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Ethyl benzoylformate

Product Name
Ethyl benzoylformate
CAS No.
1603-79-8
Chemical Name
Ethyl benzoylformate
Synonyms
ETHYL 2-OXO-2-PHENYLACETATE;ETHYL PHENYLGLYOXYLATE;Benzeneacetic acid, .alpha.-oxo-, ethyl ester;Ethyl oxophenyla;RARECHEM AL BI 0384;ETHYL BENZOYLFORMATE;PHENYLETHYLGLYOXYLATE;Ethyloxophenylacetate;Ethyl oxophenylacetate;Ethylα-oxobenzeneacetate
CBNumber
CB4299905
Molecular Formula
C10H10O3
Formula Weight
178.18
MOL File
1603-79-8.mol
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Ethyl benzoylformate Property

Boiling point:
138-139 °C/18 mmHg (lit.)
Density 
1.122 g/mL at 25 °C (lit.)
refractive index 
1.515-1.517
Flash point:
113 °C
storage temp. 
Store below +30°C.
form 
Liquid
Specific Gravity
1.122
color 
Clear colorless to greenish
Water Solubility 
Soluble in water 1143 mg/L @ 25°C .
Sensitive 
Moisture Sensitive
InChI
InChI=1S/C10H10O3/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7H,2H2,1H3
InChIKey
QKLCQKPAECHXCQ-UHFFFAOYSA-N
SMILES
C1(C=CC=CC=1)C(=O)C(=O)OCC
LogP
1.974 (est)
CAS DataBase Reference
1603-79-8(CAS DataBase Reference)
NIST Chemistry Reference
Benzeneacetic acid, «alpha»-oxo-, ethyl ester(1603-79-8)
EPA Substance Registry System
Benzeneacetic acid, .alpha.-oxo-, ethyl ester (1603-79-8)
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Safety

Hazard Codes 
Xi
Safety Statements 
24/25
WGK Germany 
3
Hazard Note 
Moisture Sensitive
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29183000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H227Combustible liquid

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
258911
Product name
Ethyl benzoylformate
Purity
95%
Packaging
5g
Price
$31.8
Updated
2024/03/01
Sigma-Aldrich
Product number
258911
Product name
Ethyl benzoylformate
Purity
95%
Packaging
25g
Price
$71
Updated
2024/03/01
TCI Chemical
Product number
B0109
Product name
Ethyl Benzoylformate
Purity
>96.0%(GC)
Packaging
5mL
Price
$29
Updated
2024/03/01
TCI Chemical
Product number
B0109
Product name
Ethyl Benzoylformate
Purity
>96.0%(GC)
Packaging
25mL
Price
$76
Updated
2024/03/01
Alfa Aesar
Product number
B25292
Product name
Ethyl phenylglyoxylate, 98%
Packaging
5g
Price
$27.65
Updated
2024/03/01
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Ethyl benzoylformate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to greenish liquid

Uses

Ethyl Benzoylformate is a general chemical reagent used in the preparation of diaminoethanediyl bismethylpyridinium salts for designing recyclable organocatalysts.

Application

Ethyl benzoylformate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.

Definition

ChEBI: Ethyl benzoylformate is the ethyl ester of phenylglyoxylic acid. Metabolite observed in cancer metabolism. It has a role as a human metabolite. It derives from a phenylglyoxylic acid.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 918, 1960
The Journal of Organic Chemistry, 50, p. 3573, 1985 DOI: 10.1021/jo00219a025
Tetrahedron Letters, 23, p. 3661, 1982 DOI: 10.1016/S0040-4039(00)88651-7

General Description

Enantioselective hydrogenation of ethyl benzoylformate on Pt/Al2O3 modified with dihydrocinchonidine has been studied.

Ethyl benzoylformate Preparation Products And Raw materials

Raw materials

Nitrogen Diethyl oxalate Bromobenzene Diethyl ether Ammonium chloride Magnesium

Preparation Products

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Ethyl benzoylformate Suppliers

Americas 1 Belgium 2 CHINA 165 Europe 3 Germany 8 India 9 Japan 2 Switzerland 2 United Kingdom 15 United States 32 USA 1 Global 240
HBCChem, Inc.
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View Lastest Price from Ethyl benzoylformate manufacturers

Career Henan Chemical Co
Product
Ethyl benzoylformate 1603-79-8
Price
US $2.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2018-12-24

1603-79-8, Ethyl benzoylformateRelated Search:

Benzoyl peroxide Ethanol Ethyl acetate Ethylparaben Ethyl cyanoacetate ETHYL ANTHRANILATE Ethyl benzoate Ethyl acrylate Stearoylbenzoylmethane Ethyl benzoylacetate Ethyl pyruvate Ethyl formate ISOXADIFEN-ETHYL Trinexapac-ethyl ETHYL 4-METHOXYBENZOYLFORMATE ETHYL 4-NITROPHENYLGLYOXYLATE ETHYL MESITYLGLYOXYLATE Ethyl phenylacetate

  • RARECHEM AL BI 0384
  • PHENYLETHYLGLYOXYLATE
  • PHENYLGLYOXYLIC ACID ETHYL ESTER
  • alpha-oxo-benzeneaceticaciethylester
  • Benzenaceticacid,-oxoethylester
  • Benzeneaceticacid,α-oxo-,ethylester
  • Ethyl oxophenylacetate
  • Ethyloxophenylacetate
  • Ethylα-oxobenzeneacetate
  • Glyoxylic acid, phenyl-, ethyl ester
  • alpha-oxo-benzeneacetic acid ethyl ester
  • Ethyl oxo(phenyl)acetate 98%
  • Ethyl phenylglyoxylate, Ethyl benzoylformate
  • Benzoylformic Acid Ethyl Ester Ethyl Phenylglyoxylate Phenylglyoxylic Acid Ethyl Ester
  • ETHYL PHENYLGLYOXYLATE FOR SYNTHESIS
  • Gloyoxylic acid, phenyl-, ethyl ester
  • 2-Oxo-2-phenylacetic acid ethyl ester
  • 2-Phenylglyoxalic acid ethyl ester
  • Phenyloxoacetic acid ethyl ester
  • Ethyl benzoylformate,95%
  • a-Oxo-benzeneacetic acid ethyl ester
  • Ethyl oxophenyla
  • Ethyl BenzoylforMate, 97+%
  • Glyoxylicacid,phenyl-,ethylester
  • Oxo-phenyl-aceticacidethylester
  • α-Oxobenzeneaceticacidethylester
  • ETHYL 2-OXO-2-PHENYLACETATE
  • ETHYL BENZOYLFORMATE
  • ETHYL PHENYLGLYOXYLATE
  • BENZOYLFORMIC ACID ETHYL ESTER
  • Benzoylformic acid ethyl ester~Ethyl phenylglyoxylate
  • BENZENACETIC ACID, -OXO ETHYL ESTER 96%
  • PhenylglyoxylicAcidEthylEther
  • Benzeneacetic acid, .alpha.-oxo-, ethyl ester
  • Ethyl benzoylformate 98%
  • Benzeneacetic acid, α-oxo-, ethyl ester
  • 1603-79-8
  • C6H5COCO2C2H5
  • C6H5COCOOC2H5
  • Carbonyl Compounds
  • C10 to C11
  • Building Blocks
  • Esters
  • Organic Building Blocks
  • Pharmaceutical Intermediates
  • Aromatic Esters
  • Esters
  • Phenyls & Phenyl-Het
  • API intermediates
  • Phenyls & Phenyl-Het