ChemicalBook > CAS DataBase List > Methyl 3-bromobenzoate

Methyl 3-bromobenzoate

Product Name
Methyl 3-bromobenzoate
CAS No.
618-89-3
Chemical Name
Methyl 3-bromobenzoate
Synonyms
RARECHEM AL BF 0052;3-Bromobenzoate Methyl;METHYL M-BROMOBENZOATE;METHYL 3-BROMOBENZOATE;Methyl-3-Bromobenzoate 98%;Methyl 3-Bromobenzoate >Methyl 3-bromobenzoate, 98+%;3-bromo-benzoicacimethylester;Methyl 3-broMobenzoate, 98% 5GR;m-Bromobenzoic acid methyl ester
CBNumber
CB4345734
Molecular Formula
C8H7BrO2
Formula Weight
215.04
MOL File
618-89-3.mol
More
Less

Methyl 3-bromobenzoate Property

Melting point:
31-33 °C(lit.)
Boiling point:
127-128 °C15 mm Hg(lit.)
Density 
1.5313 (rough estimate)
refractive index 
1.5575
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Crystalline Solid or Liquid
color 
White to light yellow
Water Solubility 
Slightly soluble in water.
BRN 
1940810
InChIKey
KMFJVYMFCAIRAN-UHFFFAOYSA-N
CAS DataBase Reference
618-89-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 3-bromo-, methyl ester(618-89-3)
EPA Substance Registry System
Benzoic acid, 3-bromo-, methyl ester (618-89-3)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-24/25
WGK Germany 
3
TSCA 
Yes
HS Code 
29163990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
499625
Product name
Methyl 3-bromobenzoate
Purity
98%
Packaging
5g
Price
$40.6
Updated
2024/03/01
Sigma-Aldrich
Product number
499625
Product name
Methyl 3-bromobenzoate
Purity
98%
Packaging
25g
Price
$65
Updated
2024/03/01
TCI Chemical
Product number
B0554
Product name
Methyl 3-Bromobenzoate
Purity
>99.0%(GC)
Packaging
5g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
B0554
Product name
Methyl 3-Bromobenzoate
Purity
>99.0%(GC)
Packaging
25g
Price
$85
Updated
2024/03/01
Alfa Aesar
Product number
A16174
Product name
Methyl 3-bromobenzoate, 98+%
Packaging
10g
Price
$56.65
Updated
2024/03/01
More
Less

Methyl 3-bromobenzoate Chemical Properties,Usage,Production

Chemical Properties

Methyl 3-bromobenzoate is white to light yellow low melting crystalline

Uses

Methyl 3-bromobenzoate is an halogenated benzoate derivative used as a reagent in organic synthesis.Methyl 3-bromobenzoate is used in the synthesis of a novel series of tetrahydro dibenzazocine as inhibitors of 17β-hydroxysteroid dehydrogenase type 3.

Uses

Methyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.

General Description

Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.

Methyl 3-bromobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Methyl 3-bromobenzoate Suppliers

Americas 1 Belgium 1 Canada 1 China 183 Cyprus 1 Europe 3 France 1 Germany 5 India 26 Japan 3 Slovakia 1 Switzerland 3 United Kingdom 19 United States 35 Global 283
HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10648
Advantage
60
AbaChemScene
Tel
732-484-9848
Fax
888-484-5008
Email
sales@chemscene.com
Country
United States
ProdList
3982
Advantage
60
Accela ChemBio Inc.
Tel
+1-858-6993322
Fax
(+1)-858-876-1948
Email
info@accelachem.com
Country
United States
ProdList
17982
Advantage
58
Alchem Pharmtech,Inc.
Tel
8485655694
Email
sales@alchempharmtech.com
Country
United States
ProdList
63687
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Aceschem Inc.
Tel
+1-817863-6948 +1-（817）863-6948
Email
sales@aceschem.com
Country
United States
ProdList
19632
Advantage
58
Synthonix Inc
Tel
--
Fax
--
Email
info@synthonix.com
Country
United States
ProdList
6872
Advantage
58
Alfa Chemistry
Tel
--
Fax
--
Email
info@Alfa-Chemistry.com
Country
United States
ProdList
6814
Advantage
0
Frontier Scientific Services, Inc.
Tel
--
Fax
--
Email
customerservice@frontierssi.com
Country
United States
ProdList
1575
Advantage
0
BromOrganics Corporation
Tel
--
Fax
--
Email
sales@bromorganics.com
Country
United States
ProdList
1065
Advantage
58
Alichem Inc.
Tel
--
Fax
--
Email
sales@alichem.com
Country
United States
ProdList
6167
Advantage
58
Fine Chem Trading LTD
Tel
--
Fax
--
Email
chemfinder@chemfinder.co.uk
Country
United States
ProdList
1609
Advantage
64
AOBChem
Tel
--
Fax
--
Email
sales@aobchem.com
Country
United States
ProdList
885
Advantage
58
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Frontier Scientific, Inc.
Tel
--
Fax
--
Email
sales@frontiersci.com
Country
United States
ProdList
6222
Advantage
86
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
Labseeker Inc
Tel
--
Fax
--
Email
marketing@labseeker.com
Country
United States
ProdList
1495
Advantage
55
Chirofine Chemicals Company
Tel
--
Fax
--
Country
United States
ProdList
41
Advantage
38
HBCChem Inc.
Tel
--
Fax
--
Email
sales@hbcchem-inc.com
Country
United States
ProdList
4569
Advantage
30
Ivy Fine Chemicals
Tel
--
Fax
--
Email
sales@ivychem.com
Country
United States
ProdList
6493
Advantage
58
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6962
Advantage
56
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
INDOFINE Chemical Company, Inc.
Tel
--
Fax
--
Email
chemical@indofinechemical.com
Country
United States
ProdList
6176
Advantage
69
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
Esprit Chemical Company
Tel
--
Fax
--
Email
admin@esprixtech.com
Country
United States
ProdList
1616
Advantage
55
Davos Chemical Corporation
Tel
--
Fax
--
Email
info@davos.com
Country
United States
ProdList
1640
Advantage
65
Honeywell Specialty Chemicals Seelze GmbH
Tel
--
Fax
--
Email
ofc@honeywell.com
Country
United States
ProdList
639
Advantage
87
ASDI Incorporated
Tel
--
Fax
--
Email
customerservice@asdi.net
Country
United States
ProdList
6922
Advantage
67
More
Less

View Lastest Price from Methyl 3-bromobenzoate manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd
Product
Methyl 3-bromobenzoate 618-89-3
Price
US $70.00-700.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-11-08
Shanghai Rlavie Technology Co ltd
Product
3-bromobenzoate Methyl 618-89-3
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
100kgs/month
Release date
2022-01-03
Career Henan Chemical Co
Product
Methyl 3-bromobenzoate 618-89-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-02

618-89-3, Methyl 3-bromobenzoateRelated Search:

Methylparaben Methyl bromoacetate METHYL THIOPHENE-2-CARBOXYLATE Methyl benzoate Benzoic acid Bensulfuron methyl Methyl 2-bromo-2-methylpropionate 4-Bromomethylbenzoic acid Thiophanate-methyl Methyl 4-cyanobenzoate Methyl acrylate Methyl acetate Kresoxim-methyl METHYL 5-BROMOSALICYLATE 4-Bromobenzoic acid 3-BROMOISONICOTINIC ACID METHYL ESTER Methyl 3-bromopropionate methyl 3-bromopicolinate

  • METHYL 3-BROMOBENZOATE FOR SYNTHESIS
  • 3-bromo-benzoicacimethylester
  • Benzoic acid, m-bromo-, methyl ester
  • Benzoicacid,3-bromo-,methylester
  • m-Bromobenzoic acid methyl ester
  • RARECHEM AL BF 0052
  • 3-BROMOBENZOIC ACID METHYL ESTER
  • Methyl 3-bromobenzoate, 98+%
  • Methyl-3-Bromobenzoate 98%
  • Methyl 3-broMobenzoate, 98% 5GR
  • 3-Bromobenzoate Methyl
  • METHYL M-BROMOBENZOATE
  • METHYL 3-BROMOBENZOATE
  • Methyl 3-Bromobenzoate &gt
  • 618-89-3
  • Organic Building Blocks
  • Esters
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Aromatic Esters
  • API intermediates
  • Acids & Esters
  • Bromine Compounds
  • C8 to C9
  • Carbonyl Compounds
  • Esters
  • Acids and Derivatives
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks