Reaction
ChemicalBook > CAS DataBase List > (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

Reaction
Product Name
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
CAS No.
158923-11-6
Chemical Name
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
Synonyms
JOSIPHOS SL-J009-1;(R)-(S)-cy2PF-PtBu2;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine;(2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene;CyPFt-Bu;(R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE;(R)-1-[(S;SL-J009-1;(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t...
CBNumber
CB4258744
Molecular Formula
C32H52FeP2 10*
Formula Weight
554.55
MOL File
158923-11-6.mol
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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Property

Melting point:
118-120oC
alpha 
-185° ±10° (c 0.5, CHCl3)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Chloroform (Slightly), Methanol (Very Slightly)
form 
Powder
color 
orange
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
88733
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Purity
≥97%
Packaging
1g
Price
$662
Updated
2024/03/01
Sigma-Aldrich
Product number
88733
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Purity
≥97%
Packaging
5g
Price
$2430
Updated
2024/03/01
Strem Chemicals
Product number
26-0975
Product name
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
Packaging
100mg
Price
$107
Updated
2024/03/01
Strem Chemicals
Product number
26-0975
Product name
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine, min. 97%
Packaging
500mg
Price
$375
Updated
2024/03/01
Sigma-Aldrich
Product number
88733
Product name
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Purity
≥97%
Packaging
100mg
Price
$122
Updated
2024/03/01
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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Chemical Properties,Usage,Production

Reaction

  1. Ligand for Palladium-catalyzed C-N cross-coupling.
  2. Ligand for Palladium-catalyzed C-S cross-coupling.
  3. Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
  4. Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
  5. Ligand for Palladium-catalyzed C-O cross-coupling.
  6. Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
  7. Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation


Chemical Properties

Orange powder

Uses

It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.

General Description

sold in collaboration with Solvias AG

(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE Suppliers

China 129 Germany 2 India 3 Norway 1 Switzerland 1 United States 6 Global 142
SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE manufacturers

Henan Bao Enluo International TradeCo.，LTD
Product
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 158923-11-6
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500t/month
Release date
2023-08-02
XINXIANG RUNYU MATERIAL CO., LTD.
Product
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 158923-11-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
0.98
Supply Ability
larger package as required
Release date
2023-02-08
Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine 158923-11-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

158923-11-6, (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINERelated Search:

(R)-1-[3,5-Bis(trifluoromethyl)phenyl]ethanol (R)-1-nonen-3-ol (R)-(-)-1,2,3,4-TETRAHYDRO-1-NAPHTHOL (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(S)-JOSIPHOS (R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Di-tert-butylphosphine T-BUTYLPHOSPHINE CYCLOHEXYLPHOSPHINE Ferrocene DICYCLOHEXYLPHOSPHINE (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE 1,3-BIS(DIETHYLPHOSPHINO)PROPANE 1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE (S)-1-[(R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE (R)-(-)-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE

  • (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine
  • (R)-(S)-cy2PF-PtBu2
  • (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
  • Ferrocene,1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)-,(2R)-
  • (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%
  • (Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine
  • Josiphos SL-J009-1 / (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine
  • (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl] ethyldi-t-butylphosphine, min. 97%
  • (R)-1-[(S
  • (R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-(DICYCLOHEXYLPHOSPHINO)FERROCENE
  • (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE
  • (R)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
  • JOSIPHOS SL-J009-1
  • (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97%
  • (r,r)-1-[1-(di-tert-butylphosphino)ethyl]-2-(dicyclohexylphosphino)ferrocene (acc to cas)
  • (R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl]di-tert-butylphosphine
  • CyPFt-Bu
  • (R)-1-[(Sp)-2-(Dicyclohexylphosphino)ferrocenyl]ethyl di-tert-butylphospine
  • (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t...
  • (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene
  • (R)-(-)-1-[(Sp)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine
  • (R)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyli-tert-butylphosphine(Josiphos SL-J009-1)
  • cyclopenta-2,4-dien-1-yl-[2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron
  • SL-J009-1
  • 158923-11-6
  • C32H52FeP2
  • C27H47P2C5H5Fe
  • Solvias Ligands
  • Privileged Ligands
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • organophosphine ligand
  • Chiral Phosphine
  • Ferrocene Series
  • Josiphos Series