purity: ≥97%
Packaging: 5g
Price: $2500
Updated: 2025/07/31

Strem Chemicals

Product number: 26-0975
Product name: (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
Packaging: 100mg
Price: $107
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0975
Product name: (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
Packaging: 500mg
Price: $375
Updated: 2024/03/01

Sigma-Aldrich

Product number: 88733
Product name: (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Purity: ≥97%
Packaging: 100mg
Price: $126
Updated: 2025/07/31

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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Chemical Properties,Usage,Production

Reaction

Ligand for Palladium-catalyzed C-N cross-coupling.
Ligand for Palladium-catalyzed C-S cross-coupling.
Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
Ligand for Palladium-catalyzed C-O cross-coupling.
Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation

Chemical Properties

Orange powder

Uses

It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.

General Description

sold in collaboration with Solvias AG

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Suppliers

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View Lastest Price from (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine 158923-11-6
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-19

XINXIANG RUNYU MATERIAL CO., LTD.

Product: (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 158923-11-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 0.98
Supply Ability: larger package as required
Release date: 2023-02-08

Henan Bao Enluo International TradeCo.，LTD

Product: (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 158923-11-6
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 500t/month
Release date: 2023-08-02

158923-11-6, (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINERelated Search:

(R)-1-[3,5-Bis(trifluoromethyl)phenyl]ethanol (R)-1-nonen-3-ol (R)-(-)-1,2,3,4-TETRAHYDRO-1-NAPHTHOL (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(S)-JOSIPHOS (R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Di-tert-butylphosphine T-BUTYLPHOSPHINE CYCLOHEXYLPHOSPHINE Ferrocene DICYCLOHEXYLPHOSPHINE (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 1,3-BIS(DIETHYLPHOSPHINO)PROPANE 1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE (S)-1-[(R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE (R)-(-)-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

(R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine

(R)-(S)-cy2PF-PtBu2

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

Ferrocene,1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)-,(2R)-

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%

(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine

Josiphos SL-J009-1 / (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine

(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] ethyldi-t-butylphosphine, min. 97%

(R)-1-[(S

(R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-(DICYCLOHEXYLPHOSPHINO)FERROCENE

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE

JOSIPHOS SL-J009-1

(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97%

(r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-(dicyclohexylphosphino)ferrocene (acc to cas)

(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl]di-tert-butylphosphine

CyPFt-Bu

(R)-1-[(Sp)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl di-tert-butylphospine

(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t...

(2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene

(R)-(-)-1-[(Sp)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine

(R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine(Josiphos SL-J009-1)

cyclopenta-2,4-dien-1-yl-[2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron

SL-J009-1

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

158923-11-6

C32H52FeP2

C27H47P2C5H5Fe

Solvias Ligands

Privileged Ligands

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

organophosphine ligand

Chiral Phosphine

Ferrocene Series

Josiphos Series